• Title/Summary/Keyword: CA1

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Comparison of Properties of Natural Ca-Montmorillonite and its Al-pillared Montmorillonites (천연 Ca-몬모릴로나이트와 이로부터 합성된 Al-가교몬모릴로나이트의 특성 비교연구)

  • 이정현;김수진
    • Journal of the Mineralogical Society of Korea
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    • v.15 no.4
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    • pp.273-282
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    • 2002
  • Al-pillared montmorillonite was synthesized from Na-saturated montmorillonite which was prepared by ionic substitution from Ca-montmorillonite of the Jabut mine, Gyeongiu City d(001), surface areas, and dehydration and ionic substitution properties have been compared for both Ca-montmorillonite and Al-pillared montmorillonite. d(001) spacings of Ca-montmorillonite and Al-pillared montmorillonite were 15.1 $\AA$ and $18.3\AA$, respectively. Dehydration took place before $350 ^{\circ}C$ in Ca-montmorillonite, whereas linealy up to $550^{\circ}C$ in Al-pillared montmorillonite. BET surface areas are 5~6 times larger in Al-pillared montmorillonite ($192 \m^2$/g) than Camontmorillonite. Ca-montmorilonite shows high selectivity for $Na^{+}$ /, whereas Al-pillared montmorillonite for $Ca^{2+}$ . The former shows decreasing d(001) spacing with increasing substitution of $Na^{+}$ and irregular interstratified structure at high substitution of $Ca^{2+}$ /, whereas the latter shows linear decreasing pattern in d(001) spacing with increasing $Ca^{ 2+}$.

PLAQUE ADHESION ON THE SURFACES OF VARIOUS COMPOSITE RESIN (수종 복합레진에 대한 치태 부착도 비교)

  • Kim, Young-Jong;Kim, Shin;Jeong, Tae-Sung
    • Journal of the korean academy of Pediatric Dentistry
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    • v.31 no.4
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    • pp.547-554
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    • 2004
  • The surface characteristics of restoration such as surface roughness and droplet contact angle are important part for the process of bacterial adhesion. The purpose of this study is to compare plaque adhesion by measuring roughness, droplet contact angle, and amount of accumulated plaque on the surfaces of composite resins. Four kinds of composite resins, Z-100(Z1), Durafil(DF), Filtek supreme(FS), Clearfil AP X(CA) were used. Ten samples were divided into unpolished and polished group. Surface roughnesses and droplet contact angles were measured by profilometer and goniometer. Plaque weight gains are measured. The results were as follows: 1. The experimental group were rougher than the control group. Surface roughnesses were decreased in the following order; (Z1, DF, CA)>FS in the control group, and CA>Z1>(FS, DF) in the experimental group(P<0.05). 2 The control group showed larger contact angle than the experimental group. Contact angles were decreased in the following order; CA>(FS, DF, Z1) in the control group, and (CA, DF)>(FS, Z1) in the experimental group(P<0.05). 3. The experimental group showed more much plaque than the control group. The amounts of plaque accumulation in vitro were decreased in the following order; Z1>(DF, FS)>CA in the control group, and Z1>FS>(CA, DF) in the experimental group. The latter showed more much plaque than the former(P<0.05). 4. There were stronger correlation between plaque deposition and contact angle (P<0.05) than that of plaque deposition and surface roughness.

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Surface dissolution of Hydroxyapatite Biomaterials with Ca/P Ratio (Ca/P 비에 따른 수산화아파타이트 생체재료의 표면용해 특성)

  • Seo, Dong-Seok;Kim, Hwan;Lee, Jong-Kook
    • Journal of the Korean Ceramic Society
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    • v.41 no.1
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    • pp.45-50
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    • 2004
  • Hydroxyapatite (HA) ceramics with the Ca/P ratios of 1.62, 1.67 and 1.72 were prepared and their dissolution behaviors in distilled water at $37^{\circ}C$ were investigated. It appeared that surface dissolution of the ceramics was initiated from grain boundaries after 3 days of immersion in water. Following 10 days of immersion, microstructural disintergration of HA was severs for non-stoichiometric compounds, I.e Ca/P ratios of 1.62 and 1.72. Notably, a micron-sized circular cavity similar to lacunae, which can be generally formed in osteoclastic resorption process, was observed.

Effects of Supplementation of Fat Sources, Ca and Mg on In Vitro Fermentation and the Performance of Finishing Hanwoo Bulls (지방의 공급형태와 Ca 및 Mg의 첨가가 In Vitro 발효 및 비육후기 한우의 성장성적에 미치는 영향)

  • Lee, H.G.;Lee, D.H.;Choi, N.J.;Lee, S.R.;Choi, Y.J.;Maeng, W.J.
    • Journal of Animal Science and Technology
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    • v.46 no.4
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    • pp.613-624
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    • 2004
  • This study was aimed at investigating the effect of fat supplementation with divalent ions such as MgO and $CaCl_2$ on 1) in vitro ruminal fermentation characteristics and insoluble fatty acid formation, and on 2) animal performance in finishing Hanwoo bulls. In in vitro trial, five different types of diets based on supplementation sources of fat and divalent ions, i.e. T=basal diet+4% tallow, T-Ca=T+0.5% $CaCl_2$, T-Mg=TA+0.5% MgO, T-MgCa = T +0.5% $CaCl_2$+0.5% MgO, T-caS =4% Ca salt tallow, were tested. Higher pH values were observed at 6 hr incubation(P<0.01) while higher amount of VFA were produced in diets 4 and 5 at 12 hr incubation(P<0.05). Nutrients(DM, OM, Crude protein and NDF) degradation tended to increase in divalent ions or Ca-salts treated tallow treatments compared with tallow treatment after 12 h. The amount of insoluble fatty acid increased by adding MgO or $CaCl_2$ to tallow or Ca soap tallow during incubation(P<0.05). In in vivo trial, thirty finishing Hanwoo(average BW 460kg) were divided into three groups based on fat sources and divalent ions, i.e. Control(EE 2.40), T-MgCa = control + tallow + $CaCl_2$ + MgO, T-CaS = control + Ca soap tallow (EE 5.30%). After feeding each diet for 80 days, average daily weight gain showed 0.89, 1.02, 1.17kg in diets 1, 2 and 3, respectively. The highest feed efficiency was observed(0.12) in diet 2 group, followed by diet 3 (0.10) and 1 groups(0.08; P < 0.05). In conclusion, the present results could be sununarized that the performance of Hanwoo bulls was improved by tallow with divalent ions without any negative effect on rumen fermentation.

Role of $Ca^{2+}$ in the Stimulation of Glucose Transport by Insulin in Adipocytes

  • Chang, Sung-Hoe;Jang, Yeon-Jin;Park, Kun-Koo;Kim, Ghi-Su;Ryu, Hee-Jeong;Park, Chun-Sik
    • The Korean Journal of Physiology and Pharmacology
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    • v.3 no.3
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    • pp.357-364
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    • 1999
  • We investigated the role of $Ca^{2+}$ and protein kinases/phosphatases in the stimulatory effect of insulin on glucose transport. In isolated rat adipocytes, the simple omission of $CaCl_2$ from the incubation medium significantly reduced, but did not abolish, insulin-stimulated 2-deoxy glucose (2-DG) uptake. Pre-loading adipocytes with intracellular $Ca^{2+}$ chelator, 5,5'-dimethyl bis (o-aminophenoxy)ethane-N,N,N'N' tetraacetic acetoxymethyl ester (5,5'-dimethyl BAPTA/AM) completely blocked the stimulation. Insulin raised intracellular $Ca^{2+}$ concentration $([Ca^{2+}]_i)$ about 1.7 times the basal level of $72{\pm}5$ nM, and 5,5'-dimethyl BAPTA/AM kept it constant at the basal level. This correlation between insulin-induced increases in 2-DG uptake and $[Ca^{2+}]_i$ indicates that the elevation of $[Ca^{2+}]_i$ may be prerequisite for the stimulation of glucose transport. Studies with inhibitors (ML-9, KN-62, cyclosporin A) of $Ca^{2+}-calmodulin$ dependent protein kinases/phosphatases also indicate an involvement of intracellular $Ca^{2+}.$ Additional studies with okadaic acid and calyculin A, protein phosphatase-1 (PP-1) and 2A (PP-2A) inhibitors, indicate an involvement of PP-1 in insulin action on 2-DG uptake. These results indicate an involvement of $Ca^{2+}-dependent$ signaling pathway in insulin action on glucose transport.

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Study on the Free CaO Analysis of Coal Ash in the Domestic Circulating Fluidized Bed Combustion using ethylene glycol method (에틸렌글리콜법을 활용한 국내 순환유동층보일러 석탄회의 Free CaO 평가 연구)

  • Seo, Jun-Hyung;Baek, Chul-Seoung;Kim, Young-Jin;Choi, Moon-Kwan;Cho, Kye-Hong;Ahn, Ji-Whan
    • Journal of Energy Engineering
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    • v.26 no.1
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    • pp.1-8
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    • 2017
  • This study was carried out to physicochemical properties and free CaO contents of coal ash in domestic circulating fludized bed combustion power plant using ethylene glycol method. Results of physicochemical properties, there are many differences in CaO contents for the region position in CFBC plant. The reason, It is considered to be reflected that regulation of exhaust concentration for oxides of sulfur and other operation characteristics of region position in CFBC plant. Free CaO contents are 1.96 ~ 10.78% of fly ash and 0.07~4.24 % of bottom ash, fly ash is higher than in the bottom ash. besides CaO contents of raw materials, particle distribution have a lot of influence Free CaO contents.

The Influence of Sodium on the Calcium Release from Cardiac Mitochondria (심장근(心臟筋) mithochondria의 $Ca^{++}$유리에 대한 $Na^+$의 영향(影響))

  • Kim, Yong-Sik;Park, Chan-Woong;Kim, Myung-Suk
    • The Korean Journal of Pharmacology
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    • v.17 no.1 s.28
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    • pp.1-8
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    • 1981
  • The $Na^+$-induced calcium release and the effect of sodium on the transmitochondrial calcium flux were observed in mitochondria isolated from pig ventricular myocardium by Milipore filtration technique using radioisotope $^{45}Ca$. The release of calcium from cardiac mitochondria was induced by small amount of sodium, and was promoted by increasing sodium concentration in the incubation medium. The extent of the $Na^+$-induced calcium release was much greater in the absence of extramitochondrial calcium than in the presence of calcium. At steady state of calcium binding on the mitochondrial membrane unidirectional calcium influx was inhibited by sodium and unidirectional calcium efflux was increased., From the above results, it was suggested that calcium might be released from cardiac mitochondria in exchange with sodium through the mediation of the postulated '$Na^+/Ca^{++}$ exchange' mechanism.

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Effect of Ca Implantation on the Sintering and Crack Healing Behavior of High Purity Al2O3 Using Micro-lithographic Technique - I. Formation of Crack-like Pore and Its Morphological Evolution (Ion Implantation으로 Ca를 첨가한 단결정 Al2O3의 Crack-like Pore의 Healing 거동 - I. Crack-like Pore의 형성과 Morphological Evolution)

  • 김배연
    • Journal of the Korean Ceramic Society
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    • v.34 no.8
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    • pp.834-842
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    • 1997
  • Controlled Ca impurity implanted inner crack-like pore in the high purity alumina single crystal, sapphire, had been created by micro-fabrication technique, which includes ion implantation, photo-lithography, Ar ion milling, and hot press technique. The morphological change and the healing of cracklike pore in Ca doped high purity single crystal alumina, sapphire, during high temperature heat treatment in vacuum were observed using optical microscopy. The dot-like surface roughening was developed and hexagon like crystal appeared on inner surface of crack-like pore after heat treatment. Bar type crystals, probably CaO.6Al2O3, were observed on the inner surface after 1 hour heat treatment at 1, 50$0^{\circ}C$, but this bar type crystal disappeared after 1 hour heat treatment at 1, $600^{\circ}C$. This disappearance means that there should be a little increase of Ca solubility limit to alumina at this temperatures.

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Microsatellite marker distribution pattern in rock bream iridovirus (RBIV) infected rock bream, Oplegnathus fasciatus

  • Jung, Myung-Hwa;Jung, Sung-Ju
    • Journal of fish pathology
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    • v.34 no.1
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    • pp.9-15
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    • 2021
  • Rock bream (Oplegnathus fasciatus) is a highly valued aquaculture species in Korea. However, the aquaculture industry suffers huge economic losses due to rock bream iridovirus (RBIV) infection in summer. The objective of this study was to determine genetic diversity and relationships of DNAs isolated from two groups of rock bream after RBIV infection using five microsatellite (MS) markers. The first group of fish died early and the second group of fish died later after RBIV infection. In this experiment, 90 fish (5.1±1.0 cm and 4.1±1.3 g) were injected with 50 μl of RBIV (104 TCID50/ml) and maintained at 26℃ for 15 days. Genomic DNAs were extracted from fins of 20 fish that died earlier or later after RBIV infection. These DNAs were subjected to genotyping using five MS markers (CA-03, CA3-05, CA3-06, CA-10, and CA3-36). Of these markers, CA3-05 (early death group), CA3-06 (late death group), and CA3-36 (both early and late death groups) showed different alleles distribution rates. In-depth studies are needed to provide valuable information for selecting RBIV-resistant fish. In conclusion, microsatellite marker distribution pattern differences between early- and late- death groups of rock bream after RBIV infection showing different RBIV susceptibilities were determined using MS markers and genotyping. Results of this study suggest that MS markers could be used to facilitate the selection of RBIV resistant rock bream.

Effect of γ-PGA (Poly-γ-Glutamic Acid) Supplement on Calcium Absorption and Bone Metabolism in Rats (γ-PGA(Poly-γ-glutamic acid) 보충이 흰쥐의 칼슘 흡수율 및 골대사에 미치는 영향)

  • Lee, Min-Sook;Kang, Jung-Il;Kim, Hyun-Su
    • Journal of the Korean Society of Food Science and Nutrition
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    • v.35 no.3
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    • pp.255-261
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    • 2006
  • This study was Conducted to investigate the effect of ${\gamma}-PGA\;({\gamma}-poly\;glutamic\;acid)$ on Ca absorption and bone metabolism in rats. Weaned 4-week old male rats were fed Ca-deficient diets for 3 weeks after the adjustment period. Rats were divided into 6 groups and were fed experimental diets for four weeks. Experimental groups were basal (Ca deficient), control (Ca diet: Ca 0.45%), CP1(Ca 0.45%+casein phosphopeptide 1%), PG1(Ca 0.45%+gamma poly glutamic acid 1%), CPG (Ca 0.45%+casein phosphopeptide 1%+gamma poly glutamic acid 1%) and PG3(Ca 0.45%+gamma poly glutamic acid 3%). Though daily Ca intake and food intake of experimental groups showed no significant difference that of control group. The values of fecal Ca excretion and urinary Ca excretion in groups fed ${\gamma}-PGA$ were significantly lower than that in tile control group. The values of Ca absorption in groups fed ${\gamma}-PGA$ were significantly higher than that in the control group. The levels of femur Ca in ${\gamma}-PGA$ supplemented group were significantly increased compared to the control group. Also, breaking force of femur in ${\gamma}-PGA$ supplemented group showed about 40% increase compared to the control group. These results show that ${\gamma}-PGA$ supplement could be helpful to increase Ca absorption as well as to intensify the femur strength and to increase the Ca content of femur in rats.