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Study on the Free CaO Analysis of Coal Ash in the Domestic Circulating Fluidized Bed Combustion using ethylene glycol method

에틸렌글리콜법을 활용한 국내 순환유동층보일러 석탄회의 Free CaO 평가 연구

  • Seo, Jun-Hyung (Department of Research and Development, Korea Institute of Limestone and Advanced Materials) ;
  • Baek, Chul-Seoung (Department of Research and Development, Korea Institute of Limestone and Advanced Materials) ;
  • Kim, Young-Jin (Department of Research and Development, Korea Institute of Limestone and Advanced Materials) ;
  • Choi, Moon-Kwan (Department of Research and Development, Korea Institute of Limestone and Advanced Materials) ;
  • Cho, Kye-Hong (Department of Research and Development, Korea Institute of Limestone and Advanced Materials) ;
  • Ahn, Ji-Whan (Carbon Resource Recycling Appropriate Technology Center, Korea Institute of Geoscience and Mineral Resources)
  • 서준형 (한국석회석신소재연구소 연구개발실) ;
  • 백철승 (한국석회석신소재연구소 연구개발실) ;
  • 김영진 (한국석회석신소재연구소 연구개발실) ;
  • 최문관 (한국석회석신소재연구소 연구개발실) ;
  • 조계홍 (한국석회석신소재연구소 연구개발실) ;
  • 안지환 (한국지질자원연구원 탄소광물화적정기술사업단)
  • Received : 2017.02.01
  • Accepted : 2017.02.17
  • Published : 2017.03.31

Abstract

This study was carried out to physicochemical properties and free CaO contents of coal ash in domestic circulating fludized bed combustion power plant using ethylene glycol method. Results of physicochemical properties, there are many differences in CaO contents for the region position in CFBC plant. The reason, It is considered to be reflected that regulation of exhaust concentration for oxides of sulfur and other operation characteristics of region position in CFBC plant. Free CaO contents are 1.96 ~ 10.78% of fly ash and 0.07~4.24 % of bottom ash, fly ash is higher than in the bottom ash. besides CaO contents of raw materials, particle distribution have a lot of influence Free CaO contents.

에틸렌글리콜법을 활용하여 국내 순환유동층보일러형 발전소에서 발생되는 석탄회의 물리화학적 특성 및 Free CaO 평가를 수행하였다. 물리화학적 특성결과, 각 발전사마다 많은 CaO 함량 차이를 나타내었는데, 이는 황산화물 배출농도 규제 차이 및 보일러 제작사가 다른 발전소의 운전특성이 복합적으로 반영된 것으로 판단된다. Free CaO의 함량은, 비산재는 1.96 ~ 10.78 %, 바닥재는 0.07 ~ 4.24%로 비산재가 바닥재보다 높게 나타났으며, 원시료의 CaO 함량 이외에 입도 분포에 따라서도 크게 변화되는 것으로 확인되었다.

Keywords

References

  1. Park, S. U. et al., 2015, Evaluation of Some Rare Metals and Rare Earth Metals Contained in Coal Ash of Coal-fired Power Plants in Korea, Journal of Korean Institute of Resources Recycling, Vol. 24, No. 4, pp. 67-75 https://doi.org/10.7844/kirr.2015.24.4.67
  2. Do, J. N. et al., 2014, Case of construction technology using coal ash (thermal power plant byproducts), Journal of the Korean Geotechnical Society, Vol. 30, No. 2, pp. 21-26 https://doi.org/10.7843/kgs.2014.30.4.21
  3. Jeong, E. D. and Moon, S. J., 2010 : Co-Combustion Characteristics of Mixed Coal with Anthracite and Bituminous in a Circulating Fluidized Bed Boiler, The Plant Journal, Vol. 6, No. 2, pp. 70-77
  4. Choi, S. W. et al., 2007, The present situation of production and utilization of steel slag in Korea and other countries, Journal of the Korea Concrete Institute, Vol. 19, pp. 28-33
  5. Ahn, N. S. et al., 2011, Sulfate Attack According to the Quantity of Composition of Cement and Mineral Admixtures, Journal of Korea Institute Building Construction, Vol. 11, No. 6, pp. 547-556 https://doi.org/10.5345/JKIBC.2011.11.6.547
  6. Kim, K. H. et al., 2007, The Present Situation of Production and It's Utilization of Electronic arc Furnace Oxidizing Slag in Korea and Other Countries, Journal of the Korea Concrete Institute, Vol. 19, No. 6, pp. 51-57
  7. Chun, B. S. and Yeoh, Y. H., 2000, A Study on the Recycling of Coal Ash as Structural Backfill Materials, Journal of Ocean Engineering and Technology, Vol. 14, No. 1, pp. 74-79
  8. Choi, S. J. and Kim, M. H., 2009, A Study on the Durabilities of High Volume Coal Ash Concrete by the Kinds of Coal Ash, Journal of the Korea Institute of Building Construction, Vol. 9, No. 3, pp. 73-78 https://doi.org/10.5345/JKIC.2009.9.3.073
  9. Yoon, Y. W. et al., 2009, Evaluation of Static and Dynamic Characteristic of Coal Ashes, Journal of the Korean Geoenvironmental Society, Vol. 10, No. 3, pp. 5-12
  10. Sim, J. S, 2012, Hydration Characteristics of Coal-Fly Ash Containing High CaO Compound, Journal of the Korean Ceramic Society, Vol. 49, No. 2, pp. 185-190 https://doi.org/10.4191/kcers.2012.49.2.185
  11. Lee, J. J. and Park, J. L., 2001, Manufacture of Precipitated Calcium Carbonate from Pungchon Limestone, Research report the Institute of Industrial Technology, Vol. 21, No. A, pp 251-256
  12. Hong, S. R. et al., 2011, Characteristics of Recycled Fine Aggregate by Sodium Carbonated Water, Korean Recycled Construction Resource Institute, Vol. 6, No. 2, pp. 97-102
  13. Choi, J. S. and Park, C. H., 1999, Study on Whiteness Improvement of Precipitated Calcium Carbonate Made from Jeongseon Limestone in Korea, Journal of the Korean Institute of Mineral and Energy Resources Engineers, Vol. 36, No. 6, pp. 456-462
  14. Lee, H. G. and Lee, C. T., 1995, Recovery of Fe Fraction from Coal Fly Ash by Using High Gradient Magnetic Separator, Journal of Industrial and Engineering Chemistry, Vol. 6, No. 4, pp. 601-609
  15. Jeong, J. Y. et al., 2007, The Physical Properties of Mortar used Bottom Ash, Journal of the Korea Concrete Institute, Vol. 21, pp. 813-816.
  16. Jang, Y. C. et al., 2009, Physico-chemical Characteristics and Environmental Assessment of Coal Bottom Ash from Coal-fired Power Plant for Beneficial Use, Journal of Korea Solid Wastes Engineering Society, Vol. 26, pp. 680-688
  17. Yoo, S. W. et al., 2013, Evaluation of Domestic CCPs(Coal Combustion Products) Quality by API Test Method, Journal of the Korean Recycled Construction Resources Institute, Vol. 1, pp. 49-57 https://doi.org/10.14190/JRCR.2013.1.1.049
  18. Hwang. Y., 2012, Effect of Additives on the Compressive Strength of Geopolymerized Fly Ash, Korean Journal of Materials Research, Vol. 22, pp. 494-498 https://doi.org/10.3740/MRSK.2012.22.9.494
  19. Kim, Y. T. et al., 2012, Characteristics of geopolymer based on recycling resources, Journal of the Korean Crystal Growth and Crystal Technology, Vol. 22, pp. 152-157. https://doi.org/10.6111/JKCGCT.2012.22.3.152
  20. Lee. S. J. et al., 2013, Developing and Assessing Geopolymers from Seochun Pond Ash with a Range of Compositional Ratios, Journal of the Korean Ceramic Society, Vol. 50, pp. 134-141 https://doi.org/10.4191/kcers.2013.50.2.134
  21. Lee. H. S. et al., 2017, Quantitative evaluation of free CaO in electric furnace slag using the ethylene glycol method, Construction and Building Materials, Vol. 131, pp. 676-681 https://doi.org/10.1016/j.conbuildmat.2016.11.047
  22. Lim, H. S and Lee. H. S., 2014, An Experimental Study on the Free-CaO Quantitative Analysis in the Aging Period of the Electric Arc Furnace Slag, Korea Concrete Institute, pp. 349-350.
  23. Choe, H. B. et al., 2014, A Study on the Content Evaluation of Free-CaO in Electric Arc Furnace Oxidizing Slag and Reduction Slag in accordance with its Collection Location at Openair Storage Yard, Journal of the Architectural Institute of Korea, Vol. 34, No. 1, pp. 419-420.
  24. Moon. J. W., 1993, A Study on the Development of the Insulated Mortar that be used of Artificial Lightweight Fine Aggregate made from Fly Ash, Proceeding of Annual Conference of the Architectural Institute of Korea, 13(2), pp. 611-616
  25. Kim. Y. T, Kim, H. J, and Jang, C. S., 2012, Characteristics of geopolymer based on recycling resources, Journal of the Korean Crystal Growth and Crystal Technology, Vol. 22, pp. 152-157 https://doi.org/10.6111/JKCGCT.2012.22.3.152
  26. Noh, D, S. and Park, K, S, 2003, A Study on Measuring the SOx Abatement Cost in Thermal Power Plant, Korea Energy Economics Institute Research Report, pp. 1-84
  27. Construction Material Doctors Group, Development of commercialization and manufacturing system for zero emission binder using recycling resource, Korea Agency for Infrastructure Technology Advancement, Technological innovation promotion study project (2nd report).
  28. Park. J. W., 2004 : A Study on the use of Coal Ash, Japan magnetic separation research paper

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