• Title/Summary/Keyword: Analytical Techniques

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Modelling and experimental investigations on stepped beam with cavity for energy harvesting

  • Reddya, A. Rami;Umapathy, M.;Ezhilarasib, D.;Uma, G.
    • Smart Structures and Systems
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    • v.16 no.4
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    • pp.623-640
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    • 2015
  • This paper presents techniques to harvest higher voltage from piezoelectric cantilever energy harvester by structural alteration. Three different energy harvesting structures are considered namely, stepped cantilever beam, stepped cantilever beam with rectangular and trapezoidal cavity. The analytical model of three energy harvesting structures are developed using Euler-Bernoulli beam theory. The thickness, position of the rectangular cavity and the taper angle of the trapezoidal cavity is found to shift the neutral axis away from the surface of the piezoelectric element which in turn increases the generated voltage. The performance of the energy harvesters is evaluated experimentally and is compared with regular piezoelectric cantilever energy harvester. The analytical and experimental investigations reveal that, the proposed energy harvesting structures generate higher output voltage as compared to the regular piezoelectric cantilever energy harvesting structure. This work suggests that through simple structural modifications higher energy can be harvested from the widely reported piezoelectric cantilever energy harvester.

Chip-based microcapillary HPLC for proteomic analysis (칩 기반 미세관 HPLC를 이용한 단백체 분석)

  • Kim, Bo-Ra;Park, Jong-Moon;Lee, Hoo-Keun
    • Analytical Science and Technology
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    • v.24 no.6
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    • pp.407-413
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    • 2011
  • Over the last decade sophisticated and powerful microcapillary HPLC for proteomic analysis have been developed increasingly and interfaced with high resolution tandem mass spectrometers. Separation prior to mass spectrometric (MS) analysis removes impurities, and concentrates analytes in the narrow elution peaks, resulting in increased sensitivity of MS analysis. This review will focus on the recent advances of on-line highperformance separation techniques based on microfluidic chips for complex proteomic analysis.

Comparison of chemical and photochemical generation of hydrides in Se speciation study with HPLC-HG-ICPMS (HPLC-ICPMS를 이용한 셀레늄 화학종의 연구에서 화학적 및 광화학적 수소화물 발생법의 비교)

  • Ji, Hana;Pak, Yong-Nam
    • Analytical Science and Technology
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    • v.25 no.6
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    • pp.339-344
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    • 2012
  • In this research, hydride generation in HPLC-ICPMS for the selenium speciation was investigated. Chemical and photochemical vapor generation techniques were compared for the effective generation of selenium vapour. $HBr/KBrO_3$ was used for the chemical reduction and a UV lamp was used for the photochemical reduction. It was found out that the photochemical reduction was more effective than the chemical reduction in all of selenium species studied. The optimum conditions for the generation of vapour are 0.4% KI, 2.5% $NaBH_4$, and 1.0 M HCl. The enhancement factor using a photochemical hydride generation was from 6.3 to 16.7 times for inorganic and organic selenium species.

Basics of Ion Mobility Mass Spectrometry

  • Lee, Jong Wha
    • Mass Spectrometry Letters
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    • v.8 no.4
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    • pp.79-89
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    • 2017
  • Ion mobility mass spectrometry (IM-MS) combines the advantages of ion mobility spectrometry (IMS) and MS for effective gas-phase ion analysis. Separation of ions based on their mobilities prior to MS can be performed without a great loss in other analytical figures of merit, and the extra dimension of analysis offered by IM can be beneficial for isomer and complex sample analyses. In this review, basic principles of IMS and IM-MS are described in addition to an introduction to various IMS techniques and commercial IM-MS instruments. The nature of collision cross-section (${\Omega}_D$), an important parameter determining the transport properties of ions in IMS, is also explained in detail.

Rainfall-Runoff Simulation by Analytical Estimation of Soil Parameters (토양 매개변수의 해석적 산정을 통한 강우-유출 모의)

  • Jeong, Woo-Chang;Hwang, Ma-Ha;Song, Jai-Woo
    • Proceedings of the Korea Water Resources Association Conference
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    • 2006.05a
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    • pp.1870-1875
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    • 2006
  • This study was carried out to investigate the applicability of SAC-SMA model with parameters which were derived from analytical relationships proposed by Koren etc. (2000), with various data of soil properties in a basin. The studied basin is Yongdam dam basin and the daily runoff with 2003-year hydrological data was simulated. Simulated runoff results were compared with those measured at three check points(Chuchun, Donhyang and Yongdam) and analyzed through the statistical techniques such as VE(Volume Error), RMSE(Root Mean Squared Error) and CORR(Correlation). As a result of analyses, the good agreement was obtained between simulated and measured results.

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Emerging Data Management Tools and Their Implications for Decision Support

  • Eorm, Sean B.;Novikova, Elena;Yoo, Sangjin
    • Journal of Korea Society of Industrial Information Systems
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    • v.2 no.2
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    • pp.189-207
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    • 1997
  • Recently, we have witnessed a host of emerging tools in the management support systems (MSS) area including the data warehouse/multidimensinal databases (MDDB), data mining, on-line analytical processing (OLAP), intelligent agents, World Wide Web(WWW) technologies, the Internet, and corporate intranets. These tools are reshaping MSS developments in organizations. This article reviews a set of emerging data management technologies in the knowledge discovery in databases(KDD) process and analyzes their implications for decision support. Furthermore, today's MSS are equipped with a plethora of AI techniques (artifical neural networks, and genetic algorithms, etc) fuzzy sets, modeling by example , geographical information system(GIS), logic modeling, and visual interactive modeling (VIM) , All these developments suggest that we are shifting the corporate decision making paradigm form information-driven decision making in the1980s to knowledge-driven decision making in the 1990s.

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ANALYTICAL TECHNIQUES FOR SYSTEM OF TIME FRACTIONAL NONLINEAR DIFFERENTIAL EQUATIONS

  • Choi, Junesang;Kumar, Devendra;Singh, Jagdev;Swroop, Ram
    • Journal of the Korean Mathematical Society
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    • v.54 no.4
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    • pp.1209-1229
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    • 2017
  • We coupled the so-called Sumudu transform with the homotopy perturbation method (HPM) and the homotopy analysis method (HAM), which are called homotopy perturbation Sumudu transform method (HPSTM) and homotopy analysis Sumudu transform method (HASTM), respectively. Then we show how HPSTM and HASTM are more convenient than HPM and HAM by conducting a comparative analytical study for a system of time fractional nonlinear differential equations. A Maple package is also used to enhance the clarity of the involved numerical simulations.

The Selection of Sample Injection Modes and Its Effect on the Calibration Bias in S Gas Detection by Gas Chromatography (GC의 주입방식 차에 따른 고농도 악취황 성분의 검량오차 연구 : 주입부피의 고정방식 대비 주입농도의 고정방식 간 비교연구)

  • Kim Ki-Hyun;Choi YJ
    • Journal of Korean Society for Atmospheric Environment
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    • v.21 no.2
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    • pp.269-274
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    • 2005
  • In this work, analytical bias arising from the gas chromatographic determination of sulfur compounds was evaluated by the application of direct loop injection method to the GC/PFPD detection of four sulfur compounds including H$_{2}$S, CH$_{3}$SH, DMS, and DMDS. For the proper evaluation of analytical uncertainties involved in GC calibration, we employed two comparative techniques of calibration at fxed concentration injection (CFCI) vs calibration at fixed volume injection (CFVI) method. The results of our study indicate that CFCI method exhibits very poor sensitivity due to the matrix effect with varying injection volumes. On the other hand, as CFVI method overcomes such limitation, it can be used to obtain very accurate quantification of S compounds at their high concentration levels above a few to a few tens ppb.

Characterization of Ferrous Metal Artifacts by Microstructure Observation (미세구조 관찰에 의한 철제금속유물의 특성화)

  • Huh, Wooyoung;Lee, Chul
    • Analytical Science and Technology
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    • v.11 no.4
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    • pp.316-320
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    • 1998
  • An image analysis was used for the interpretation of microstructures of ferrous metal artifacts. For the purposes, various microstructural features such as average grain size, phase area, shape factor, and composition of the inclusions, were parameterized for the information about manufacturing techniques such as casting, heating and tempering. The carbon content was determined through the evaluation of the amount of pearlite phase. As the amount of pearlite phase increased the shape factor also increased. Grain size was relatively smaller in trans-section than in cross-section. The manufacturing direction was trans-sectional because the orientation of inclusions was elongated lengthwise. All inclusions was of silicate groups and the manufacturing temperature was estimated up to $1450^{\circ}C$.

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Evaluation of seismic performance factors for steel DIAGRID structural system design

  • Lee, Dongkyu;Shin, Soomi;Ju, Youngkyu
    • Earthquakes and Structures
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    • v.10 no.4
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    • pp.735-755
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    • 2016
  • This article presents a proposed analytical methodology to determine seismic force-resisting system R-values for steel diagrid framed systems. As current model building codes do not explicitly address the seismic design performance factors for this new and emerging structural system, the purpose of this study is to provide a sound and reliable basis for defining such seismic design parameters. An approach and methodology for the reliable determination of seismic performance factors for use in the design of steel diagrid framed structural systems is proposed. The recommended methodology is based on current state-of-the-art and state-of-the practice methods including structural nonlinear dynamic analysis techniques, testing data requirements, building code design procedures and earthquake ground motion characterization. In determining appropriate seismic performance factors (R, ${\Omega}_O$, $C_d$) for new archetypical building structural systems, the methodology defines acceptably low values of probability against collapse under maximum considered earthquake ground shaking.