• 제목/요약/키워드: Amorphous Structure

검색결과 979건 처리시간 0.027초

Mechanical Alloying Effect in Immiscible Cu-Based Alloy Systems.

  • Lee, Chung-Hyo;Lee, Seong-Hee;Kim, Ji-Soon;Kwon, Young-Soon
    • 한국분말재료학회지
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    • 제10권3호
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    • pp.164-167
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    • 2003
  • The mechanical alloying effect has been studied on the three Cu-based alloy systems with a positive heat of mixing. The extended bcc solid solution has been formed in the Cu-V system and an amorphous phase in the Cu-Ta system. However, it is round that a mixture of nanocrystalline Cu and Mo Is formed in the Cu-Mo system. The neutron diffraction has been employed at a main tool to characterize the detailed amorphization process. The formation of an amorphous phase in Cu-Ta system can be understood by assuming that the smaller Cu atoms preferentially enter into the bcc Ta lattice during ball milling.

Study of surface state density of hydrogenated amorphous silicon thinfilm transistors by admittance spectroscopy

  • Hsieh, Ming-Ta;Chang, Chan-Ching;Chen, Jenn-Fang;Zan, Hsiao-Wen;Yen, Kuo-Hsi;Shih, Ching-Chieh;Chen, Chih-Hsien;Lee, Yeong-Shyang;Chiu, Hsin-Chih
    • 한국정보디스플레이학회:학술대회논문집
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    • 한국정보디스플레이학회 2007년도 7th International Meeting on Information Display 제7권1호
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    • pp.904-907
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    • 2007
  • We reported a simplified circuit model to investigate the interface states and the quality of a-Si film based on a MIS structure using admittance spectroscopy. The model can be employed easily to monitor the fabrication process of thin-film transistor and to obtain the important parameters.

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기계적 합금화법으로 제조한 비정질 Ni-Ta 및 Cu-Ta 합금분말의 중성자회절에 관한 연구 (A study on neutron diffraction of amorphous Ni-Ta and Cu-Ta alloy powders prepared by mechanical alloying)

  • 이충효;이진
    • E2M - 전기 전자와 첨단 소재
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    • 제8권6호
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    • pp.715-720
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    • 1995
  • 기계적 합금화법에 의한 비정질화 과정을 Ni-Ta계 및 Cu-Ta계에 대하여 조사하였다. Ni-Ta합금계는 혼합엔탈피가 음이나, Cu-Ta계는 혼합엔탈피가 양인 열역학적으로 대조적인 합금계이다. 볼밀 중 발생하는 원자구조 변화를 중성자회절법을 이용하여 관찰하였다. 두 합금게에 있어서 기계적 합금화에 의한 비정질상이 생성되었다. 비정질 Cu-Ta합금의 local원자구조를 혼합엔탈피가 크게 음인 Ni-Ta계의 결과와 비교하였다. 그 결과, 대조적 특성을 가진 두 합금계임에도 불구하고 원자크기가 작은 Ni 및 Cu가 bcc Ta의 결정격자 속으로 우선적으로 침입함으로써 비정질화가 진행됨을 알 수 있었다.

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기계적 합금화 방법에 의한 $Nb_3Sn$합금 제조 (The synthesis of $Nb_3Sn$ alloy powders by mechanical alloying)

  • 이성만
    • 대한전기학회:학술대회논문집
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    • 대한전기학회 1996년도 추계학술대회 논문집 학회본부
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    • pp.464-467
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    • 1996
  • The microstructural evolution during mechanical alloying of Nb and Sn powders, of average composition Nb3Sn, has been investigated by X-ray diffraction(XRD) and scanning electron microscopy(SEM). Observations by SEM showed a progressive change of milling time. From the XRD studies, the structural development with milling time depends on the ball size for a given powder/ball ratio. Using a larger ball of 9.5mm diameter, the elemental powders initially alloy mechanically to form an A15 structure phase, and then amorphised with continued milling. However, in case of milling with a smaller ball of 3.968mm diameter, an amorphous phase is first formed. These results can be understood by considering the dependence of the milling energy on the ball size. The homogeneous stoichiometric $Nb_3Sn$ phase could be easily obtained by heat treatment of a supersaturated solid solution produced by MA. Heat treatment of an amorphous phase formed by MA resulted in the mixture of the $Nb_3Sn$ and $Nb_6Sn_5$ phases.

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Processing of Tin Oxide Nanoparticles by Inert Gas Condensation Method and Characterization

  • Simchi, Abdolreza;Kohi, Payam
    • 한국분말야금학회:학술대회논문집
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    • 한국분말야금학회 2006년도 Extended Abstracts of 2006 POWDER METALLURGY World Congress Part 1
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    • pp.122-123
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    • 2006
  • Tin oxide nanoparticles (n-SnO and $n-SnO_2$) were synthesized by the inert gas condensation (IGC) method under dynamic gas flow of oxygen and argon at various conditions. Transmission electron microscopy (TEM) and X-ray diffraction (XRD) method were used to analysis the size, shape and crystal structure of the produced powders. The synthesized particles were mostly amorphous and their size increased with increasing the partial pressure of oxygen in the processing chamber. The particles also became broader in size when higher oxygen pressures were applied. Low temperature annealing at $320^{\circ}C$ in air resulted to crystallization of the amorphous n-SnO particles to $SnO_2$.

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$16{\times}16$ 비정질 실리콘 볼로미터 설계 및 제작 (Design and Fabrication of the $16{\times}16$ Amorphous Silicon Microbolometer Array)

  • 강태영;임성수;곽용석;장원수;한영수;박영식
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2007년도 하계학술대회 논문집 Vol.8
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    • pp.373-374
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    • 2007
  • The amorphous silicon microbolometer array has been developed by the MEMS design and fabrication technology. Before the bolometer array for the image sensor being designed, the structure of unit cel I and 16x16 array of it was simulated, designed and fabricated. The properties of bolometer have been measured as such that the TCR and thermal time constant can be achieved -2 %/K and 1.4 msec respectively.

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RF 반응성 스퍼터링에 의한 비정질 carbon nitride 박막의 제조에 관한 연구 (A Study on carbon nitride thin films prepared by RF reactively sputtering)

  • 이철화;김병수;이상희;진윤영;이덕출;박구범
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 1999년도 추계학술대회 논문집
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    • pp.406-408
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    • 1999
  • Amorphous carbon nitride thin films were prepared on pretreated silicon(100) substrate in sputtering graphite target by activated gas phase using RF reactively sputtering. We measured the FT-IR spectrum to identify C=N(nitrile)stretching mode(2200cm$\^$-1/), C-H stretching mode(2800cm$\^$-1/), C-H bending mode, C=C stretching mode C=N(imino) mode(1680cm$\^$-1/ ), and the XPS to investigate chemical structure of surface. By the results of FT-H and XPS spectrum, We confirmed that amorphous carbon nitride films with typel (C(1s): 285.9[eV], N(1s): 398.5[ev]) and type 2(C1s): 287.5[eV, N(1s): 400.2[eV]) successfully were synthesized by RF reactively sputtering

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$300^{\circ}C$$500^{\circ}C$사이에서 산회된 304, 316 스테인리스강의 표면특성 (A Surface Study of 304 and 316 Stainless Steel Oxidized between $300^{\circ}C$ and $500^{\circ}C$)

  • 김경록;이경구;강창석;최답천;이도재
    • 한국표면공학회지
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    • 제32권1호
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    • pp.43-48
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    • 1999
  • Oxidation behavior of 304 and 316 stainless steels was studied. After solution heat treatment, specimens were polished up to 1$mu \textrm{m}$ using $Al_2O_3$ powder and then subjected to oxidation between $300^{\circ}C$ and 50$0^{\circ}C$ in dry air. TEM and EDS were used for analyzing the components and structure of oxide film. TEM analysis of oxide film revealed that thin amorphous Fe oxide ($Fe_2O_3$) was formed on the top of surface while polycrystalline (Cr, $Fe_2O_3$ was formed below the amorphous Fe oxide layer. The specimens oxidized at $500^{\circ}C$ showed that 316 stainless steel had higher oxidation resistance than 304 stainless steel. These results suggest that Mo component of 316 stainless steel suppresses the formation of Cr carbide which may result in a local Cr depleted area.

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IMPROVEMENT IN HIGH FREQUENCY MAGNETIC PROPERTIES OF THIN AMORPHOUS RIBBONS BY SURFACE OXIDATION

  • Ooae, K.;Fukunaga, H.;Kakehashi, H.;Ogasawara, H.
    • 한국자기학회지
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    • 제5권5호
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    • pp.597-600
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    • 1995
  • The effects of surface oxidation on magnetic properties were investigated at high frequencies (10k-100MHz) for $7-18\mu\textrm{m}$ thick $Co_{70}Fe_{5}Si_{15}B_{10}$ amorphous ribbons with controlled domain structure. Oxidation was accelerated by acid-treatment or anodic oxidation treatment, and the insulation layers were prepared on the surfaces of the ribbons. The acid-treatment was effective in improving permeability and magnetic loss. Although the anodic oxidation treatment was effective in both making oxide layer and thinning, the magnetic properties were not improved compared with the case of the acid-treatment.

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A CLASSIFICATION OF UNIQUELY DIFFERENT TYPES OF NUCLEAR FISSION GAS BEHAVIOR

  • HOFMAN GERARD L.;KIM YEON SOO
    • Nuclear Engineering and Technology
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    • 제37권4호
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    • pp.299-308
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    • 2005
  • The behavior of fission gas in all major types of nuclear fuel has been reviewed with an emphasis on more recently discovered aspects. It is proposed that the behavior of fission gas can be classified in a number of characteristic types that occur at a high or low operating temperature, and/or at high or low fissile burnup. The crystal structure and microstructure of the various fuels are the determinant factors in the proposed classification scheme. Three types of behavior, characterized by anisotropic $\alpha$-U, high temperature metallic $\gamma$-U, and cubic ceramics, are well-known and have been extensively studied in the literature. Less widely known are two equally typical low temperature kinds: one associated with fission induced grain refinement and the other with fission induced amorphization. Grain refinement is seen in crystalline fuel irradiated to high burnup at low temperatures, whereas breakaway swelling is observed in amorphous fuel containing sufficient excess free-volume. Amorphous fuel, however, shows stable swelling if insufficient excess free-volume is available during irradiation.