• Title/Summary/Keyword: Air-Water

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Selective Nitrate Removal Performance Analysis of Ion Exchange Resin in Shipboard Waste Washwater by Air Pollution Prevention Facility (선박용 대기오염장치 폐세정수 내 질산염의 선택적 제거를 위한 이온교환수지 공정 성능 평가)

  • Kim, Bong-Chul;Yeo, In-Seol;Park, Chan-Gyu
    • KSCE Journal of Civil and Environmental Engineering Research
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    • v.41 no.4
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    • pp.399-404
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    • 2021
  • From 1 January 2020, the limit for Sulphur in fuel oil used on board ships operating outside designated emission control areas will be reduced to 0.5 %. This regulation by international maritime organization (IMO) is able to significantly reduce the amount of Sulphur oxides (SOx) discharging from ships and should have environmental advantages and health for all over the world. To meet the regulation, in these days, wet scrubber system is being actively developed. However, this process leads to make washing wastewater. In this study, we evaluated ion exchange resin system in accordance with scrubber wastewater discharge regulation by IMO. Theoretical wastewater used as feed solution of lab scale water treatment systems. The results revealed that nitrate ion was removed selectively in spite of high TDS wash wastewater solution depending on ion exchange resin property. Moreover, it was possible to improve efficiency of the system by optimizing operating conditions.

Numerical Study on Performance of PEMFC with Block and Sub-channel of Cathode Flow Field (캐소드 유로에서 블록과 서브 채널의 고분자전해질 연료전지의 성능에 관한 전산해석 연구)

  • Jo, Seonghun;Kim, Junbom
    • Applied Chemistry for Engineering
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    • v.32 no.6
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    • pp.613-620
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    • 2021
  • A flow channel shape of PEMFC has an influence on the internal flow uniformity. If the reactant distribution in a flow path is not uniform during operation, both catalyst deactivation and mechanical damage of membrane could occur resulting in decreasing the membrane electrode assembly (MEA) durability. Numerous studies concerning flow design have been conducted to make smooth supply and uniform distribution of reactants in fuel cells. The baffle of flow path could improve fuel cell performance through the forced convection effect. A sub-channel, as an additional air flow path, could increase the reactant concentration and reduce the mass transfer loss via a smooth water discharge. In this study, computational fluid dynamics (CFD) was used to analyze the effect of blocks and sub-channels on the current density and oxygen concentration of the fuel cell. As a result, the limit current density and oxygen concentration at a rear block increased when using blocks and sub-channels in a flow channel. In particular, the current density increased significantly when the sub-channel was placed between two blocks. Also, the sub-channel position was optimized by analyzing the oxygen concentration, and the oxygen concentration was recovered at a rear block in the fuel cell.

Surface Modification of Recycled Plastic Film-Based Aggregates for Use in Concrete (폐플라스틱 복합필름 기반 콘크리트용 골재의 표면 개질)

  • Kim, Tae Hun;Lee, Jea Uk;Hong, Jin-Yong
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.9 no.3
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    • pp.295-302
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    • 2021
  • Surface modification of recycled plastic film-based aggregates is demonstrated to enhance the interaction between aggregates and cement paste. It is shown that the oxygen(O2) atmospheric pressure plasma(APP) treatment leads to a drastic increase in hydrophilicity. In case of the plasma treatment at 100W of RF power, 15/4sccm of O2/Ar flow rate and 30sec of discharging time, the water contact angle on the aggregates surface decreased from 104.5° to 44.0°. In addition, the contact angle of surface modified aggregates kept in air increased with time elapse. Improvement of hydrophilicity can be explained by the formation of new hydrophilic oxygen functional groups which is identified as C-OH, C-O-C, C=O, -COOH by X-ray photoelectron spectroscopy(XPS) analysis and Fourier-transform infrared spectroscopy(FT-IR). Therefore, it can be concluded that the plasma treatment process is an effective method to improve adhesion of the recycled plastic film-based aggregates and cement paste.

Health Risk Assessment for Residents after Exposure to Chemical Accidents: Formaldehyde (화학사고물질 노출에 따른 피해지역 주민 건강위해성평가: 폼알데하이드 사례를 중심으로)

  • Park, Sihyun;Cho, Yong-Sung;Lim, Huibeen;Park, Jihoon;Lee, Cheolmin;Hwang, Seung-Ryul;Lee, Chungsoo
    • Journal of Environmental Health Sciences
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    • v.47 no.2
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    • pp.155-165
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    • 2021
  • Objectives: Acute exposure to high concentrations of chemicals can occur when a chemical accident takes place. As such exposure can cause ongoing environmental pollution, such as in the soil and groundwater, there is a need for a tool that can assess health effects in the long term. The purpose of this study was assessing the health risks of residents living near a chemical accident site due to long-term exposure while considering the temporal concentration changes of the toxic chemicals leaked during the accident until their extinction in the environment using a multimedia environmental dynamics model. Methods: A health risk assessment was conducted on three cases of formaldehyde chemical accidents. In this study, health risk assessment was performed using a multimedia environmental dynamics model that considers the behavior of the atmosphere, soil, and water. In addition, the extinction period of formaldehyde in the environment was regarded as extinction in the environment when the concentration in the air and soil fell below the background concentration prior to the accident. The subjects of health risk assessment were classified into four groups according to age: 0-9 years old, 10-18 years old, 19-64 years old, and over 65 years old. Carcinogenic risk assessment by respiratory exposure and non-carcinogenic risk assessment by soil intake were conducted as well. Results: In the assessment of carcinogenic risk due to respiratory exposure, the excess carcinogenic risk did not exceed 1.0×10-6 in all three chemical accidents, so there was no health effect due to the formaldehyde chemical accident. As a result of the evaluation of non-carcinogenic risk due to soil intake, none of the three chemical accidents had a risk index of 1, so there was no health effect. For all three chemical accidents, the excess cancer risk and hazard index were the highest in the age group 0-9. Next, 10-18 years old, 65 years old or older, and 19-64 years old showed the highest risk. Conclusion: This study considers environmental changes after a chemical accident occurs and until the substance disappears from the environment. It also conducts a health risk assessment by reflecting the characteristics of the long-term persistence and concentration change over time. It is thought that it is of significance as a health risk assessment study reflecting the exposure characteristics of the accident substance for an actual chemical accident.

Improvement Plan of Fire-Related Laws of Disaster Prevention Facilities of Road Tunnels (도로터널 방재시설의 소방관계법령 개선방안)

  • Seo, Hyo-Seon;Whang, Young-Kwon;Lee, Seung-Chul
    • Fire Science and Engineering
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    • v.33 no.2
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    • pp.124-131
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    • 2019
  • When a fire occurs in a road tunnel, it is likely to develop into a major disaster because of its sealed structural characteristics. Because of this, a range of disaster prevention facilities should be installed, and they should show their appropriate functions in fire prevention and response. In addition, the installation of essential disaster prevention facilities is missing due to the lack of considering an extension of continuous tunnels and soundproof tunnels. For these reasons, it was judged that an amendment to the law would be necessary. Therefore, this paper reviewed the changes in domestic laws related to the disaster prevention facilities of road tunnels, and the results of the study on the parts that need to be revised in the fire-related laws through a comparative analysis between laws are as follows. First, consecutive tunnels should consider the sum of the extensions of the individual tunnels and ensure that the soundproof tunnels are included in the category of tunnels in the law. In this way, the necessary disaster prevention facilities should be installed. Second, it is necessary to secure a legal justification for installing disaster prevention facilities in tunnels. Therefore, it is essential that water mist fire extinguishing system facilities, emergency broadcasting facilities, and leading lights, which are excluded from installation in tunnels, are specified in the Fire-related laws. Third, to specify in the law that air respirators must be provided in the tunnel is necessary from the viewpoint of the field response. Accordingly, it will make a great contribution to the fire-fighting activities and the life-saving efforts by fire-fighters.

The Study of Wave, Wave-Induced Current in CHUNG-UI Beach (충의휴양소 전면 해수욕장의 파랑 및 해빈류에 관한 연구)

  • Chang, Pyong-Sang;Bae, Sung-Gyu
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.20 no.6
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    • pp.142-149
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    • 2019
  • In this study, the past erosion history and current status in the CHUNG-UI beach of Eulwang-dong, Jung-gu, Incheon-Si, South Korea were investigated and analyzed the wave with wave-induced current to investigate the causes of coastal erosion. As a result, the significant wave height ($H_{1/3}$) was in the range of 0.07~1.57 m and the mean value was 0.21 m. The maximum wave height ($H_{max}$) was in the range of 0.02-4.76m and the mean value was 0.27m. The vertical wave height and cycles were estimated through numerical model experiments of wave transformation. The 50-year frequency design wave height ranged from 0.82m to 3.75m. As a result of the experiment of wave-induced current, wave-induced current in the CHUNG-UI beach was decreased after the installation of the Detached breakwater and the Jetty. On the other hand, when the crest elevation was increased up to 5 m, there was no significant change, but when the crest elevation was increased to 8m, strong wave-induced current occurred around the submerged breakwaters due to lowered depth of water. In addition, the main erosion of the CHUNG-UI beach is due to the intensive invasion of the wave characteristics coming from the outer sea into the white sandy beach. The deformation of the wave centered on the front of the sandy beach caused additional longshore currents flowing parallel to the sandy beach and rip currents in the transverse direction, thus confirming that the longshore sediment was moved out of the front and out of the sea. The results of this study can be used as preliminary data for the recovery of the sand and the selection of efficient erosion prevention facilities.

Quantifying Climate Change Regulating Service of Forest Ecosystem - Focus on Quantifying Carbon Storage and Sequestration - (산림생태계 기후변화 조절서비스 계량화 방법 - 탄소 저장 및 흡수기능 계량화 방법을 중심으로 -)

  • Choi, Hyun-Ah;Lee, Woo-Kyun;Jeon, Seong Woo;Kim, Joon Sun;Kwak, Hanbin;Kim, Moonil;Kim, Jaeuk;Kim, Jung Teak
    • Journal of Climate Change Research
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    • v.5 no.1
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    • pp.21-36
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    • 2014
  • Forest ecosystem provides variety goods and services for human being. Unlike goods, forest ecosystem services could not be easily priced by market mechanism. This uncertainty has been caused to conflict in decision-making related forest ecosystem services. Quantification of forest ecosystem services is required to understand the importance of ecosystem services and their contribution to decision-making. As a growing concern of climate change, it is necessary to quantify and calculate carbon storage and sequestration in forest. In this study, for quantifying carbon storage and sequestration, we compared scale, output, input data availability of the models and analyzed the applicability of the models to Korea. The results of this study show that most models are applicable for quantifying carbon storage and sequestration. However, relatively few models are applicable for other regulating services (air quality regulation, flood mitigation, erosion control, water quality, etc.) of forest. This study would be helpful for quantifying regulating services of forest ecosystem research.

A experimental Feasibility of Magnetic Resonance Based Monitoring Method for Underground Environment (지하 환경 감시를 위한 자기공명 기반 모니터링 방법의 타당성 연구)

  • Ryu, Dong-Woo;Lee, Ki-Song;Kim, Eun-Hee;Yum, Byung-Woo
    • Tunnel and Underground Space
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    • v.28 no.6
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    • pp.596-608
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    • 2018
  • As urban infrastructure is aging, the possibility of accidents due to the failures or breakdowns of infrastructure increases. Especially, aging underground infrastructures like sewer pipes, waterworks, and subway have a potential to cause an urban ground sink. Urban ground sink is defined just as a local and erratic collapse occurred by underground cavity due to soil erosion or soil loss, which is separated from a sinkhole in soluble bedrock such as limestone. The conventional measurements such as differential settlement gauge, inclinometer or earth pressure gauge have a shortcoming just to provide point measurements with short coverage. Therefore, these methods are not adequate for monitoring of an erratic subsidence caused by underground cavity due to soil erosion or soil loss which occurring at unspecified time and location. Therefore, an alternative technology is required to detect a change of underground physical condition in real time. In this study, the feasibility of a novel magnetic resonance based monitoring method is investigated through laboratory tests, where the changes of path loss (S21) were measured under various testing conditions: media including air, water, and soil, resonant frequency, impedance, and distances between transmitter (TX) and receiver (RX). Theoretically, the transfer characteristic of magnetic field is known to be independent of the density of the medium. However, the results of the test showed the meaningful differences in the path loss (S21) under the different conditions of medium. And it is found that the reflection coefficient showed the more distinct differences over the testing conditions than the path loss. In particular, input reflection coefficient (S11) is more distinguishable than output reflection coefficient (S22).

Geoacoustic Model at the YSDP-105 Long-core Site in the Mid-eastern Yellow Sea (황해 중동부 해역 YSDP-105 심부코어 지점의 지음향 모델)

  • Ryang, Woo-Hun;Jin, Jae-Hwa;Hahn, Jooyoung
    • Journal of the Korean earth science society
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    • v.40 no.1
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    • pp.24-36
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    • 2019
  • In the mid-eastern Yellow Sea, glacio-eustatic sea-level fluctuations and a regional tectonic subsidence have combined to represent an aggradational stacking pattern of sedimentary units during late Pleistocene-Holocene. The accumulated sediments are divisible into two-type units of Type-A and Type-B in high-resolution air-gun seismic profiles and the deep-drilled core of YSDP-105. Type-A unit largely comprises clast-rich coarse-grained sediments of non-marine to paralic origin, whereas Type-B unit consists mostly of tidal fine-grained sediments. Based on a bottom model of the sedimentary units, this study suggested a geoacoustic model of long-coring bottom layers at the YSDP-105 drilling site of the mid-eastern Yellow Sea. The geoacoustic model of 64-m depth below the seafloor with four-layer geoacoustic units was reconstructed in continental shelf strata at 45 m in water depth. For actual modeling, the geoacoustic property values of the models were compensated to in situ depth values below the seafloor using the Hamilton modeling method. We suggest that the geoacoustic model will be used for geoacoustic and underwater acoustic experiments of mid- and low-frequency reflecting on the deep bottom layers in the mid-eastern Yellow Sea.

Dissipation and Processing Factor of Etofenprox and Fenitrothion Residue in Chinese Matrimony Vine by drying (건조에 따른 구기자 중 etofenprox와 fenitrothion의 잔류량 변화 및 가공계수)

  • Noh, Hyun Ho;Lee, Jae Yun;Park, Hyo Kyoung;Jeong, Hye Rim;Lee, Jung Woo;Jo, Seung Hyeon;Kwon, Hyeyoung;Kyung, Kee Sung
    • Korean Journal of Environmental Agriculture
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    • v.37 no.3
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    • pp.213-220
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    • 2018
  • BACKGROUND: This study was carried out to determine characteristics of residual pesticides in time-dependent manner and calculate half-lives of the residual pesticides in fresh and dried Chinese matrimony vine. In addition, processing factors were calculated based on the residual concentrations in them. METHODS AND RESULTS: The test pesticides, etofenprox and fenitrothion, were sprayed onto the Chinese matrimony vine plants at once or twice (at seven-day interval) and then samples were collected at 0 (after 3 hours), 1, 3, 5 and 7 days after the last spraying. Dried samples were prepared in hot-air drying oven at $60^{\circ}C$ for 48 hours until water content of less than 20%. Residual concentrations of etofenprox in fresh and dried samples decreased by 54.0-60.9% after 7 days of the last pesticide-application. In case of fenitrothion, the concentrations were found to have decreased by 69.2-76.5%. Processing factors of etofenprox were 2.6-3.0 for the one-time spraying and 2.5-3.0 for the two-time spraying and those of fenitrothion were found to be 1.5-22 for the one-time spraying and 1.6-2.0 for the two-time spraying. First half-lives of etofenprox and fenitrothion in fresh and dried samples ranged from 5.0 to 6.3 and from 3.4 to 4.0 days, respectively. The third half-lives were found to be 15.0-18.9 and 10.2-12.1 days, respectively. CONCLUSION: Residual concentrations of the tested pesticides in the studied crop decreased, but those in the dried samples appeared to have increased. In addition, processing factor and half life were constant regardless of spraying times.