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Dissipation and Processing Factor of Etofenprox and Fenitrothion Residue in Chinese Matrimony Vine by drying

건조에 따른 구기자 중 etofenprox와 fenitrothion의 잔류량 변화 및 가공계수

  • Noh, Hyun Ho (Department of Agro-food Safety and Crop protection, National Institute of Agricultural Science, Rural Development Administration) ;
  • Lee, Jae Yun (Research Institute, Residue Research Team, Nonghyeop Chemical) ;
  • Park, Hyo Kyoung (Department of Environmental and Biological Chemistry, College of Agriculture, Life and Environmental Sciences, Chungbuk National University) ;
  • Jeong, Hye Rim (Department of Environmental and Biological Chemistry, College of Agriculture, Life and Environmental Sciences, Chungbuk National University) ;
  • Lee, Jung Woo (Department of Environmental and Biological Chemistry, College of Agriculture, Life and Environmental Sciences, Chungbuk National University) ;
  • Jo, Seung Hyeon (Department of Environmental and Biological Chemistry, College of Agriculture, Life and Environmental Sciences, Chungbuk National University) ;
  • Kwon, Hyeyoung (Department of Agro-food Safety and Crop protection, National Institute of Agricultural Science, Rural Development Administration) ;
  • Kyung, Kee Sung (Department of Environmental and Biological Chemistry, College of Agriculture, Life and Environmental Sciences, Chungbuk National University)
  • 노현호 (농촌진흥청 국립농업과학원 농산물안전성부) ;
  • 이재윤 ((주)농협케미컬 연구소) ;
  • 박효경 (충북대학교 농업생명환경대학 환경생명화학과) ;
  • 정혜림 (충북대학교 농업생명환경대학 환경생명화학과) ;
  • 이정우 (충북대학교 농업생명환경대학 환경생명화학과) ;
  • 조승현 (충북대학교 농업생명환경대학 환경생명화학과) ;
  • 권혜영 (농촌진흥청 국립농업과학원 농산물안전성부) ;
  • 경기성 (충북대학교 농업생명환경대학 환경생명화학과)
  • Received : 2018.07.25
  • Accepted : 2018.09.27
  • Published : 2018.09.30

Abstract

BACKGROUND: This study was carried out to determine characteristics of residual pesticides in time-dependent manner and calculate half-lives of the residual pesticides in fresh and dried Chinese matrimony vine. In addition, processing factors were calculated based on the residual concentrations in them. METHODS AND RESULTS: The test pesticides, etofenprox and fenitrothion, were sprayed onto the Chinese matrimony vine plants at once or twice (at seven-day interval) and then samples were collected at 0 (after 3 hours), 1, 3, 5 and 7 days after the last spraying. Dried samples were prepared in hot-air drying oven at $60^{\circ}C$ for 48 hours until water content of less than 20%. Residual concentrations of etofenprox in fresh and dried samples decreased by 54.0-60.9% after 7 days of the last pesticide-application. In case of fenitrothion, the concentrations were found to have decreased by 69.2-76.5%. Processing factors of etofenprox were 2.6-3.0 for the one-time spraying and 2.5-3.0 for the two-time spraying and those of fenitrothion were found to be 1.5-22 for the one-time spraying and 1.6-2.0 for the two-time spraying. First half-lives of etofenprox and fenitrothion in fresh and dried samples ranged from 5.0 to 6.3 and from 3.4 to 4.0 days, respectively. The third half-lives were found to be 15.0-18.9 and 10.2-12.1 days, respectively. CONCLUSION: Residual concentrations of the tested pesticides in the studied crop decreased, but those in the dried samples appeared to have increased. In addition, processing factor and half life were constant regardless of spraying times.

Keywords

References

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