• 제목/요약/키워드: AC Corrosion

검색결과 113건 처리시간 0.025초

지하 매설 배관의 부식방지를 위한 교류유도 저감대책에 관한 연구 (Study on the Countermeasure to Induced AC Voltage for Protection to Corrosion of Underground Pipelines)

  • 김대경;배정효;이현구
    • 대한전기학회:학술대회논문집
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    • 대한전기학회 1997년도 하계학술대회 논문집 D
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    • pp.803-806
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    • 1997
  • The AC induced voltage on underground pipelines not only do harm to workers and instruments, but also cause big trouble in some case. This paper gives the mechanisms, examples, and countermeasure for the AC induced voltages which are caused by the resistive coupling between the grounding system of the 22.9kV distribution power system and the underground pipeline.

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An Investigation on the Tetrahydropyrimidine Derivatives as Acid Corrosion Inhibitors for Mild Steel

  • Chitra, S.;Gayathri, N.;Parameswari, K.
    • Corrosion Science and Technology
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    • 제8권2호
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    • pp.45-52
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    • 2009
  • The corrosive behavior of mild steel in 0.05 M to 10 M $H_2SO_4$ solutions containing different concentrations of tetrahydropyrimidine derivatives (THPM) was investigated using weight loss method, gasometric technique, electrochemical studies which include AC - impedance and potentiodynamic polarization method, atomic absorption studies and synergistic effect. The results obtained reveal that THPM derivatives is an efficient mixed type inhibitor but slightly anodic and it is more effective in reducing corrosion of mild steel in $H_2SO_4$ media. The adsorption of the inhibitor on the mild steel surface obeys the Langmuir adsorption isotherm. The thermodynamic parameters of adsorption reveal a strong interaction and spontaneous adsorption of THPM on the mild steel surface. The influence of temperature and inhibitor concentration on the corrosion of mild steel has also been investigated.

해수용 열교환기 적용을 위한 열분사 코팅의 침지부식특성 연구 (Study on the Immersion Corrosion Characteristics of Thermal Spray Coating for Sea Water Heat Exchanger)

  • 허철;조맹익;권정태;권영철
    • 한국산학기술학회논문지
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    • 제15권1호
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    • pp.32-38
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    • 2014
  • 본 연구에서는 해수용 열교환기 적용을 위한 열분사 코팅의 침지부식 특성 및 열확산율을 조사하기 위해 실험이 수행되었다. 코팅은 아연과 알루미늄을 열분사 코팅한 뒤 실리콘 및 에폭시 수지를 추가 도포한 총 8개의 시편이며 이를 $70^{\circ}C$ 3.5%w NaCl 수용액에 2주간 침지하여 침지 전후의 부식특성 변화를 관찰하였다. 코팅의 부식특성 변화를 관찰하기 위하여 AC 임피던스 측정, SEM 촬영 등을 진행하였으며 레이저 확산법을 이용하여 침지 전후의 열확산율을 측정 및 비교하였다. 침지실험 결과로부터 실리콘 및 에폭시가 추가된 코팅 시편은 표면에 블리스터가 생성되지 않았으며 이에 실러 추가 코팅에 따른 내부식성 향상효과가 있는 것으로 확인되었다.

Study of Corrosion of Brass Coated Steel Cords in the Acetonitrile Solution of Sulfenamide Derivatives by Tafel Plot and AC Impedance Measurements

  • Young Chun Ko;Byung Ho Park;Hae Jin Kim;Q Won Choi;Jongbaik Ree;Keun Ho Chung
    • Bulletin of the Korean Chemical Society
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    • 제15권2호
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    • pp.122-126
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    • 1994
  • Corrosion of brass coated steel cords in the acetonitrile solution of sulfenamide derivatives, N-Cyclohexylbenzothiazole-2-sulfenamide (CBTS), N,N'-Dicyclohexylbenzothiazole-2-sulfenamide (DCBS), N-tert-Butylbenzothiazole-2-sulfenamide (TBBS), N-tert-Amylbenzothiazole-2-sulfenamide (TABS), and N-Oxydiethylbenzothiazole-2-sulfenamide (OBTS) was investigated by potentiostatic anodic and cathodic polarization (Tafel plot), DC polarization resistance, and AC impedance measurements. The corrosion current densities and rates are 1.236 ${\mu}A /cm^2$ and 0.655 MPY for CBTS; 1.881 ${\mu}A/cm^2$ and 0.988 MPY for DCBS; 2.367 ${\mu}A/cm^2$ and 1.257 MPY for TBBS; 3.398 ${\mu}A /cm^2$ and 1.809 MPY for TABS, respectively. OBTS among derivatives under study shows the lowest corrosion density (0.546 ${\mu}A /cm^2$) and the slowest corrosion rate (0.288 MPY). Also, the charge transfer resistances and the double layer capacitances are 275.21 $k{\Omega}{\cdot}cm^2$ and 7.0 ${\mu}F{cdot}cm^{-2}$ for CBTS; 14.24 ${\mu}F{\cdot}cm^2$ and 26 ${\mu}F{\cdot}cm^{-2}$ for DCBS; 54.15 $k{\Omega}{\cdot}cm^2$ and 26 ${\mu}F{\cdot}cm^{-2}$ for TBBS; 0.96$k{\Omega}{\cdot}cm^2$ and 83 ${\mu}F{\cdot}cm^{-2}$ for TABS, respectively. The weaker the electron donating inductive effect of derivatives is and the smaller the effect of steric hindrance is, the more the corrosion of brass coated steel cords in the acetonitrile solution of sulfenamide derivatives is prevented. The above results agree with that observed in the field of tire industry.

Preparation of Novel Sorbents for Gas-phase Mercury Removal

  • Lee, Si-Hyun;Rhim, Young-Jun;Park, Young-Ok
    • Carbon letters
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    • 제3권4호
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    • pp.187-191
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    • 2002
  • In the present research, we prepared the activated carbon (AC) sorbents to remove gas-phase mercury. The mercury adsorption of virgin AC, chemically treated AC and fly ash was performed. Sulfur impregnated and sulfuric acid impregnated ACs were used as the chemically treated ACs. A simulated flue gas was made of SOx, NOx and mercury vapor in nitrogen balance. A reduced mercury adsorption capacity was obtained with the simulated gas as compared with that containing only mercury vapor in nitrogen. With the simulated gas, the sulfuric acid treated AC showed the highest performance, but it might have the problem of corrosion due to the emission of sulfuric acid. It was also found that the high sulfur impregnated AC also released a portion of sulfur at $140^{\circ}C$. Thus, it was concluded that the low sulfur impregnated AC was suitable for the treatment of flue gas in terms of stability and efficiency.

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Effect of the Amplitude in Ultrasonic Nano-crystalline Surface Modification on the Corrosion Properties of Alloy 600

  • Kim, Ki Tae;Kim, Young Sik
    • Corrosion Science and Technology
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    • 제18권5호
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    • pp.196-205
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    • 2019
  • Surface modification techniques are known to improve SCC by adding large compressive residual stresses to metal surfaces. This surface modification technology is attracting attention because it is an economical and practical technology compared to the maintenance method of existing nuclear power plants. Surface modification techniques include laser, water jet and ultrasonic peening, pinning and ultrasonic Nano-crystal surface modification (UNSM). The focus of this study was on the effect of ultrasonic amplitude in UNSM treatment on the corrosion properties of Alloy 600. A microstructure analysis was conducted using an optical microscope (OM), scanning electron microscope (SEM) and electron backscattering diffraction (EBSD). A cyclic polarization test and AC-impedance measurement were both used to analyze the corrosion properties. UNSM treatment influences the corrosion resistance of Alloy 600 depending on its amplitude. Below the critical amplitude value, the pitting corrosion properties are improved by grain refinement and compressive residual stress, but above the critical amplitude value, crevices are formed by the formation of overlapped waves. These crevices act as corrosion initiators, reducing pitting corrosion resistance.

Corrosion Mechanisms of New Wrought Mg-Zn Based Alloys Alloying with Si, Ca and Ag

  • Ben-Hamu, G.;Eliezer, D.;Shin, K.S.;Wagner, L.
    • Corrosion Science and Technology
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    • 제7권3호
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    • pp.152-157
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    • 2008
  • New wrought magnesium alloys have increasingly been developed in recent years for the automotive industry due to their high potential as structural materials for low density and high strength/weight ratio demands. However, their poor mechanical properties and low corrosion resistance have led to a search for new kinds of magnesium alloys with better strength, ductility, and high corrosion resistance. The main objective of this research is to investigate the corrosion behaviour of new magnesium alloys: Mg-Zn-Ag (ZQ), Mg-Zn-Mn-Si (ZSM) and Mg-Zn-Mn-Si-Ca (ZSMX). These ZQ6X, ZSM6X1, and ZSM651+YCa alloys were prepared using hot extrusion. AC, DC polarization and immersion tests were carried out on the extruded rods. Microstructure was examined using optical and electron microscopy (SEM) and EDS. The addition of silver decreased the corrosion resistance. The additions of silicon and calcium also affected the corrosion behaviour. These results can be explained by the effects of alloying elements on the microstructure of Mg-Zn alloys such as grain size and precipitates caused by the change in precipitation and recrystallisation behaviour.

수중용접봉으로 용접한 누수 배관 용접부위의 부식 특성 평가 (Evaluation of Corrosion Characteristics on Welding Part of Leakage Water Pipe by Underwater Welding Electrode)

  • 김진경;문경만
    • 한국마린엔지니어링학회:학술대회논문집
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    • 한국마린엔지니어링학회 2006년도 전기학술대회논문집
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    • pp.93-94
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    • 2006
  • The repair welding of small leakage parts on the water pipeline in engine room is often and important factor in standby and emergency condition in a ship. So, the purpose of this study is to evaluate the corrosion characteristics of welding part of leakage water pipe in case of some underwater welding electrodes. The corrosion current density between welding metal and base metal was considerably different according to used underwater welding electrodes. In case of DC welding, its corrosion characteristics was better than that of AC welding.

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Development of Al-added High Strength Galvannealed Daul Phase Steel Sheets

  • Kim, Dong-Eun;Han, Young-Chul;Ko, Heung Seok;Kim, Jong-Gi;Moon, Man-Been
    • Corrosion Science and Technology
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    • 제10권5호
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    • pp.162-166
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    • 2011
  • Effects of chemical compositions and manufacturing conditions on mechanical properties and microstructures were investigated in order to obtain galvannealed high strength dual phase steel sheets with superior mechanical properties and coating properties. An intercritical annealing between Ac1 and Ac3 was conducted to produce the DP (dual phase) steel sheets, followed by quenching to room temperature. The purposes of Al addition are to reduce the iron oxidation with chemical composition (Si, Mn etc.) and to improve the wettability by liquid zinc. The present study will focus on the characterization for making dual phase steel sheets and enhancing the galvanizability of Al added DP steel sheets about continuous annealing line in CGL.