• Title/Summary/Keyword: 확산실험

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Basic Studies in Improvement of Freeze Concentration -(II) The Growth Rate and the Variety in Diameters of Ice Crystals- (동결농축(凍結濃縮)의 개선(改善)을 위한 기초적연구(基礎的硏究) -II. 빙결정(氷結晶)의 성장속도(成長速度)와 입경분포(粒徑分布)-)

  • Kong, Jai-Yul
    • Journal of the Korean Society of Food Science and Nutrition
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    • v.14 no.4
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    • pp.359-364
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    • 1985
  • Being used the three kinds of aqueous solution of tobacco extracts as a new experimental material, experiment and theoretical analysis are performed. Measurements are made with a apparatus designed and constructed by the author.The average diameter of the ice crystals is 0.04-0.1cm between 0.2 and $0.6^{\circ}C$ of the subcooling temperature of the solution. The growth rate of ice crystals in direction of axies A, $V_a$ is in proportion to the subcooling temperature, viz; $v_a=0.058{\Delta}t_b,\;where\;{\Delta}t_b<0.1^{\circ}C$ The growth rate of ice crystal have to be considered not only the mass diffusion and the heat transfer of rate controlling but also the process in ice crystallization. The growth rate of ice crystal is found to be independent on the concentration of the solution and a diameter of ice crystal.

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Removal of pharmaceuticals in biologically treated sewage with $O_3$ and advanced oxidation processes (오존 및 고도산화처리에 의한 하수 2차 처리수중의 의약품류 제거)

  • Kim, Il-Ho;Tanaka, Hiroaki;Song, Ho-Myeon;Joo, Jin-Chul;Ahn, Chang-Hyuk
    • Proceedings of the Korea Water Resources Association Conference
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    • 2011.05a
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    • pp.137-137
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    • 2011
  • 급격한 세계인구의 증가에 의해 물 부족지역이 세계 각지로 확산되고 있다. 이에 따라, 건전한 수자원으로써 하수처리수의 재이용이 주목을 받고 있다. 하수처리수의 재이용시에는 특히, 재이용수의 미생물학적 안전성과 더불어 화학물질 등으로부터 기인할 수 있는 인체 및 생태계에의 리스크를 고려해야 한다. 미국 EPA는 병원성 미생물 뿐만 아니라 화학물질에 대한 안전성을 확보 차원에자외선/과산화수소 등의 고도산화처리법을 검토하였다. 1일 $10m^3$ 처리규모의 연속실험장치를 이용, 검토된 공정별 실제 하수 2차 처리수중에 존재하는 의약품류의 제거효과, 에너지 소비량 및 생태리스크 저감효과 등을 비교, 평가하였다. 에너지 소비량에 있어서는 공정별로 다소 차이가 있었으나, 본 실험동안 검출된 38종의 의약품류 제거에는 각 공정 모두 매우 효과적이었다. 에너지 소비측면에서는 오존 단독공정이 가장 적은 에너지 소비량에서 타 공정과 동일한 수준의 의약품류 서 막처리나 자외선 처리 등의 고도처리시설에 대한 정보를 재이용수 가이드라인에 제시하고 있는 반면, 우리나라에서는 재이용수중에 일정농도 이상의 염소가 잔류하도록 함으로써, 재이용수의 미생물학적 안전성 확보만을 고려하고 있다. 최근, 수환경분야에서는 의약품류라는 화학물질이 유럽, 미국 및 일본 등지를 중심으로 주목을 받아오고 있으며, 이들은 ng/L-${\mu}g$/L 수준으로 수환경중에서 검출되고 있다. 이들의 주요 발생원으로 하수처리시설이 지목되고 있으며, 따라서 하수처리수의 재이용시 잔류 의약품류에 의한 리스크 발생 가능성이 우려되고 있다. 이를 배경으로, 하수처리시설에서 의약품류를 효과적으로 제거할 수 있는 공정으로 오존 및 오존/자외선, 제거효과가 얻어졌다. 한편, 오존처리시 발암성 물질인 브로메이트($BrO_3^-$) 등과 같은 부생성물 생성 가능성을 고려하면, 오존 단독공정보다 상대적으로 많은 에너지를 소비하는 오존/자외선, 자외선/과산화수소 등의 고도산화처리법이 높은 적용성을 갖는 것으로 나타났다. 향후, 수자원 부족문제로 재이용수의 용도가 훨씬 다양해 질 것으로 예상된다. 그에 따라, 재이용수의 안전성 확보를 위해 보다 폭넓은 검토가 예상되지만, 현 단계에서는 오존을 포함, 다소 많은 에너지 소비가 예상되는 자외선을 이용한 고도산화처리법이 다양한 미량 화학물질의 제거에 유효한 공정으로 판단된다.

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A Study on the Performance of Boiling Beat Transfer of Inclined Thermosyphon Heat Exchangers with Internal Grooves (경사 열사이폰 열교환기의 비등열전달 성능에 관한 연구)

  • Cho, Dong-Hyun;Lee, Jong-Sun
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.6 no.2
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    • pp.202-209
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    • 2005
  • This study concerns the performance of boiling heat transfer in inclined thermosyphons with internal grooves. A study was carried out with the performance of the heat transfer of the inclined thermosyphon having 60 internal grooves in which boiling and condensation occur. A plain thermosyphon having the same inner and outer diameter as the grooved thermosyphon is also tested for comparison. Distilled water, methanol and ethanol have been used as the working fluid. The inclination angle, three working fluids, heat flux and the boiling heat transfer coefficient at the evaporator zone are estimated from the experimental results. The experimental results have been assessed and compared with existing correlations. Imura's and Kusuda's correlation for boiling showed in good agreement with experimental results within ${\pm}20%$ in plain thermosyphon. The high heat transfer coefficient was found between $25^{\circ}$ and $30^{\circ}$ of inclination angle for water and between $20^{\circ}$ and $25^{\circ}$ for methanol and ethanol. The relatively high rates of heat transfer have been achieved in the thermosyphon with internal micro grooves.

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Formation Control of Calcium and Magnesium Compounds by Electrodeposition Process in Seawater (해수 중 전착 프로세스에 의한 칼슘 및 마그네슘 화합물의 형성 제어)

  • Park, Jun-Mu;Hwang, Seong-Hwa;Choe, In-Hye;Gang, Jun;Lee, Myeong-Hun
    • Proceedings of the Korean Institute of Surface Engineering Conference
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    • 2017.05a
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    • pp.164-164
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    • 2017
  • 해양환경 중 많이 사용되는 철강재료들은 그 가혹한 부식환경에 대응하기 위하여 일반적으로 피복 도장방식법이나 음극방식법이 적용되고 있다. 여기서 음극방식법은 선박 및 해양구조물의 해중부 부식에 대해 가장 효과적인 방식법으로 알려져 있다. 한편, 이와 같이 해수 중 철강재에 음극방식을 적용할 경우, 피방식체인 그 강재 표면에 해수 중 용존된 산소의 음극환원 반응이 일어나며 국부적인 알카리 표면 조건을 형성시켜 $Mg(OH)_2$$CaCO_3$의 막을 석출시킨다. 이와같이 음극방식 중 형성된 전착물은 방식해야 될 표면적을 감소시켜 방식전류밀도를 감소시키는 효과가 있는 것으로 보고되고 있다. 이렇게 석출된 전착물은 음극표면에 부분적으로 형성되고, 여러 가지 환경 조건 등의 영향을 받아 그 피막의 형성 정도도 가늠하기 어렵기 때문에 음극방식 설계 시 그 정도에 따른 영향을 고려-반영하기가 곤란하다. 또한 이 전착물은 그 형성 메커니즘에 관한 해석이나 강도, 균일한 밀착성, 장기적인 방식효과 및 효율성 등이 아직 충분히 입증되어 있지 않은 실정에 있다. 따라서 본 연구에서는 해수 중 다양한 전착 프로세스에 의해 제작된 전착물의 기간별, 도장코팅 종류별 특성변화를 분석 및 평가하고, 전착물에 의한 희생양극 소모전류 변화 측정 분석을 통해 전착막을 균일하고 치밀하게 형성시키기 위한 최적의 조건을 찾고자 하였다. 또한 석출속도, 밀착성 및 내식특성을 향상시키기 위해 해수 중 기체를 용해시켜 제작한 막의 특성을 분석-평가하였다. 본 연구에 사용된 강 기판은 일반구조용강(KS D 3503, SS400)으로 ${\varnothing}42.7{\times}1,000mm{\times}4.0t$의 형상으로 제작하였다. 인가된 전류밀도는 1, 3 및 $5A/m^2$이고 도장 코팅 종류별 전착 석출물의 형성차이 비교 분석을 위한 실험은 선박 및 해양구조물에 많이 사용되는 Universal Epoxy 도료 2종을 선정하여 진행하였다. 또한 Steel Wire Mesh의 영향을 알아보기 위해 Mesh를 설치하여 실험을 진행하였다. 기간별-도장 종류별 외관관찰, 전착물의 두께 측정, SEM, EDS 및 XRD를 통해 막의 모폴로지, 조성원소 및 결정구조를 분석하였으며, 전착물의 내식성과 내구성을 평가하기 위해 테이핑 테스트(Taping Test) 및 전기화학적 양극분극 시험을 실시하였다. 희생양극 소모율에 대한 전착물의 영향을 확인하기 위해 외부전원을 인가하여 전착 피막을 형성시킨 강 기판에 희생양극을 연결하여 희생양극 소모효율 측정 시험을 진행하였다. 전착물의 석출량은 시간 및 전류밀도의 증가에 따라 비례하여 증가하였으며, 음극전류 인가 시 금속과 용액 계면 사이의 확산층에서 발생한 $OH^-$ 이온으로 인해 금속과 용액 계면 사이 pH가 부분적으로 증가하여 $Mg(OH)_2$ 화합물이 많이 생성되는 것으로 확인되었다. 또한 Mesh의 부착으로 평활하지 않게 형성된 미세한 굴곡구조 및 표면적 증가로 인하여 단계적으로 피복되는데 필요한 시간이 지연되면서 $CaCO_3$에 비해 $Mg(OH)_2$ 화합물이 상대적으로 증가한 것으로 사료된다. $CaCO_3$(Aragonite) 구조는 견고한 피막으로 치밀하고 화학적 친화력이 높아 우수한 밀착성을 보였으며 전착물의 영향으로 양극 전류가 감소하였고, 이로인해 방식전류 절감효과를 얻을 수 있을 것으로 기대된다.

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Material Characteristic of POFA Concrete and Its Application to Corrosion Resistance Evaluation (POFA 콘크리트의 재료특성 및 부식 저항성 평가로의 적용)

  • Lee, Chang-Hong;Song, Ha-Won;Ann, Ki-Yong;Ismail, Mohamed Abdel
    • Journal of the Korea Concrete Institute
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    • v.21 no.5
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    • pp.565-572
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    • 2009
  • In this study, corrosion resistance of palm oil fuel ash (POFA) concrete as a blended concrete is evaluated by using electrochemical technique. The POFA is an industrial byproduct obtained from fuel ash after extracting palm oil from palm-tree. In order to obtain basic material characteristics of the POFA concrete, tests on compressive strength, slump, weight loss, bleeding and expansion ratio were carried out the early-aged POFA concrete. On the other hand, durability characteristics, both chloride penetration and carbonation depth test, were also conducted. Finally, corrosion resistance were evaluated by applying electro-chemical artificial crack healing technique, and the tests on the impressed voltage characteristic, galvanic current and linear polarization resistance. From the experimental results, it was found that long-term strength, bleeding, lower slump ratio, expansion ratio, chloride penetration, carbonation and corrosion resistance were improved by using the POFA due to activated pozzolanic reaction. It can be also mentioned that POFA concrete has a potential to be used as a cementitious binder for green-recycling resources.

A Study on Elasto-Plastic Behavior of Column-to-Beam Welded Connection with 600MPa Class High Performance Steel (600MPa급(SM 570 TMC) 고성능강 기둥-보 용접접합부의 탄소성 거동에 관한 연구)

  • Kim, Jong Rak;Oh, Young Suk;Baek, Ki Youl;Chang, Sung Yun
    • Journal of Korean Society of Steel Construction
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    • v.20 no.6
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    • pp.783-792
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    • 2008
  • While the recent high demand for mega-tall buildings has led to the development of high-performance and high-strength steels, the requirements for architectural-structure-performance steel have been raised as engineers recognize the potential damage that an earthquake can wreak on a tall building. A 600MPa-class steel has emerged to meet such need, and many studies are currently exploring its practical applications on civil engineering works and mega-tall buildings. The available data on the horizontal-force behaviors of structures built with such new steel, however, are still insufficient. There is an urgent need to look into its design data, especially its toughness, and to compare the plastic strain ratios of column-to-beam connections using high-strength steel and regular steel. One of the first studies on the behavior of a column-to-beam connection using 600MPa-class steel (SM570 TMC), this thesis analyzes such steel's structural performance by conducting a structural test on seismic resistance on a full-scale column-to-beam welded connection with non-scallop and recommended-scallop details. Compared with the previous studies on SM490, this thesis evaluates the weldability of SM570 TMC and presents the latter's seismic design data for use in testing its practical application.

Comparison of the Modulation Transfer Function of Several Image Plate (Image Plate(IP) 영상의 MTF 비교)

  • Kim, Chang-Bok;Lee, Yang-Sup;Kim, Young-Keun;Lee, Seong-Kil;Lee, Kyung-Sup
    • Journal of radiological science and technology
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    • v.27 no.3
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    • pp.25-29
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    • 2004
  • Among the digital radiography systems, the computed radiography Image Plate Detector System is most frequently being used for the general radiography and also this system commonly diffracts the x-ray images since it is the system that is influenced by the light diffusion from the fluorescent substances. In this study, by using the X-ray Generator, a comparative analysis has been made between 2 different models of computer radiography image plate investigate each model's resolution and sharpness through the modulation transfer function(MTF) measurement. For the analysis, two image plates for general radiography one Fuji ST-VN model(more than 3years old) and one Fuji ST-VL model(less than 2years old) that are currently being used in "Hospital A" were sampled for the MTF measurement here. As the experimental method for this study, the resolution chart method has been carried out by using X-ray generator. Also all the experimental data were printed out by laser printer and measured by microdensitometer. As the results of the experiment carried out in this study, some differences have been found between the two different IP models and Fuji ST-VL has shown its excellence in both of the resolution and the sharpness fields.

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Characterization of Plasmid-Mediated SHV-11 β-lactamase Gene of Klebsiella pneumoniae Isolated from the Clinical Specimens (임상검체로부터 분리한 플라스미드 매개성 SHV-11 β-lactamase 유전자의 특성)

  • Kim, Yun-Tae;Lee, Sang-Hoo;Jang, Ji-Hyun;Kim, Tae-Un;Choi, Seok-Cheol;Baik, Hyung-Suk;Lee, Kyoung-Ryul;Yoon, Hye-Ryoung;Kim, Young-Jin
    • Journal of Life Science
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    • v.19 no.12
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    • pp.1718-1723
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    • 2009
  • In this study, we characterized extended-spectrum $\beta$-lactamase (ESBL)-producing Enterobacteriaceae isolated from clinical specimens in Korea and found two strains harboring plasmid-mediated $bla_{SHV-11}$, Klebsiella pneumoniae. First, the isolates were detected using the Vitek system and confirmed by the double-disk synergy test. The classification of gene coding for ESBL was also performed by polymerase chain reactions and followed by DNA sequencing. The transmission of genes was confirmed by transconjugation and transformation. Resistant expression of transformants was determined by broth microdilution minimal inhibitory concentration test. Genotypic analysis revealed that one strain harbored the $bla_{TEM-1}$, $bla_{SHV-11}$ and $bla_{CTX-M-15}$ and the other strain harbored the $bla_{SHV-11}$ and $bla_{CTX-M-15}$. They showed high resistance to oxyiminocephalosphorins (3rd-generation cephalosporins), while the transformant containing only $bla_{SHV-11}$ did not show any resistance to the antibiotics.

An Esitimation of Lognitudinal Dispersion Coefficient in Natural Stram Using Hydraulic Model (수리모형을 이용한 자연하천에서 종확산계수 추정)

  • Yun, Se-Ui;Han, Geon-Yeon;Han, Jeong-Seok;Kim, Jeong-Su
    • Journal of Korea Water Resources Association
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    • v.33 no.4
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    • pp.407-417
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    • 2000
  • To estimate the longitudinal dispersion coefficient at the downstream of Jungrang-River, the undistorted 1/20 scale hydraulic model was used in this study. Experiments were conducted for dry season discharge, and Rhodamine B was used as a tracer. The relationship curve between concentration and conductivity of Rhodamine B was otained by laboratory test, and the conductivity which was measured in hydraulic model was converted to concentration using this curve. The longitudinal dispersion coefficient was calculated using the relationship between the peak concentration and the time to peak concentration. The results of this study were compared with the calculated values by the empirical equations for the longitudinal dispersion coefficient and with the field data. The results of comparison show that Parker's equation underestimates, and Liu'g equation and Iwasa and Aya's one overestimate, and McQuivey and Keefer's equations, Fischer's one, Magazine's one, and Seo and Cheong's one predict relatively well. The measured data sets were relatively close to the observed ones in natural river. The longitudinal dispersion coefficient at the downstream of Jungrang-River was estimated $10\textrm{m}^2/s$.

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Numerical analysis of the morphological changes by sediment supply at the downstream channel of Youngju dam (댐 하류하천에서 유사공급에 의한 하도의 지형변화 수치모의 분석(영주댐을 중심으로))

  • Kang, Ki-Ho;Jang, Chnag-Lae;Lee, Gi Ha;Jung, Kwansue
    • Journal of Korea Water Resources Association
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    • v.49 no.8
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    • pp.693-705
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    • 2016
  • In this study, the effects of sediment supply on the downstream of a large dam are investigated using a numerical model. The model simulation shows a good agreement with laboratory experiment results of sediment transport and diffusion from sediment pulses. The water surface changes from the various sediment bed elevations are also simulated using the model. The site which has a relatively stiff bed slope and meandering of a channel is selected as an appropriate location for sediment supply because of its shear stress enough to supply the sediment downstream. The model simulation shows the decrease of channel bed elevation through the simulation period with time. The well-deposition of sediment supplied from the downstream of dam is found in the location where the flow rate is relatively low. A bed relief index is increased with time and it is relatively greater in downstream compared to upstream. The channel bed variability increases as flow rate increases with a greater bed relief index. The results of this study demonstrate the importance of increasing water discharge of a large dam to increase the dynamic of channel bed and thus to enhance the efficiency of channel bed restoration by sediment supply.