• Title/Summary/Keyword: 저온 소성

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A Study on the Co-firing Compatibility with Ag-thick film and Dielectric Characteristics of Low Temperature Sinterable SiO$_2$-TiO$_2$-Bi$_2$O$_3$-RO system (RO :BaO-CaO-SrO) Glass/Ceramic Dielectric Material with the Addition of B$_2$O$_3$ (저온 소성용 SiO$_2$-TiO$_2$-Bi$_2$O$_3$-RO계(RO :BaO-CaO-SrO) Glass/ceramic 유전체 재료의 B$_2$O$_3$첨가에 따른 Ag 후막과의 동시 소결시 정합성 밀 유전 특성에 관한 연구)

  • 윤장석;이인규;유찬세;이우성;강남기
    • Journal of the Microelectronics and Packaging Society
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    • v.6 no.3
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    • pp.37-43
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    • 1999
  • Co-firing incompatibility between the low temperature sinterable Glass/ceramic and Ag-thick film was studied. The dielectric material, which has been developed for microwave frequency applications, consists of $SiO_2-TiO_2-Bi_2O_3$-$Bi_2O_3$-RO system(RO:BaO -CaO-SrO) crystallizable glass and $Al_2O_3$as a ceramic filler. The large camber in the sintered specimen and cracks at the Ag-film under the influence of the camber occurred due to the difference of densification rate between the ceramic sheet and the Ag-film $B_2O_3$addition to the Glass/ceramic mixture reduced the severe camber. The cambers decreased with increasing the $B_2O_3$ content, and completely disappeared with 14 vol% $B_2O_3$addition. With additions of $B_2O_3$, $\varepsilon_{r}$ decreased abruptly, Q$\times$f value increased largely and the $\tau_f$ value of the material quickly shifted to positive one.

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Effect of lead-free frit and RuO2 on the electrical properties of thick film NTC thermistors for low temperature co-firing (저온 동시 소성용 후막 NTC 서미스터의 전기적 특성에 미치는 무연계 프릿트 및 RuO2의 영향)

  • Koo, Bon Keup
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.31 no.5
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    • pp.218-227
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    • 2021
  • A thick film NTC thermistor for low temperature co-firing was manufactured by printing and sintering a paste prepared using NTC powder of Mn1.5Ni0.4Co0.9Cu0.4O4 composition, lead free frit, and RuO2 on a 96 % alumina substrate. The effect of frit and RuO2 on the electrical properties of thick film NTC thermistor was studied. The resistance of the thick film NTC thermistor was higher than that of the bulk phase sintered at the same temperature, but it was found that the negative resistance temperature characteristic appeared more clearly and linearly in the resistance - temperature characteristic. On the other hand, the area resistance decreased as the sintering temperature increased, and the area resistance increased as the amount of frit added increased. The B constant of the thick film NTC thermistor was 3000 K or higher. Among them, it was found that the B constant of the thick film NTC thermistor made of paste with 5 wt% of frit added and sintered at 900℃ showed the highest B constant. Also, it can be seen that the area resistance decreased with the addition of RuO2, and the change in the area resistance decrease of the thick film NTC thermistor obtained by sintering the paste containing 5 wt% of RuO2 at 900℃ is the most obvious.

Investigation on the Ratio and Type of Gypsum for Early Strength Improvement of Blast Furnace Slag Powder (고로슬래그 미분말의 초기강도 향상을 위한 석고 종류 및 첨가량 검토)

  • Jeong, Yong;Yoo, Jung-Hoon;Shin, Jae-Kyung
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.5 no.4
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    • pp.106-113
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    • 2010
  • We were tried to draw a conclusions related to additive amount of gypsum in blast furnace slag in the study. In the result, fluidity of concrete decreased with an increase of gypsum and was not satisfied with KS standard in the cases of natural gypsum and limestone sludge more than 2.6% addition. Early compressive strength of concrete containing desulfurized gypsum, fluosilicic acid gypsum and phosphoric acid gypsum were improved respectively but calcined lime sludge and lime powder were not influenced on strength. If available, additive gypsum should be managed less than 2.0% owing to low fluidity. In low temperature, fluosilicic acid gypsum was to advantages on the fluidity while desulfurized gypsum was in high temperature. There also are conclusions that additive gypsum was to be 2.6% in winter and in summer; it's to be fewer than 2.6%.

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Characteristics of Embedded R, L, C Fabricated by Using LTCC-M Technology and Development of a PAM for LMR thereby (LTCC-M 기술을 이용한 내부실장 R, L, C 수동소자의 특징 및 LMR용 PAM개발)

  • 김인태;박성대;강현규;공선식;박윤휘;문제도
    • Journal of the Microelectronics and Packaging Society
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    • v.7 no.1
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    • pp.13-18
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    • 2000
  • Low temperature co-fired ceramics on metal (LTCC-M) is efficient for embedding passive components with good tolerance in a module due to the dimensional stability in x and y directions by the constraint of metal core during the firing. In addition, the radiation noise can be reduced by metal core. In this paper, embedded passive components were introduced and a power amplifier module (PAM) fabricated by using the passive components was explained. The embedded passive components in test patters showed the tolerance of 10~20% and the good repeatability in tolerance of embedded passives was maintained in module fabrication. The shortened traces in multi chip modules (MCMs) make the signal delay time decreased and the embedded passives simplify the packaging processes owing to the less solder points, which enhance the electrical performance and increase the reliability of the modules. The LTCC-M technology is one of the promising candidates for RF application and is expected to expand its applications to power and high performance devices.

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Fabrication and Characterization of Buried Resistor for RF MCM-C (고주파 MCM-C용 내부저항의 제작 및 특성 평가)

  • Cho, H. M.;Lee, W. S.;Lim, W.;Yoo, C. S.;Kang, N. K.;Park, J. C.
    • Journal of the Microelectronics and Packaging Society
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    • v.7 no.1
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    • pp.1-5
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    • 2000
  • Co-fired resistors for high frequency MCM-C (Multi Chip Module-Cofired) were fabricated and measured their RF properties from DC to 6 GHz. LTCC (Low Temperature Co-fired Ceramics) substrates with 8 layers were used as the substrates. Resisters and electrodes were printed on the 7th layer and connected to the top layer by via holes. Deviation from DC resistance of the resistors was resulted from the resister pastes, resistor size, and via length. From the experimental results, the suitable equivalent circuit model was adopted with resistor, transmission line, capacitor, and inductor. The characteristic impedance $Z_{o}$ of the transmission line from the equivalent circuit can explain the RF behavior of the buried resistor according to the structural variation.

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A Study on the Regeneration of SCR Catalyst Deactivated by Unburned Carbon Deposition (탄소침적으로 피독된 탈질 촉매의 재생에 관한 연구)

  • Moon, Seung-Hyun;Lee, Seung-Jae;Ryu, In-Soo
    • Journal of Korean Society of Environmental Engineers
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    • v.32 no.10
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    • pp.928-935
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    • 2010
  • A bag filter system was partially burnt down during a trial run of waste wood incineration boiler. This brought about unburned hydrocarbon which caused a rapid deactivation of low temperature SCR catalyst set up in two stage after the bag filter. The deactivated catalyst was investigated in order to trace the origin by several characterization methods such as XRD, EDX, BET, TGA, SEM. The deactivated catalyst was regenerated by different methods such as acid washing, water washing in ultrasonication, and calcination treatment under air condition. It is found the calcination treatment under air condition at $450^{\circ}C$ for 2 hours to be the best regeneration method. The catalytic activity was measured in the form of 2 cm ${\times}$ 2 cm ${\times}$ 10 cm (catalyst weight 10 g) honeycomb type. A deNOx efficiency of the regenerated catalyst showed 100% at $180^{\circ}C$ which is the same level of fresh one.

Sintering and Dielectric Properties of $BaO-Nd_2O_3-TiO_2$ Microwave Ceramics for LTCC RE module (LTCC RF 모듈용 $BaO-Nd_2O_3-TiO_2$계 세라믹스의 저온소결 및 마이크로파 유전특성)

  • Shin, Dong-Soon;Choi, Young-Jin;Park, Jae-Hwan;Nahm, Sahn;Park, Jae-Gwan
    • Journal of the Microelectronics and Packaging Society
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    • v.10 no.1
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    • pp.57-63
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    • 2003
  • The effects of glass addition on the low-temperature sintering and microwave dielectric properties of $BaO-Nd_2O_3-TiO_2$ dielectric ceramics were studied. When 10∼13 wt% of lithium borosilicate glass was added, the sintering temperature decreased from 130$0^{\circ}C$to 850-$900^{\circ}C$relative density of more than 97% was obtained. When the sample was sintered at $850^{\circ}C$ with 10 wt% of glass, the dielectric properties of $\epsilon_r{\ge}54$, $Q{\times}f_0{\ge}2300$, and $\tau_f{\ge}+8ppm/^{\circ}C$ were obtained.

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Catalytic Oxidation of Toluene over Pd-Activated Alumina Catalysts at Low Temperature (활성알루미나에 담지한 팔라듐 촉매상에서 톨루엔의 저온 연소반응)

  • Lee, Ju-Yeol;Song, Hyung-Jin;Lee, Sang-Bong;Kim, Mi-Hyung;Jo, Young-Min
    • Journal of the Korean Applied Science and Technology
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    • v.29 no.2
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    • pp.339-347
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    • 2012
  • This study focuses on developing catalysts for the removal of toluene produced from paint booth. Toluene is one of the major VOC in painting, coating process. Pd catalysts have been used in hydrogenation oxidation and low temperature combustion reaction for toluene removal. Pd catalysts, even though it is very precious and expensive. Therefore, the prepared catalysts from minimizing the amount of Pd ratio (0.1~1.0wt%) were measured. As a result, 1.0wt% Pd(R) catalyst under all conditions showed the highest activity. These results may suggest that the catalytic activity is related to Pd dispersion according sintering atmosphere and Pd ratio in the manufacturing process through the analysis of SEM, XRD.

Sintering Behavior and Microwave Dielectric Propel1ies of Mg-Si-O Ceramics with Glass Frit for LTCC Substrate (Glass firt 첨가에 따른 저온 동시소성 기판용 Mg-Si-O계 세라믹스의 소결거동 및 마이크로파 유전특성)

  • Cho, Jung-Hwan;Yeo, Dong-Hun;Shin, Hyo-Soon;Kim, Jong-Hee;Nahm, Sahn
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2007.06a
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    • pp.310-310
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    • 2007
  • Mg-Si-O계 세라믹스에 glass frit 조성을 첨가하여 저온에서의 소결 특성 및 마이크로파 유전 특성을 연구하였다. 기존의 Mg-Si-O계 세라믹스는 우수한 유전특성을 가지고 있으나 높은 소결온도로 인하여 LTCC용 기판 소재로 적용이 어려웠다. 본 연구에서는 MgO, $SiO_2$를 이용하여 $Mg_2SiO_4$을 합성한 후, $B_2O_3-ZnO-Na_2O-SiO_2-Al_2O_3$계 glass 조성을 20~40wt%로 첨가하여 소결온도를 감소시켜 LTCC 기판 소재로서의 적용성을 고찰하였다. glass frit 함량이 증가함에 따라 밀도($g/cm^3$) 및 유전율(${\varepsilon}_r$)은 증가하였고 품질계수($Qxf_0$)값은 감소하였다. glass frit 함량이 40wt%일때 $900^{\circ}C$에서 1시간 소결한 소결체의 유전톡성은 유전율 (${\varepsilon}_4$) = 6.5. 품질계수 ($Qxf_0$) = 4,000(GHz), 온도계수 $(\tau_t)\;=\;{\pm}\;10ppm/^{\circ}C$로 우수한 특성을 확인하였다.

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A Study on Rheological Behavior of Korean Straight Asphalts (국내 스트레이트 아스팔트의 거동 특성 연구)

  • Kim, Nam-Ho;Hwang, Sung-Do;Park, Young-Cheol
    • International Journal of Highway Engineering
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    • v.1 no.2
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    • pp.121-133
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    • 1999
  • This study was based on the evaluation of 9 asphalts that were produced in five major Korean refineries. The study was concentrated to identify the problems of the current asphalt specification (KS M 2201) and to determine the ranges of visco-elastic asphalt behavior. As a conventional asphalt property. asphalt penetration, ring and ball(R&B) softening point, asphalt viscosity, and flash point of asphalt were measured. Also Dynamic Shear Rheometer (DSR) were used to evaluate visco-elastic properties of asphalts in the $-20^{\circ}C$ through $30^{\circ}C$ temperature range. These properties before and after the short-term (RTFO) and long-term (PAV) aging were compared and analyzed to achieve the research objectives. The conclusion from this study can be summarized by the followings. The low temperature rheological behavior of all the straight asphalt from five major Korean refineries is similar regardless of asphalt grade. In the mean while, the rheological behavior at high and intermediate temperature of Korean straight asphalt varies depending on asphalt grade.

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