• Title/Summary/Keyword: 인산암모늄

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Effect of Ammonium Phosphate Concentration on the Growth of Recombinant E. coli (재조합 대장균의 세포성장에 대한 인산암모늄 농도의 영향)

  • 김종수;석근영차월석
    • KSBB Journal
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    • v.11 no.4
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    • pp.389-397
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    • 1996
  • The growth of recombinant E. coli and formation of the by-products were investigated. Ammonium phosphate is known to affect the cell growth as well as the enzyme formation. When initial ammonium phosphate concentration was 0.5g/L, cell mass was 4.1g/L. By adding tryptone to the medium, acetic acid formation increased while lactic acid formation decreased. In cultivating recombinant E. coli, lactic acid and acetic acid turned out to be important by-products which affected cell yield and growth rate. Initial ammonium phosphate and tryptone concentration were optimized in our research and can be applied for other culture of recombinant E. coli.

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질산칼륨을 첨가한 인산암모늄 방염제의 연소특성

  • Gwon, Gyeong-Ok;Kim, Yeong-Geun
    • Proceedings of the Korea Institute of Fire Science and Engineering Conference
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    • 2013.04a
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    • pp.158-159
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    • 2013
  • 방염제인 인산암모늄에 질산칼륨을 첨가하여 질산칼륨이 인산암모늄의 방염성능에 미치는 영향을 DSC와 실체현미경으로 분석하였다. 활성화에너지는 키싱거방법을 도입하여 분석하였다. 방염성능 실험으로서 셀룰로스를 연료로 사용하였다. 질산칼륨이 일정량 첨가된 방염제를 사용하는 경우 인산암모늄의 활성화에너지를 높이고 탄화면적을 감소시켜 연소확대를 억제하였다. 방염제인 질산칼륨이 첨가된 인산염을 방염제로 사용하는 경우 질산칼륨의 강한 산화력으로 화염발생 온도를 낮추고 탄화형성을 억제하여 화재진행 속도를 낮추는 것으로 나타났다. 적정량 이하의 질산칼륨이 포함된 방염제의 처리는 연소속도를 높이고 탄화물형성을 감소시킬 수 있음을 제시하였다.

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Manufacture Technology of Monoammonium phosphate from LCD Waste Acid (LCD 제조공정의 혼합폐산으로부터 일인산암모늄 제조 기술)

  • Lee, Ha-Young;Lee, Sang-Gil;Park, Sung-Kook;Kim, Ju-Han;Kim, Ju-Yup;Kim, Jun-Young
    • Clean Technology
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    • v.15 no.4
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    • pp.253-257
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    • 2009
  • The waste solution discharged form the LCD(Liquid Crystal Display) manufacturing process contains phosphoric acid, nitric acid, acetic acid and metal ions such Al and other impurities. In this study, vacuum evaporation and diffusion dialysis was developed to commercialize an efficient system for recovering the high-purity phosphoric acid and manufacturing monoammonium phosphate. By vacuum evaporation, almost 99% of nitric and acetic acid was removed. Also, by diffusion dialysis, about 97.5% of Al was removed. Monoammonium phosphate was manufactured from purified phosphoric acid and ammonium hydroxide. In order to get the optimum manufacturing condition, the molar ratio of ammonium hydroxide and phosphoric acid, pH and temperature was controlled. Using this optimum condition, we obtained the recovery rate of monoammonium phosphate of about 90%.

Combustive Characteristics of Pinus Rigida Treated with Ammonium Salts (암모늄염으로 처리된 리기다 소나무의 연소특성)

  • Chung, Yeong-Jin;Jin, Eui
    • Fire Science and Engineering
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    • v.24 no.5
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    • pp.115-121
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    • 2010
  • This study was performed to test the combustive properties of Pinus rigida-based materials by the treatment of ammonium salts. Pinus rigida plate was soaked in three 20 wt% ammonium salt solutions such as ammonium sulfate (AMSF), monoammonium phosphate (MAPP), and diammonium phosphate (DAPP), respectively, at the room temperature. After drying specimen treated with chemicals, combustive properties were examined by the cone calorimeter (ISO 5660-1). Comparing with virgin pinus rigida plate, specimens treated with the ammonium salts had lower combustive properties and It is supposed that the combustion-retardation properties improved due to the treated ammonium salts in the virgin Pinus rigida. Also, the specimens with treated ammonium salts showed both the lower peak heat release rate (PHRR) and lower total heat release (THR) than those of virgin plate.

A Comparative Study on the Effect of Fire Retardancy of the Plywood Treated by Ammonium Sulphate and Monoammonium Phosphate (황산암모늄과 제 1 암모늄처리(處理) 합판(合板)의 내화효과에 관(關)한 비교연구(比較硏究))

  • Lee, Phil-Woo;Kim, Cheol-San
    • Journal of the Korean Wood Science and Technology
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    • v.11 no.3
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    • pp.23-30
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    • 1983
  • This experiment was carried out for diminishing the material loss and the damage of human life due to the fire disaster by treating plywood with fire retardant chemical solution. At this study, we observed and measured chemical retention, burning point, maximum flame length, flame exausted time, carbonized area, and weight loss of plywood treated by each solution of ammonium sulphate [$(NH_4)_2SO_4$] and monoammonium phosphate [$NH_4H_2PO_4$]. Obtained results at the study may be summarized as follows: 1. In case of monoammonium phosphate-treated plywood, every tested item of fire retardancy was shown more excellent at the 25% chemical concentration and shown also at 9 hours treatment except maximum flame length compared with ammonium sulphate-treated plywood. 2. However in case of ammonium sulphate-treated plywood, 6 hours treatment of fire retardancy was better than 9 hours treating time. 3. Monoammonium phosphate was generally better than ammonium sulphate in every tested item.

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Effects of $NH_4-N,\;NO_3-N$ and Urea-N on the Growth of Soybean Plants Different in Phosphorus Sensitivity (인산감수성(燐酸感受性)이 다른 대두(大豆)의 생육(生育)에 대(對)한 암모늄태(態) 초산태(硝酸態) 및 요소태질소(尿素態窒素)의 영향(影響))

  • Park, Hoon;Stutte, Charles A.
    • Applied Biological Chemistry
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    • v.16 no.3
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    • pp.118-127
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    • 1973
  • Effects of nitrogen sources oi phosphorus sensitivity in soybeans were investigated using three nitrogen source ($NH_4-N,\;NO_3-N$ and urea) and six cultivars (Lee, Hill, R56-49, Harosoy, Clark-63 and Chippewa), differing in phosphorus sensitivity. Growth inhibition with ammonium or urea medium increased with phosphorus sensitivity indicating that the phosphorus sensitive cultivars are also sentitive to ammonium. The sensitive Clark-63 was inhibited two folds more than the tolerant Lee in ammonium medium. These results strongly suggest that phosphorus sensitivity is closely linked to nitrogen metabolism and ammonium toxicity. Nitrogen sources gave special morphorogical growth patterns (short internode-many branchs in $NO_3-N$, long internode-no branches in $NH_4-N$ and a low top to root ratio in urea) by affecting differently the growth of plant organs.

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Study on the Effect of the ABC Dry Chemical on Wood in Pyrolysis (ABC 분말소화약제의 열분해 시 목재에 미치는 영향에 관한 연구)

  • Ko, Wang-Youl;In, Se-Jin
    • Fire Science and Engineering
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    • v.32 no.3
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    • pp.1-7
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    • 2018
  • This study the effect of pyrolysis products ABC dry chemical and of monoammonium phosphate on wood surface. When the pyrolysis product was removed from the wood surface, monoammonium phosphate was removed due to the high viscosity of the transparent pyrolysis product, but the ABC dry chemical was removed in a lump form. Thermal analysis showed that the pyrolysis characteristics of each sample were similar but the weight of pyrolysis residue was 55.9% for ABC dry chemical and 25.2% for monoammonium phosphate. The additives added to the ABC dry chemical also affect the weight of the pyrolysis residue and the fire protection effect of metaphosphoric acid.

Effect of Phosphate Types on the Strength and pH of Magnesia-Phosphate Composites (마그네시아 인산염 복합체의 강도 및 pH에 대한 인산염 종류의 영향)

  • Lee, Kyung-Ho;Yang, Keun-Hyeok
    • Journal of the Korea Institute of Building Construction
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    • v.17 no.2
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    • pp.135-140
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    • 2017
  • As an elementary investigation to develop vegetation concrete with a relatively low pH value, magnesia-phosphate composites (MPC) were examined according to the phosphate types including Monoammonium, Monosodium, Monopotassium, Monocalcium, Diammonium, Disodium, Dipotassium, and Diacalcium phosphates. All of the MPC binders, the ratio of magnesia to phosphate was fixed to be 7:3. MPC mortars activated with Disodium, Dipotassium, and Diacalcium phosphates showed no compressive strength gain, even at age of 28 days. Meanwhile, MPC mortars with Monoammonium and Monosodium phosphates developed 28-day compressive strength of more than 34MPa, and showed a relatively low pH value below 9.8. Hence, Monoammonium and Monosodium phosphates have potentials as an activator for producing MPC-based vegetation concrete.

Oxygen Index of Fire-Retardant-Treated Plywood in Burning Test (산소지수법(酸素指數法)에 의한 내화처리합판(耐火處理合板)의 연소시험(燃燒試驗))

  • Lee, Phil Woo;Eom, Young Geun;Kim, Hyun Joong
    • Journal of Korean Society of Forest Science
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    • v.78 no.4
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    • pp.419-424
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    • 1989
  • To obtain relative effectiveness in fire resistance among fire retardant chemicals, oxygen indices were determined for 3.5 mm thick, three-ply, meranti plywoods, treated with 5 commercial chemicals and water and then press-dried, through Up and Down method following oxygen index test of ASTM D 2863-77. The oxygen indices obtained were 28.4 for ammonium sulfate, 26.9 for monoammonium phosphate, 43.4 for diammonium phosphate, 30.1 for borax-boric acid, 32.4 for minalith, and 25.5 for water. Therefore, diammonium phosphate was found to rank first in fire-retardant effectiveness, followed by minalith, borax-boric acid, ammonium sulfate, and monoammonium phosphate in turn, judging from the fact that highly flammable materials are likely to have a low oxygen index.

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Studies on the Fire Retardant Treatment of Wet Forming Mat for Hardboard (경질섬유판(硬質纖維板)의 습식(濕式)매트 내화처리(耐火處理)에 관(關)한 연구(硏究))

  • Shin, Dong-So;Lee, Hwa-Hyoung;Shim, Chong-Supp
    • Journal of the Korean Wood Science and Technology
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    • v.10 no.3
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    • pp.180-188
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    • 1982
  • This study was carried out to make hardboard fire retardants and to examine the properties of the hard-board treated with them. The fire retardant treatment was achieved by surface impregnation of water soluble retardant chemicals into the forming mat with 55 percent of moisture content. followed by the hot pressing process. Ammonium monophosphate, ammonium diphosphate, sodium borate, and boric acid were used as the fire retardants. Fire retardant test was carried out by using the differential thermal analysis thermogram. The results are summarized as follows: 1. Fire retardant-treated hardboard showed higher values of the specific gravity. water absoption, and flexural strength than those of untreated hardboard. Especially, the treatment of ammonium monophosphate gave the best results in the flexural strength, and a 10 gr/$ft^2$ loading of the fire retardant compound of ammonium monophoshate, ammonium diphosphate, and sodium borate drew the best flexural strength value among the three different experimental loadings of 10, 20 and 30 gr/$ft^2$. 2. There were no definite differences in moisture content between the fire retardant-treated hardboard and the untreated hardboard. 3. The fire retardant compound of ammonium monophosphate, ammonium diphosphate, and sodium borate resulted in the best fire retardancy, and its fire retardancy was increased in proportion to the increase of loading.

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