• Title/Summary/Keyword: 세라믹 소재

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Recent Research Progresses in 2D Nanomaterial-based Photodetectors (2D 나노소재기반 광 센서 소자의 최근 연구 동향)

  • Jang, Hye Yeon;Nam, Jae Hyeon;Cho, Byungjin
    • Ceramist
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    • v.22 no.1
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    • pp.36-55
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    • 2019
  • Atomically thin two-dimensional (2D) nanomaterials, including transition metal dichalcogenides (TMDs), graphene, boron nitride, and black phosphorus, have opened up new opportunities for the next generation optoelectronics owing to their unique properties such as high absorbance coefficient, high carrier mobility, tunable band gap, strong light-matter interaction, and flexibility. In this review, photodetectors based on 2D nanomaterials are classified with respect to critical element technology (e.g., active channel, contact, interface, and passivation). We discuss key ideas for improving the performance of the 2D photodetectors. In addition, figure-of-merits (responsivity, detectivity, response speed, and wavelength spectrum range) are compared to evaluate the performance of diverse 2D photodetectors. In order to achieve highly reliable 2D photodetectors, in-depth studies on material synthesis, device structure, and integration process are still essential. We hope that this review article is able to render the inspiration for the breakthrough of the 2D photodetector research field.

Comparison of marginal gap of monolithic CAD/CAM-generated crowns according to the ceramic materials for CEREC system (CEREC system에서 사용하는 세라믹 소재로 가공된 CAD/CAM 전부도재관의 변연간격 비교분석)

  • Kim, Jae-Hong;Kim, Ki-Baek;Kim, Sa-Hak
    • Journal of Technologic Dentistry
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    • v.38 no.3
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    • pp.119-125
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    • 2016
  • Purpose: The purpose of this study is to evaluate the marginal gap of all-ceramic crowns fabricated by CEREC$^{(R)}$ in-office CAD/CAM system. Methods: The mandibular first molar was selected as the abutment for the experiments. Thirty working models were prepared. VITA Mark II(VM) and VITA Enamic(VE), LAVA Ultimate(LU) blocks were milled using CEREC MCXL with CEREC 3D system to construct 10 crowns for each groups. To measure marginal gap, milled restorations were examined under digital microscope with scale under 160x magnifications. The results were statistically analyzed using the one-way ANOVA and Tukey's HSD test(${\alpha}=0.05$). Results: There was no significant difference in the marginal gap regarding to ceramic materials(p>0.05). Conclusion: Single crowns fabricated using CEREC in-office CAD/CAM system provided clinically acceptable marginal gap. This confirmed that the type of ceramic material used does not determine the precision of fit of a prosthesis.

A Study on the Dielectric Properties of the $Pb(Mb_{1/3}Nb_{2/3})O_3$-$BaTiO<_3$-$CaZrO<_3$Ceramics ($Pb(Mb_{1/3}Nb_{2/3})O_3$-$BaTiO<_3$-$CaZrO<_3$세라믹의 유전특성에 관한 연구)

  • 김수하;배선기
    • Electrical & Electronic Materials
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    • v.10 no.10
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    • pp.1041-1047
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    • 1997
  • In this paper the dielectric properties of (0.8-x)Pb(Mb$_{1}$3//Nb/2/3)O$_3$/BaTiO$_3$-CaZrO$_3$(x=0.1, 0.15, 0.2, 0.25) ceramics were investigated. Specimens were prepared by the conventional mixed oxide method and sintering temperature and time were 1000~115$0^{\circ}C$ 2hr, respectively. The structural and dielectric properties with variation of sintering temperature and composition were investigated. All the specimens sintered at 115$0^{\circ}C$ for 2hr showed the highest value of 1043. With increasing the contents of CZ and frequency dielectric constant was decreased and which was decreased with increasing temperature from 3$0^{\circ}C$ to 15$0^{\circ}C$.

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A study on the properties of thermally stimulated current of $(Sr_{0.85}-Ca_{0.15})$$TiO_3$ grain boundary layer ceramic ($(Sr_{0.85}-Ca_{0.15})$$TiO_3$ 입계층 세라믹의 열자력전류 특성에 관한 연구)

  • 김진사;김성열;유영각;최운식;이준웅
    • Electrical & Electronic Materials
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    • v.9 no.4
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    • pp.396-403
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    • 1996
  • In this paper, the (S $r_{0.85}$.C $a_{0.15}$)Ti $O_{3}$ of paraelectric grain boundary layer (GBL) ceramics were fabricated, and the analysis of microstructuye and the thermally stimulated current(TSC) were investigated for understanding effects of GBL's interfacial phenomenon on variations of electrical properties. As a result, the three peaks of .alpha., .alpha. and .betha. were obtained at the temperature of -20 [.deg. C], 20[.deg. C] and 80[.deg. C], respectively. The origins of these peaks are that the .alpha. peak observed at -20[.deg. C] looks like to be ascribed to the ionization excitation from donor level in the grain, and the .alpha.' peak observed at 20[.deg. C] appears to show up by detrap of the trapped carrier of border between the oxidation layer and the grain, and the .betha. peak observed at 80[.deg. C] seems to be resulted from hopping conduction of existing carrier in the trap site of the border between the oxidation and second phase. and second phase.

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Surface and Electrical Properties on EPDM/Silicone Composite Insulator (EPDM/Silicone 복합 절연체의 표면특성과 전기적 특성)

  • Shim, Dae-Sup;Park, Sung-Gyun;Kim, Bum-Jin
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2001.05c
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    • pp.92-95
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    • 2001
  • 고분자 복합체 절연재료는 porcelain 이나 glass 같은 세라믹 소재의 재료와 비교하여 옥외사용 시간의 관점에서 더 뛰어난 특정을 발휘한다. 그러나 노화되었을 때, 이들 옥외용 절연재료의 성질은 발수성이나 흡수성등과 같은 절연재료의 표면특성에 의해 변화한다. 이러한 표면특성의 변화는 누설전류에 의한 트래킹 (tracking), 침식 (erosion) 및 섬락현상(flashover) 등의 유전체 파괴에 이르게 한다. 본 연구에서는 고분자 복합체 절연재료로 널리 이용되고 있는 EPDM의 발수특성을 향상시키기 위해 기존에 이용되던 무기물 첨가제인 alumina hydrate(ATH)이외에 발수성이 뛰어난 실리콘 고무를 상용화제를 이용하여 블렌드하고, 각종 유기 첨가제 및 무기물 보강제를 이용하여 EPDM/Silicone 복합체를 제조하였다. EPDM/Silicone 복합체의 인장강도 및 유전강도는 실리콘의 함량이 증가할수록 낮아졌으며, 촉진 노화시험을 실시한 결과 $120^{\circ}C$까지 인장강도 및 신율을 유지하였다. 유전강도의 측정결과 복합체의 접촉각과 표면에너지 측정결과 Silicone 고무의 함량이 증가할수록 접촉각은 증가하고, 표면에너지는 낮아졌다. 경사평판법에의한 내트래킹성 측정결과 실리콘 함량이 증가할수록 내트래킹성은 우수하였으며, 실리콘 함량이 30%인 복합체에서는 트래킹 및 침식이 진행되지 않았다.

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Analysis of Grinding Characteristics of Ceramic (SiC) Materials (세라믹 소재의 연삭가공 특성 분석)

  • Park, Hwi-Keun;Park, Sang-Hyeon;Park, In-Seung;Yang, Dong-Ho;Cha, Seung-Hwan;Ha, Byeong-Cheol;Lee, Jong-Chan
    • Journal of the Korean Society of Manufacturing Process Engineers
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    • v.17 no.1
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    • pp.16-22
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    • 2018
  • Silicon carbide (SiC) is used in various semiconductor processes because it has superior thermal, mechanical, and electrical characteristics as well as higher chemical and corrosion resistance than existing materials. Due to these characteristics, various manufacturing technologies have been developed for SiC. A recent development among these technologies is Chemical Vapor Deposition SiC (CVD-SiC). Many studies have been carried out on the processing and manufacturing of CVD-SiC due to its different material characteristics compared to existing materials like RB-SiC or Sintered-SiC. CVD-SiC is physically stable and has excellent chemical and corrosion resistance. However, there is a problem with increasing the thickness, because it is manufactured through a deposition process. Additionally, due to its high strength and hardness, it is difficult to subject to machining.

Preparation and ferroelectric properties of the $Pb(Zr_{0.52}Ti_{0.48})O_3$ thin film by Sol-Gel method (SoI-Gel법에 의한 $Pb(Zr_{0.52}Ti_{0.48})O_3$박막의 제조 및 강유전 특성)

  • 정장호;박인길;류기원;배선기;이영희
    • Electrical & Electronic Materials
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    • v.8 no.5
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    • pp.606-610
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    • 1995
  • In this study, Pb(Z $r_{0.52}$ $Ti_{0.48}$) $O_{3}$ ceramic thin films were fabricated from an alkoxide-based by Sol-Gel method. Pb(Z $r_{0.52}$ $Ti_{0.48}$) $O_{3}$ stock solution was made and spin-coated on the Pt/ $SiO_{2}$/Si substrate at 4000[rpm] for 30[sec.]. Coated specimens were chied at 400[.deg. C] for 10[min]. The coating process was repeated 6 times and then heat-treated at 500-800[.deg. C] and 1 hour. The final thickness of the thin films were about 4800[.angs.]. The ferroelectric perovskite phases precipitated under the sintering of 700[.deg. C] for 1 hour. Pb(Z $r_{0.52}$ $Ti_{0.48}$) $O_{3}$ thin films sintered at 700[.deg. C] for 1 hour showed good dielectric and ferroelectric properties.

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A study on the grain growth and PLZT ceramics fabrication by freeze drying method (동결건조법에 의한 PLZT 세라믹제조 및 결정립 성정에 관한 연구)

  • 이성갑;류기원;배선기;이영희
    • Electrical & Electronic Materials
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    • v.1 no.1
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    • pp.35-43
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    • 1988
  • In this study, PLZT ceramics were fabricated by the freeze-drying and normal sintering method. The composition rate of the specimen was selected 9/65/35(La/Zr/Ti) which had good optical and dielectric properties, sintering time was varied 1, 10, 30, 50, 55, 60 and 65(hr) at 1250(.deg.C). After sintering, the optical and dielectric properties were investigated with the grain size. As the result of the experiment, the particle size of the powder prepared by freeze-drying method was less than 1(um). The relative dielectric constant was increased linearly with the sintering time and specimen sintered for 65(hr) had the highest value, 5780. Grain was grown with increasing time, in the case of specimen sintered for 60(hr), the grain size was 8.4(um). Transmittance was increased with the grain size. In the case of 8.4(um) grain size, the transmittance was 56(%). Curie temperature was decreased linearly by the surface-layer effect of space-charge. In the case of grain size, 1.8(um), 8.4(um), curie temperatures were appeared at 100(.deg.C) and 80(.deg.C), respectively.

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Recent Research Trends of Flexible Piezoelectric Nanofibers for Energy Conversion Materials (에너지 변환 소재용 플렉서블 압전 나노섬유 연구 개발 동향)

  • Ji, Sang Hyun;Yun, Ji Sun
    • Ceramist
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    • v.22 no.2
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    • pp.122-132
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    • 2019
  • Wearable electronic devices with batteries must be lightweight, flexible and highly durable. Most importantly, the battery should be able to self-generate to operate the devices without having to be too frequently charged externally. An eco-friendly energy harvesting technology from various sources, such as solar energy, electromagnetic energy and wind energy, has been developed for a self-charging flexible battery. Although the energy harvesting from such sources are often unstable according to the surrounding environment, the energy harvesting from body movements and vibrations has been less affected by the surrounding environment. In this regard, flexible piezoelectric modules are the most attractive solution for this issue, because they convert mechanical energy to electrical energy and harvest energy from the human body motions. Among the various flexible piezoelectric modules, piezoelectric nanofibers have advantages when used as an energy harvester in wearable devices, due to their simple manufacturing process with good applicability to polymers and ceramics. This review focused on diverse flexible piezoelectric nanofibers and discusses their applications as various energy harvesting systems.

Current Status of Nanostructured Thermoelectric Materials for Mid-High Temperature Applications (나노구조 기반 중·고온용 열전소재 연구 동향)

  • Nam, Woo Hyun;Shin, Weon Ho;Cho, Jung Young;Seo, Won-Seon
    • Ceramist
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    • v.22 no.2
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    • pp.133-145
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    • 2019
  • Thermoelectric energy conversion has attracted much attention because it can convert heat into electric power directly through solid state device and vice versa. Current research is aimed at increasing the thermoelectric figure of merit (ZT ) by improving the power factor and reducing the thermal conductivity. Although there have been significant progresses in increasing ZT of material systems composed of Bi, Te, Ge, Pb, and etc. over the last few decades, their relatively high cost, toxicity, and the scarcity have hindered further development of thermoelectrics to expand practical applications. In this paper, we review the current status of research in the fields of nanostructured thermoelectric materials with eco-friendly and low cost elements, such as skutterudites and oxides, for mid-high temperature applications, highlighting the strategies to improve thermoelectric performance.