• Clean Technology
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• v.25 no.1
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• pp.91-97
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• 2019

Oxidative desulfurization (ODS) has received much attention in recent years because refractory sulfur compounds such as dibenzothiophenes can be oxidized selectively to their corresponding sulfoxides and sulfones, and these products can be removed by extraction and adsorption. In this work, The oxidative desulfurization of marine diesel fuel was performed in a batch reactor with hydrogen peroxide ($H_2O_2$) in the presence of various supported heteropoly acid catalysts. The catalysts were characterized by XRD, XRF, XPS and nitrogen adsorption isotherm techniques. Based on the sulfur removal efficiency of promising silica supported heteropoly acid catalysts, the ranking of catalytic activity was: $30\;H_3PW_{12}/SiO_2$ > $30\;H_3PMo_{12}/SiO_2$ > $30\;H_4SiW_{12}/SiO_2$, which appears to be related with their intrinsic acid strength. The $30\;H_3PW_{12}/SiO_2$ catalyst showed the highest initial sulfur removal efficiency of about 66% under reaction conditions of $30^{\circ}C$, $0.025g\;mL^{-1}$ (cat./oil), 1 h reaction time. However, through the recycle test of the $H_3PW_{12}/SiO_2$ catalyst, significant deactivation was observed, which was attributed to the elution of the active component $H_3PW_{12}$. By introducing cesium cation ($Cs^+$) into the $H_3PW_{12}/SiO_2$ catalyst, the stability of the catalyst was improved with changing the solubility, and the $Cs^+$ ion exchanged catalyst could be recycled for at least five times without severe elution.

• Transactions of the Korean Society of Mechanical Engineers A
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• v.41 no.4
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• pp.263-270
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• 2017

The shipbuilding industry uses large stationary tanks to store low-pressure air, which is used to open and close large shut-off valves. However, when supplying air from the tank to a distant valve, there are problems related to the need for supplementary pipes and the pressure drop during transportation. In this study, a portable welded vessel for storing high-pressure nitrogen (11 kg, 10 L, and 50 bar) was designed to prevent air leakage and improve the convenience of workers. This pressure vessel was elliptical to reduce the number of welded parts, which are structurally weak. The thickness and ratio of the major and minor axes of the pressure vessel were calculated to verify its structure stability at the working pressure (50 bar), and that the proposed weight and capacity were satisfactory. The residual stress caused by the welding process was calculated by performing a transient thermal-structural coupled field analysis using the ANSYS parametric design language (APDL), and the fatigue life of the vessel was verified based on the Goodman criterion.

• Journal of the Korean Society of Marine Environment & Safety
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• v.27 no.1
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• pp.179-186
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• 2021

In this study, we attempted to comparatively analyze the structural characteristics of soot generated from marine engines to review the possibility of recycling crankcase soot by classifying it as exhaust soot and crankcase soot. The annealing procedure was performed in an argon gas atmosphere at 2,000℃ and 2,700℃, and Raman spectroscopy and High-Resolution Transmission Electron Microscopy(HRTEM) were used to analyze the structural properties of the samples. Furthermore, digital image processing techniques were utilized to quantitatively analyze the acquired HRTEM images. The Raman analysis demonstrated a relatively high G/D ratio in the exhaust soot and annealing conditions at 2,700℃. In the HRTEM images, both soot were able to identify similar forms of graphite nanostructures, but there were limitations in that they could not quantitatively derive differences in the degree of graphite depending on the type of soot and annealing temperature. Thus, digital image processing quantitatively analyzed the length and tortuosity of the fringe of the HRTEM image, which is consistent with the Raman analysis. This meant that the exhaust soot had a more graphite structure than the crankcase soot, and that annealing at a higher temperature improved the graphite structure. This study confirmed that both the crankcase soot and exhaust soot can be recycled as a graphite materials.

• Journal of the Korean Society of Marine Environment & Safety
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• v.29 no.4
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• pp.363-371
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• 2023

To construct a ship, blocks of various sizes must be moved and erected . In this process, lugs are used such that they match the block fastening method and various functions suitable for the characteristics of each shipyard facility. The sizes and shapes of the lugs vary depending on the weight and shape of the block structures. The structure is reinforced by welding the doubling pads to compensate for insufficient rigidity around the holes where the shackle is fastened. As for the method of designing lugs according to lifting loading conditions, a simple calculation based on the beam theory and structural analysis using numerical modeling are performed. In the case of the analytical method, a standardized evaluation method must be established because results may differ depending on the type of element and modeling method. The application of this ambiguous methodology may cause serious safety problems during the process of moving and turning-over blocks. In this study , the effects of various parameters are compared and analyzed through numerical structural analysis to determine the modeling conditions and evaluation method that can evaluate the actual structural response of the lug. The modeling technique that represents the plate part and weld bead around the lug hole provides the most realistic behavior results. The modeling results with the same conditions as those of the actual lug where only the weld bead is connected to the main body of the lug, showed a lower ulimated strength compared with the results obtained by applying the MPC load. The two-dimensional shell element is applied to reduce the modeling and analysis time, and a safety working load was verified to be predicted by reducing the thickness of the doubling pad by 85%. The results of the effects of various parameters reviewed in the study are expected to be used as good reference data for the lug design and safe working load prediction.

• Journal of Navigation and Port Research
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• v.31 no.5 s.121
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• pp.435-445
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• 2007

Ship structures are thin-walled structures and lots of cutouts, for example, of inner bottom structure, girder, upper deck hatch, floor and dia-frame etc. In the case where a plate has cutout it experiences reduced buckling and ultimate strength and at the same time the in-plane stress under compressive load produced by hull girder bending will be redistributed. In the present paper, we investigated several kinds of perforated stiffened model from actual ship structure and series of elasto-plastic large deflection analyses were performed to investigate into the influence of perforation on the buckling and ultimate strength of the perforated stiffened plate varying the cutout ratio, web height, thickness and type of cross-section by commercial FEA program(ANSYS). Closed-form formulas for predicting the ultimate strength of the perforated stiffened plate are empirically derived by curve fitting based on the Finite Element Analysis results. These formulas are used to evaluate the ultimate strength, which showed good correlation with FEM results. These results will be useful for evaluating the ultimate strength of the perforated stiffened plate in the preliminary design.

• Journal of Convergence for Information Technology
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• v.11 no.2
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• pp.98-106
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• 2021

The paper deals with comparative study on sensitivity analysis using various methods regarding to design of experiments for structure design of an active type DSF (Deck support frame) that was developed for float-over installation of offshore plant. The thickness sizing variables of structure member of the active type DSF were considered the design factors. The output responses were defined from the weight and the strength performances. Various methods such as orthogonal array design, Box-Behnken design, and Latin hypercube design were applied to the comparative study. In order to evaluate the approximation performance of the design space exploration according to the design of experiments, response surface method was generated for each design of experiment, and the accuracy characteristics of the approximation were reviewed. The design enhancement results such as numerical costs, weight minimization, etc. via the design of experiment methods were compared to the results of the best design. The orthogonal array design method represented the most improved results for the structure design of the active type DSF.

• Journal of the Korean Society of Marine Environment & Safety
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• v.21 no.6
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• pp.744-750
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• 2015

In this paper, development of mobile robot for the inspection of hull surface was mentioned. In the sea, it is difficult to proceed with the visual inspection of hull side and thus mobile robot for checking the status could be run with strap-on its surface. To do this, permanent magnet module to generate magnetic force between hull surface and mobile robot, and structure to minimize variance of the force under curvature circumstance were considered on the design. Based on the design, mobile robot with four NdFeB, four driving wheels and image aquisition module was applied. Load experiment to check the adhesive force, slip test during stop state and driving test to measure driving speed were executed. From the experiments 13 Kgf adhesive force was obtained and slip was not happened until 8 Kgf load on the inclined plate. Driving speed of mobile robot was measured at 0.82 m/s corresponding to 6.5 ampere. We confirmed the effectiveness of developed mobile robot by experiments to check its characteristics.

• Clean Technology
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• v.24 no.2
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• pp.127-134
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• 2018

To reduce the environmental pollution by $NO_x$ from ship engine, International maritime organization (IMO) announced Tier III regulation, which is the emmision regulation of ship's exhaust gas in Emission control area (ECA). Selective catalytic reduction (SCR) process is the most commercial $De-NO_x$ system in order to meet the requirement of Tier III regulation. In generally, commercial ceramic honeycomb SCR catalyst has been installed in SCR reactor inside marine vessel engine. However, the ceramic honeycomb SCR catalyst has some serious issues such as low strength and easy destroution at high velocity of exhaust gas from the marine engine. For these reasons, we design to metallic structured catalyst in order to compensate the defects of the ceramic honeycomb catalyst for applying marine SCR system. Especially, metallic structured catalyst has many advantages such as robustness, compactness, lightness, and high thermal conductivity etc. In this study, in order to support catalyst on metal substrate, coating slurry is prepared by changing binder. we successfully fabricate the metallic structured catalyst with strong adhesion by coating, drying, and calcination process. And we carry out the SCR performance and durability such as sonication and dropping test for the prepared samples. The MFC01 shows above 95% of $NO_x$ conversion and much more robust and more stable compared to the commercial honeycomb catalyst. Based on the evaluation of characterization and performance test, we confirm that the proposed metallic structured catalyst in this study has high efficient and durability. Therefore, we suggest that the metallic structured catalyst may be a good alternative as a new type of SCR catalyst for marine SCR system.

• The Journal of Korean Institute of Communications and Information Sciences
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• v.38C no.3
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• pp.254-262
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• 2013

This paper proposes FMT(Filtered Multi-Tone)-based digital radio implementation algorithms and the results obtained by various field tests especially in terms of transmitter characteristics. In this study, we predefined frame structure and protocols used for the CSTDMA(Carrier Sensing Time Division Multiple Access) scheme, designed digital filters and RF front end to fulfill the system characteristics such as the spectral mask and processing delays given by the Recommendation ITU-R M.1842-1. The proposed system supports exchange of data for e-Navigation with the usage of wider channel of 50-100kHz bandwidth, Turbo coding and FMT modulation. Furthermore, the common Ethernet protocol makes connection to local WLAN(Wireless Local Area Network) on board the ship for other data services.

• Journal of the Korean Society for Precision Engineering
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• v.29 no.12
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• pp.1331-1339
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• 2012

Safety valve used in LNG/LNG-FPSO ships is a high value valve, and it plays an important role in maintaining a fixed level of pressure by emitting LNG gas out of pipes in LNG piping system under the cryogenic and high-pressure condition when the pressure of the system connected with the LNG storage tank and pipes reaches over the set pressure. The structural stability is required for the inner pressure and thermal load because of the cryogenic and high-pressure condition, and a reliability of the safety valve is necessary for impact and deformation by opening the valve. But, the safety valve, which plays a key role for a safety of the transport and storage system, is depended on imports for over 90%, and in domestic production, the design of the valve is performed on the basis of experiences of the works without quantitative analysis for the inner operation characteristics and structural stability of the valve. In this study, impact velocity is calculated by theoretical analysis for obtaining the structural stability of the guide according to the impact load by opening the valve. The shape of the guide and the diaphragm for satisfying the structural stability are suggested and verified by using a thermal-structural analysis.