• Title/Summary/Keyword: 상전하

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Tutorial Review on Membrane Classification and Preparation Methods (멤브레인 분류 및 제조 방법에 대한 튜토리얼 총설)

  • Moon, Seung Jae;Kim, Young Jun;Kim, Jong Hak
    • Membrane Journal
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    • v.32 no.3
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    • pp.198-208
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    • 2022
  • Membrane can selectively separate various substances such as organic substances, liquids, solutes, vapors, gases, ions or electrons according to the separation technology and various uses. Membranes are largely divided into symmetric membranes and asymmetric membranes, and classified into porous and nonporous structure depending on the presence or absence of pores. Also, the interface of the membrane may be molecularly uniform, or chemically or physically non-uniform. Preparation techniques include melt extrusion, stretching, template leaching, track-etching, solution casting, phase inversion, and solution coating method. The prepared membrane can be applied to various applications such as microfiltration, ultrafiltration, nanofiltration, reverse osmosis, gas separation and energy fields. This review provides a tutorial on how to prepare membranes according to the classification and types.

Effect of Heat and Moisture on the Phase Transition in Dimethylammonium-Facilitated CsPbI3 Perovskite (다이메틸암모늄 유도 CsPbI3 페로브스카이트 상의 상전이 거동에 대한 열과 수분의 영향)

  • Sohyun Kang;Seungmin Lee;Jun Hong Noh
    • Korean Journal of Materials Research
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    • v.33 no.8
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    • pp.344-351
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    • 2023
  • Cesium lead iodide (CsPbI3) with a bandgap of ~1.7 eV is an attractive material for use as a wide-gap perovskite in tandem perovskite solar cells due to its single halide component, which is capable of inhibiting halide segregation. However, phase transition into a photo inactive δ-CsPbI3 at room temperature significantly hinders performance and stability. Thus, maintaining the photo-active phase is a key challenge because it determines the reliability of the tandem device. The dimethylammonium (DMA)-facilitated CsPbI3, widely used to fabricate CsPbI3, exhibits different phase transition behaviors than pure CsPbI3. Here, we experimentally investigated the phase behavior of DMA-facilitated CsPbI3 when exposed to external factors, such as heat and moisture. In DMA-facilitated CsPbI3 films, the phase transition involving degradation was observed to begin at a temperature of 150 ℃ and a relative humidity of 65 %, which is presumed to be related to the sublimation of DMA. Forming a closed system to inhibit the sublimation of DMA significantly improved the phase transition under the same conditions. These results indicate that management of DMA is a crucial factor in maintaining the photo-active phase and implies that when employing DMA designs are necessary to ensure phase stability in DMA-facilitated CsPbI3 devices.

Effect of Li2CO3 Doping on Phase Transition and Piezoelectric Properties of 0.96K0.5Na0.5NbO3-0.04SrTiO3 Ceramics (0.96K0.5Na0.5NbO3-0.04SrTiO3 세라믹스의 상전이와 압전 특성에 대한 Li2CO3 도핑 효과)

  • Jae Young Park;Trang An Duong;Sang Sub Lee;Chang Won Ahn;Byeong Woo Kim;Hyoung-Su Han;Jae-Shin Lee
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.36 no.5
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    • pp.513-519
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    • 2023
  • It was reported that a tetragonal phase can be stabilized with maintaining good piezoelectric properties when Na0.5K0.5NbO3 (KNN) is modified with 0.06 mol SrTiO3. However, such a high amount of SrTiO3 leads not only to poor sinterability but low Curie temperature (TC). To maintain high TC with good piezoelectric properties in KNN-based lead-free piezoelectric ceramics, this study investigates the effect of Li-doping on the dielectric and piezoelectric properties of 0.96Na0.5K0.5NbO3-0.04SrTiO3 (KNN-4ST) ceramics. As a result, the orthorhombic-tetragonal phase transition was observed at 2 mol% Li2CO3 modified KNN-4ST ceramics, whose TC, d33 and kp values are 328℃, 165pC/N and 0.33, respectively.

Analysis of freeze-thaw conditions of soil using surface state factor and synthetic aperture radar (지표상태인자와 영상레이더를 활용한 토양의 동결-융해 상태 분석)

  • Yonggwan Lee;Jeehun Chung;Wonjin Jang;Wonjin Kim;Seongjoon Kim
    • Proceedings of the Korea Water Resources Association Conference
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    • 2023.05a
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    • pp.53-53
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    • 2023
  • 본 연구에서는 토양의 동결-융해 상태 구분을 위해 영상레이더(Synthetic Aperture Radar) 자료를 활용해 지표상태인자(Surface State Factor, SSF)를 산정하고, 관측 토양수분 자료 및 지표면 온도(Land Surface Temperature, LST) 자료와의 비교를 통해 SSF의 정확도를 분석하였다. SSF 산정은 용담댐 유역을 포함한 인근 40×50 km2의 영역(N35°35'~36°00', E127°20'~127°45')에 대한 9개의 토양수분 관측지점(계북, 천천, 상전, 안천, 부귀, 주천, 장수읍, 진안읍, 무주읍)을 대상으로 연구를 수행하였으며, 이를 위해 2015년부터 2019년까지의 해당 지점의 토양수분 관측자료와 Sentinel-1A Interferometric Wide swath (IW) 모드의 Ground Range Detected (GRD) product를 구축하여 활용하였다. SSF 자료의 정확도 분석을 위한 토양수분 관측지점에 대한 LST 자료는 인근 7개 기상관측소 지점(전주, 금산, 임실, 남원, 장수, 함양군, 거창)의 관측자료로부터 역거리가중법을 통해 산정하였다. Receiver Operating Characteristic (ROC) 분석을 통한 겨울철(12-2월)의 SSF 산정 정확도를 평가한 결과, 지표면 온도 자료와의 평균 정확도는 0.75(0.48-0.87)로 나타났다. 그러나, 지표면 온도가 0℃ 이상일 때 SSF가 동결 상태로 나타나는 오차가 관측되었으며, 이는 여름철 후방산란계수의 평균값과 겨울철 후방산란계수의 평균값을 통해 산정하는 SSF 산정 수식의 특성 때문으로 이 값의 조정을 통해 오차를 개선할 수 있음을 보였다.

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A Study on Development of Superconducting Wires for a Fault Current Limiter (한류기용 초전도 선재개발에 관한 연구)

  • Hwang, Kwang-Soo;Lee, Hun-Ju;Moon, Chae-Joo
    • The Journal of the Korea institute of electronic communication sciences
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    • v.17 no.2
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    • pp.279-290
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    • 2022
  • A superconducting fault current limiter(SFCL) is a power device that exploits superconducting transition to control currents and enhances the flexibility, stability and reliability of the power system within a few milliseconds. With a high phase transition speed, high critical current densities and little AC loss, high-temperature superconducting (HTS) wires are suitable for a resistive-type SFCL. However, HTS wires due to the lack of optimization research are rather inefficient to directly apply to a fault current limiter in terms of the design and capacity, for the existing method relied the characteristics. Therefore, in order to develop a suitable wire for an SFCL, it is necessary to enhance critical current uniformity, select optimal stabilizer materials and conducted research on the development of uniform stabilizer layering technology. The high temperature superconducting wires manufactured by this study get an average critical current of 804 A/12mm-width at the length of 710m; therefore, conducted research was able to secure economic performance by improving efficiency, reducing costs, and reducing size.

Reaction morphology depending on the amounts of HCl and NH4OH and effect of pH on the preparation of TiO2 nanopowder (TiO2 나노분말 제조시 HCI과 NH4OH의 첨가량에 따른 반응양상과 pH의 영향)

  • Lim, Chang Sung;Oh, Won Chun
    • Analytical Science and Technology
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    • v.20 no.4
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    • pp.302-307
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    • 2007
  • The reaction morphology was investigated depending on the amounts of HCl and $NH_4OH$, and the effect of pH was studied on the preparation of $TiO_2$ nanopowders. $TiO_2$ nanopowder was prepared using a titanium tetra-isopropoxide. Subsequently, the effect of pH on the characteristics of the prepared $TiO_2$ nanopowder was evaluated depending on the amounts of the catalysts such as HCl and $NH_4OH$. The morphology and phase transformation of $TiO_2$ powder prepared by hydrolysis of titanium tetra-isopropoxide were strongly influenced by the presence of the catalysts. In the case of using $NH_4OH$, the morphology of the $TiO_2$ powder exhibited powder form. For the HCl catalyst, it showed bulk or granule form. The phase transformations of amorphous $Ti(OH)_4$ to anatase $TiO_2$ and the anatase to rutile was significantly influenced by the kind and amount of thecatalysts.

Undrained Shear Behavior of Cemented Sand (고결모래의 비배수 전단거동)

  • Lee, Moon Joo;Choi, Sung Kun;Hong, Sung Jin;Lee, Woo Jin
    • KSCE Journal of Civil and Environmental Engineering Research
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    • v.26 no.3C
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    • pp.181-190
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    • 2006
  • The behavior of artificially cemented sands were investigated by undrained triaxial test of isotropically consolidated sample. The cementation were induced by gypsum that is generally used for the aitificial cementation of sands. The gypsum of 5~20%(sand weight) were included in the sand and cured in the mold under the overburden pressure 55kPa. The yielding strength and stiffness of cemented sand were increased as the degree of cementation. And the dilation of sand was restricted by the cementation bonds, but after breakage of the bonds, it was increased more abrupt than the uncemented sands. The effective stress path showed that the aspects of effective pore water pressure were changed as the degree of cementation and the relative density. The effective stress ratio of cemented sand in the phase transformation line and the failure line were changed by the cementation. Generally the behavior of cemented sand more influenced by the degree of cementation than the relative density.

The problem on the restortion and performance of "Jainpalkwangdae" (자인팔광대의 복원과 연희적 특징에 따른 문제)

  • Jung, Hyung-ho
    • (The) Research of the performance art and culture
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    • no.19
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    • pp.61-86
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    • 2009
  • Jainpalkwangdae(慈仁八廣大) of Kyungsan area in Kyungbuk province was restored through over 50 years gap. This play basically has the structure of conflict - reconcillation, which is differentiated from a masque and a tightrope walking. The characters of this play are a nobleman, Malttuki (a servant), a legal wife and a second wife. Their personality is deviant from a existing Korean masque. This weird and artificial appearance may be a problem in the process of restoration. Otherwise, it might be a very different transmission type of masque. Therefore, we need to investigate why Jainpalkwangdae is different from a traditional masque.

A.C. servo motor current control parameter measurement strategy using the three phase inverter driver (3상 인버터 구동기를 이용하는 교류 서보전동기의 전류제어 파라미터 계측법)

  • Jung-Keyng Choi
    • The Journal of Korea Institute of Information, Electronics, and Communication Technology
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    • v.16 no.6
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    • pp.434-440
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    • 2023
  • This paper propose the method that measure the main system parameters for current control of a.c. motor adopting the vector control technique. The automatical method that tuning PI control gains for current control of servo motors are used frequently through the information of main system parameters, wire resistance and inductance. In this study, the techniques to measure these two system parameters through the control of 3-phase inverter are presented. These control and measuring method are implemented by measuring output phase current obtained as a results of the step current control using simple proportional feedback input. Moreover, this method use freewheeling current of inverter at special switching mode for measuring inductance. This analytic strategy is could measure and calculate the system parameters without the complex measurement algorithm and new additional measuring circuits. That is could measure the total resistance and total inductance including wiring resistance and conduction resistance of switching devices using real driving circuits to control the motors.

Characterization of Microbial Diversity of Metal-Reducing Bacteria Enriched from Groundwater and Reduction/Biomineralization of Iron and Manganese (KURT 지하심부 지하수 내 토착 금속환원미생물의 종 다양성 및 철/망간의 환원과 생광물화작용)

  • Kim, Yumi;Oh, Jong-Min;Jung, Hea-Yeon;Lee, Seung Yeop;Roh, Yul
    • Economic and Environmental Geology
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    • v.47 no.4
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    • pp.431-439
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    • 2014
  • The purposes of this research were to investigate the enrichment of metal-reducing bacteria from KURT groundwater and the identification of the microbial diversity by 16S rRNA as well as to examine microbial Fe(III)/Mn(IV) reduction and to analyze morphological features of interactions between microbes and precipitates and their mineralogical composition. To cultivate metal-reducing bacteria from groundwater sampled at the KURT in S. Korea, different electron donors such as glucose, acetate, lactate, formate, pyruvate and Fe(III)-citrate as an electron accepter were added into growth media. The enriched culture was identified by 16S rRNA gene sequence analysis for the diversity of microbial species. The effect of electron donors (i.e., glucose, acetate, lactate, formate, pyruvate) and electron acceptors (i.e., akaganeite, manganese oxide) on microbial iron/manganese reduction and biomineralization were examined using the 1st enriched culture, respectively. SEM, EDX, and XRD analyses were used to determine morphological features, chemical composition of microbes and mineralogical characteristics of the iron and manganese minerals. Based on 16S rRNA gene analysis, the four species, Fusibacter, Desulfuromonas, Actinobacteria, Pseudomonas sp., from KURT groundwater were identified as anaerobic metal reducers and these microbes precipitated metals outside of cells in common. XRD and EDX analyses showed that Fe(III)-containing mineral, akaganeite (${\beta}$-FeOOH), reduced into Fe(II)/Fe(III)-containing magnetite ($Fe_3O_4$) and Mn(IV)-containing manganese oxide (${\lambda}-MnO_2$) into Mn(II)-containing rhodochrosite ($MnCO_3$) by the microbes. These results implicate that microbial metabolism and respiratory activities under anaerobic condition result in reduction and biomineralization of iron and manganese minerals. Therefore, the microbes cultivated from groundwater in KURT might play a major role to reduce various metals from highly toxic, mobile to less toxic, immobile.