• Title/Summary/Keyword: 복합신소재구조

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Observation of Diverse Aluminum Oxide Structures in a Phosphoric Acid Solution according to the Applied Anodization Voltage (인산용액에서 양극산화 인가전압에 따른 알루미늄 산화피막 성장 관찰)

  • Jeong, Chanyoung
    • Journal of the Microelectronics and Packaging Society
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    • v.26 no.1
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    • pp.35-39
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    • 2019
  • To date, porous alumina structures have been implemented by electrochemical anodization technique. The anodizing methods can easy to make a porous aluminum oxide film with a regular arrangement, but oxide film with complex structure type such as pillar-on-pore is relatively difficult to implement. Therefore, this study aims to observe the change of anodized oxide pore size, thickness, and structure in a phosphoric acid solution according to applied anodization voltage conditions. For the implementation of hybrid composite oxide structures, it is possible to create by modulating anodization voltage. The experimental conditions were performed at the applied anodization voltage of 100 V and 120 V in 10% phosphoric acid solution, respectively. The experimental results were able to observe the structure of oxides in the form of porous and composite structures (pillar-on-pore), depending on each condition.

Synthesis of porous-structured (Ni,Co)Se2-CNT microsphere and its electrochemical properties as anode for sodium-ion batteries (다공성 구조를 갖는 (Ni,Co)Se2-CNT microsphere의 합성과 소듐 이차전지 음극활물질로서의 전기화학적 특성 연구)

  • Yeong Beom Kim;Gi Dae Park
    • Clean Technology
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    • v.29 no.3
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    • pp.178-184
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    • 2023
  • Transition metal chalcogenides have garnered significant attention as anode materials for sodium-ion batteries due to their high theoretical capacity. Nevertheless, their practical application is impeded by their limited lifespan resulting from substantial volume expansion during cycling and their low electrical conductivity. To tackle these issues, this study devised a solution by synthesizing a nanostructured anode material composed of porous CNT (carbon nanotube) spheres and (Ni,Co)Se2 nanocrystals. By employing spray pyrolysis and subsequent heat treatments, a porous-structured (Ni,Co)Se2-CNT composite microsphere was successfully synthesized, and its electrochemical properties as an anode for sodium-ion batteries were evaluated. The synthesized (Ni,Co)Se2-CNT microsphere possesses a porous structure due to the nanovoids that formed as a result of the decomposition of the polystyrene (PS) nanobeads during spray pyrolysis. This porous structure can effectively accommodate the volume expansion that occurs during repeated cycling, while the CNT scaffold enhances electronic conductivity. Consequently, the (Ni,Co)Se2-CNT anode exhibited an initial discharge capacity of 698 mA h g-1 and maintained a high discharge capacity of 400 mA h g-1 after 100 cycles at a current density of 0.2 A g-1.

Estimation on Clamping Force of High Strength Bolts Considering Temperature Variable of Both Site conditions and Indoor Environments (실내환경과 건설현장 온도변수를 고려한 고력볼트 체결력 예측)

  • Nah, Hwan-Seon;Lee, Hyeon-Ju
    • Journal of the Korean Society for Advanced Composite Structures
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    • v.6 no.3
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    • pp.32-40
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    • 2015
  • The torque shear high strength bolt is clamped normally at the break of pin-tail specified. However, the clamping forces on slip critical connections do not often meet the required tension, as it considerably fluctuates due to torque coefficient dependent on lubricant affected temperature. In this study, the clamping tests of torque shear bolts were conducted independently at indoor conditions and at construction site conditions. During last six years, temperature of candidated site conditions was recorded from $-11^{\circ}C$ to $34^{\circ}C$. The indoor temperature condition was ranged from $-10^{\circ}C$ to $50^{\circ}C$ at each $10^{\circ}C$ interval. As for site conditions, the clamping force was reached in the range from 159 to 210 kN and the torque value was from 405 to $556 N{\cdot}m$. The range of torque coefficient at indoor conditions was analyzed from 0.126 to 0.158 while tensions were indicated from 179 to 192 kN. The torque coefficient at site conditions was ranged from 0.118 to 0.152. Based on this test, the variable trends of torque coefficient, tension subjected temperature can be taken by statistic regressive analysis. The variable of torque coefficient under the indoor conditions is $0.13%/^{\circ}C$ while it reaches $2.73%/^{\circ}C$ at actual site conditions. When the indoor trends and site conditions is combined, the modified variable of torque coefficient can be expected as $0.2%/^{\circ}C$. and the modified variable of tension can be determined as $0.18%/^{\circ}C$.

Study on the Field Construction of Semi-Integral Bridge with PSC Girder Integrating End-Diaphragm (단부격벽 일체형 PSC거더를 갖는 반일체식 교량의 시공성 연구)

  • Park, Jong-Myen;Kim, Jin-Bae;Jun, Sung-Yong;Kim, Chung-Sik;You, Sung-Kun;Park, Joong-Bai;Lim, Jung-Hoon
    • Journal of the Korean Society for Advanced Composite Structures
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    • v.5 no.2
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    • pp.21-26
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    • 2014
  • This paper introduces general concepts of jointless bridges and field construction case of semi-integral bridge with psc girder integrating end-diaphragm. The expansion joints need to satisfy thermal and safety conditions of bridges. General bridges with joints have some problems, which are frequently replacement cycle time from mechanical damage or unstable movement, maintenance cost and more. To solve these problems, Integral Abutment Bridges(IAB) have been applied overseas in the 1930s. In Korea, first IAB was constructed in the early 2000s and precast IAB systems was invented and applied lately. Kyungshin overpass bridge in Incheon is the Semi-IAB constructed, the span length is 2@35=70m and the width is 13.9m. The original plan was to use general joint bridge but design field changed with expectations for advanced economic estimation and maintenance. This changed method of B.I.B bridge construction provided not only workability, construction cost but also safety improvement at the same time.

Local Buckling Strength of PFRP I-Shape Compression Members Obtained by LRFD Design Method and Closed-Form Solution (하중저항계수설계법 및 정밀해법에 의한 PFRP I형 단면 압축재의 국부좌굴강도)

  • Choi, Jin-Woo;Seo, Su-Hong;Joo, Hyung-Joong;Yoon, Soon-Jong
    • Journal of the Korean Society for Advanced Composite Structures
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    • v.5 no.2
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    • pp.1-8
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    • 2014
  • Fiber reinforced polymeric plastic (FRP) materials have many advantages over conventional structural materials, i.e., high specific strength and stiffness, high corrosion resistance, right weight, etc. Among the various manufacturing methods, pultrusion process is one of the best choices for the mass production of structural plastic members. Since the major reinforcing fibers are placed along the axial direction of the member, this material is usually considered as an orthotropic material. However, pultruded FRP (PFRP) structural members have low modulus of elasticity and are composed of orthotropic thin plate components the members are prone to buckle. Therefore, stability is an important issue in the design of the pultruded FRP structural members. Many researchers have conducted related studies to publish the design method of FRP structures and recently, referred to the previous researches, pre-standard for LRFD of pultruded FRP structures is presented. In this paper, the accuracy and suitability of design equation for the local buckling strength of pultruded FRP I-shape compression members presented by ASCE are estimated. In the estimation, we compared the results obtained by design equation, closed-form solution, and experiments conducted by previous researches.

Strength Evaluation of Bolt Arrangement in PFRP Bolted Connection with 2 Bolts (2개의 볼트를 가지는 PFRP 볼트연결부의 볼트배치에 따른 강도평가)

  • Lee, Young-Geun;Kim, Sun-Hee;Won, Yong-Seok;Cheon, Jin-Uk;Shin, Kwang-Yeoul;Yoon, Soon-Jong
    • Journal of the Korean Society for Advanced Composite Structures
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    • v.5 no.3
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    • pp.17-22
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    • 2014
  • Fiber reinforced plastic (FRP) structural shapes are readily available in civil engineering applications. Among many manufacturing techniques used for FRP structural shapes, pultrusion process is one of the most widely used techniques in civil engineering applications. Pultrusion is a manufacturing process for producing continuous lengths of reinforced polymeric plastic structural shapes with constant cross-section. Pultruded composites are attractive for structural applications because of their continuous mass production with excellent mechanical properties. This paper presents the results of investigations pertaining to the bolted connection with two bolts for the pultruded FRP (PFRP) structural members. PFRP bolted connection tests were conducted with end distance to bolt diameter ratio ($e_1/d_b$) and two types of bolt pattern such as horizontal (Pattern A) and vertical arrangement (Pattern B). As a result, it is found that the $e_1/d_b$ is recommended as the ratio of 4. In addition, it is also found that the bearing strengths at failure of the Pattern A and Pattern B have a similar value.

A Study on the Secure Plan of Clamping Force according to the Variation of Torque-Coefficient in Torque-Shear High Strength Bolts (토크전단형 고력볼트의 토크계수 변동에 따른 체결축력 확보방안에 관한 연구)

  • Lee, Hyeon-Ju;Nah, Hwan-Seon;Choi, Sung-Mo
    • Journal of the Korean Society for Advanced Composite Structures
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    • v.5 no.3
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    • pp.8-16
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    • 2014
  • Torque control method and turn of nut method are specified as clamping method of high strength bolts in the steel construction specifications. Quality control of torque coefficient is essential activity because torque control method, which is presently adopted as clamping method in domestic construction sites, is affected by variation of torque coefficient. The clamping of torque shear bolt is based on KS B 2819. It was misunderstood that the tension force of the TS bolt was induced generally at the break of pin-tail specified. However, the clamping forces on slip critical connections do not often meet the intended tension, as it considerably varies due to torque coefficient dependent on the environmental factors and temperature variables despite the break of the pin tail.This study was focused to evaluate the effect of environmental factors and errors of installing bolts during tightening high strength bolts. The environmental parameters were composed of 'wet' condition, 'rust' condition, 'only exposure to air' condition. And the manufacture of trial product was planned to identify the induced force into the bolts. The algorithm for a trial product was composed of the relation between electricity energy taken from torque shear wrench and tension force from hydraulic tension meter.

Influence of Measurements of Lathe Scrap on the Characteristics of Fiber Reinforced Cementitious Composites (섬유보강 시멘트 복합체의 특성에 미치는 선반 스크랩 규격의 영향)

  • Kwon, Soon-Oh;Bae, Su-Ho;Lee, Hyun-Jin;Kim, Sung-Wook;Park, Jung-Jun
    • Journal of the Korean Society for Advanced Composite Structures
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    • v.6 no.2
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    • pp.70-76
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    • 2015
  • It should be noted that the use of the lathe scrap for making fiber reinforced cementitious composites(FRCCs) raised friendly environmental effect as well as economy because the lathe scrap is a by-product of steel manufactures and is occurred when lathe and milling works of them are conducted to process steel manufactures. Thus, the purpose of this research is to investigate the effect of measurements of lathe scrap on the characteristics of FRCCs. For this purpose, various lathe scraps were collected from processing plants of metal, and then these were processed 10mm, 20mm, and 40mm in lengths for 2mm and 4mm in widths, respectively. FRCCs containing lathe scraps were made according to their widths and lengths, and then characteristics such as the workability, compressive strength, and flexural strength of those were evaluated. As a result, it was observed from the test results that the optimum measurements of the lathe scrap for manufacturing FRCCs was 2mm in width and 40mm in length.

Resistance against Chloride Ion and Sulfate Attack of Cementless Concrete (무시멘트 콘크리트의 염소이온 침투 및 황산염 침투 저항성)

  • Lee, Hyun-Jin;Bae, Su-Ho;Kwon, Soon-Oh;Lee, Kwang-Myong;Jeon, Jun-Tai
    • Journal of the Korean Society for Advanced Composite Structures
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    • v.6 no.2
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    • pp.63-69
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    • 2015
  • It has been well known that concrete structures exposed to chloride and sulfate attack environments lead to significant deterioration in their durability due to chloride ion and sulfate ion attack. The purpose of this experimental research is to evaluate the resistance against chloride ion and sulfate attack of the cementless concrete replacing the cement with ground granulated blast furnace slag. For this purpose, the cementless concrete specimens were made for water-binder ratios of 40%, 45%, and 50%, respectively and then this specimens were cured in the water of $20{\pm}3^{\circ}C$ and immersed in fresh water, 10% sodium sulfate solution for 28 and 91 days, respectively. To evaluate the resistance to chloride ion and sulfate attack for the cementless concrete specimens, the diffusion coefficient for chloride ion and compressive strength ratio, mass change ratio, and length change ratio were measured according to the NT BUILD 492 and JSTM C 7401, respectively. It was observed from the test results that the resistance against chloride ion and sulfate attack of the cemetntless concrete were comparatively largely increased than those of OPC concrete with decreasing water-binder ratio.

An Experimental Study for Strength Improvement of Soft Ground using Hardening Agent and Silicate Mineral Power (수용성 고화재와 규산염광물 결합재를 활용한 지반개량재의 실험적 연구)

  • Kim, Sung-Wook;Choi, Eun-Kyeong;Cho, Jinwoo;Lee, JuHyung;Lee, Kyu-Hwan
    • Journal of the Korean Society for Advanced Composite Structures
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    • v.6 no.4
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    • pp.8-15
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    • 2015
  • The demand for environmental consideration is on the increase in civil engineering. This study focuses on the development of technology to reduce the use of carbonate cement and improve its performance by using a silicate mineral and hardening agents, and presents the test results for the demonstrative evaluation of the properties of the raw material. Highly active feldspar was used as a binder to augment the bonding of the carbonate cement, and their change in strength was observed after test piece construction with the addition of soluble hardening agent. The uniaxial compression strength of the test piece of the general Portland cement with the addition of 0.5% soluble hardening agent, showed an increase by 33% and that of the test piece of cement with the addition of 70% substituted with feldspar increased by 28%. The strength of viscous soil; classified as soft ground, showed an increase of a maximum of 1.7 times when it was mixed with cement and solidifier depending on the curing period. These tests confirmed that a soluble solidifier is effective for improving the strength of a cement binder and that the highly active feldspar can be used as a binder.