• Title/Summary/Keyword: 모드 변이

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전기장에 의한 물 분자의 O-H 신축 진동수 변화

  • Im, Jong-Hyeon;Jo, Dae-Heum;Lee, Jin-Yong
    • Proceeding of EDISON Challenge
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    • 2016.03a
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    • pp.8-14
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    • 2016
  • 화학 결합을 이해하는 중요한 방법 중 하나는 결합이 가지는 고유한 진동 모드를 분석하는 것이다. 진동 모드의 변화를 관측함으로써 다양한 외부 자극과 분자의 상호작용에 대한 연구도 가능하다. 본 연구에서는 전기장이 가해진 물 분자의 진동 모드 변화를 분석함으로써 전기장과 물분자의 상호작용이 화학 결합에 미치는 영향을 알아보았다. 물 분자의 특정 O-H 결합 방향으로 전기장을 걸어주었을 때 신축 진동수의 변화를 살펴봄으로써 결합의 변화를 분석했다. 전기장에 따른 결합의 진동수 변화를 vibrational Stark effect (VSE)라 하고 그 정도를 Stark tuning rate ${\Delta}{\mu}$ ($={\Delta}v/{\Delta}E$, ${\Delta}v$ :진동수의 변화, ${\Delta}E$: 전기장의 변화)로 정의한다. 이때 Stark tuning rate에 영향을 미치는 요소는 전기장에 의한 (1) 분자 구조 변화(geometric effect)와 (2) 전자 구조의 분극현상(polarization effect)으로 나누어 생각해 볼 수 있다. 본 연구에서 물 단일체, 이중체, 사중체의 O-H 결합에 대해 살펴본 결과, VSE 효과에 주로 영향을 미치는 것은 전기장에 의한 구조 변화인 것으로 나타났다. 이를 통해 전기장이 주는 전자 구조 분극 효과는 크지 않지만 이를 통해 유발되는 구조 변화에 의해 진동수 (또는 화학 결합의 세기)가 크게 변한다는 것을 알 수 있다. 그렇기 때문에 수소 결합 안정화로 인해 구조 변화가 쉬운 물 이중체, 사중체에서 VSE 효과가 크게 나타났다. 추가적으로 물 클러스터에서 형성되는 내부 전기장과 O-H 결합의 포텐셜 비조화성(anharmonicity)이 VSE에 주는 영향에 대한 연구도 수행하였다.

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Resonance Scattering Characteristics of Multi-layered Dielectric Gratings under Conical Incidence (원추형 입사에서 다층 유전체 격자구조의 공진 산란특성)

  • Ho, Kwang-Chun
    • The Journal of the Institute of Internet, Broadcasting and Communication
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    • v.22 no.5
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    • pp.123-128
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    • 2022
  • Applying rigorous modal transmission-line theory (MTLT), the properties of resonant diffraction gratings under conical light incidence is investigated. The mode vectors pertinent to resonant diffraction under conical mounting vary less with incident angle than those associated with diffraction gratings in classical mounting. Furthermore, as the evanescent diffracted waves drive the leaky modes responsible for the resonance effects, the conical mounting imbues diffraction gratings with larger angular tolerance than their classical counterparts. Based on these concepts, the angular-spectral and wavelength-spectral performance of resonant diffraction gratings in conical and classical mounts by numerical calculations with spectra found for conical incidence are quantified. These results will be useful in various applications demanding resonant diffraction gratings that are efficient and physically sparse.

A Study on the Resonant Characteristics of a Tonpilz Transducer with a Fixed Tail Mass (후면추 고정형 Tonpilz 트랜스듀서의 공진 특성 연구)

  • Kim, Jin-Wook;Kim, Won-Ho;Joh, Chee-Young;Roh, Yong-Rae
    • The Journal of the Acoustical Society of Korea
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    • v.29 no.7
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    • pp.439-447
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    • 2010
  • In this paper, the resonant characteristic of a Tonpilz transducer with a fixed tail mass has been researched and the feasibility to utilize the transducer in that resonant frequency has been analyzed. The additional resonance is occurred by adhering an elastic tube to the tail mass of a conventional Tonpilz transducer and fixing the other end of the tube. The characteristic of this low resonant mode is analyzed by means of the finite element method, then it is shown that this mode is affected by the variation of the stiffness of the tube as well as the mass of the head mass and tail mass. Based on the analysis results, the Tonpilz transducer is designed to meet specific performance conditions.

Steep subthreshold slope at elevated temperature in junctionless and inversion-mode MuGFET (고온에서 무접합 및 반전모드 MuGFET의 문턱전압 이하에서 급격히 작은 기울기 특성)

  • Lee, Seung-Min;Park, Jong-Tae
    • Journal of the Korea Institute of Information and Communication Engineering
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    • v.17 no.9
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    • pp.2133-2138
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    • 2013
  • In this paper, the variation of a steep subthreshold slope at elevated temperature in nanowire n-channel junctionless and inversion mode MuGFETs has been compared. It has been observed that the subthreshold slopes are increased with the increase of the operation temperature in junctionless and inversio-mode transistors. The variation of a subthreshold slope with operation temperature is more significant in junctionless transistor than inversion-mode transistor. The temperature dependence on the variation of a subthreshold slope for different fin widths shows a similar behavior regardless of fin width. From the temperature dependence on the variation of a subthreshold slope for different substrate biases, it has been observed that the variation of a subthreshold slope is less significant when the substrate bias was applied. It is worth noting that one can achieve a subthreshold slope of below 41mV/dec at elevated temperature of 400K using the junctionless MuGFETs with a positive substrate bias.

2×2Ti:LiNbO3 Integrated Optical Add/Drop Multiplexers utilizing Strain-Optic Effect (스트레인광학효과를 이용한 2×2Ti:LiNbO3 삽입/분기 집적광학 멀티플렉서)

  • Jung, Hong-Sik;Choi, Yong-Wook
    • Korean Journal of Optics and Photonics
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    • v.17 no.5
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    • pp.430-436
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    • 2006
  • Polarization-independent $Ti:LiNbO_3\;2{\times}2$ optical add/drop multiplexer for the 1550nm wavelength region is fabricated. The device consists of two input waveguides, two polarization beam splitters. two polarization conversion/electrooptic tuning waveguide sections, and two output waveguides. The single mode channel waveguides for both TE and TM polarizations are fabricated on a x-cut $Ti:LiNbO_3$substrate by Ti diffusion. Spectral section is based on phase-matched polarization conversion due to shear strain induced by a thick $SiO_2$ grating overlay film. An applied voltage tunes the device by changing the waveguide birefringence, hence the optical wavelength at which most efficient polarization conversion occurs. Tuning rate of 0.094nm/V with a maximum range of 17nm has been obtained. The nearest side-lobe is about 8.2dB. The FWHM is 3.72nm.

VARIABLE STARS IN THE REGION OF CYG OB3 ASSOCIATION CENTERED ON THE OPEN CLUSTER NGC 6871 I: δ SCUTI TYPE STARS (산개성단 NGC 6871을 중심으로 한 Cyg OB3 성협 영역의 변광성 I: δ Scuti 형 변광성)

  • Jeon, Young-Beom;Lee, Uiryeol;Park, Yoon-Ho;Kim, Donghyeon;Jang, Hyeeun;Cho, Sungyoon
    • Publications of The Korean Astronomical Society
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    • v.27 no.5
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    • pp.399-409
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    • 2012
  • As a part of the short-period variability survey (SPVS) at Bohyunsan Optical Astronomy Observatory, we obtained time-series BV CCD images in the region of Cyg OB3 association centered on the open cluster NGC 6871. The observations were performed for 18 nights from September 5, 2008 to September 1, 2009. We found 15 short-period variable stars in the region. They are ${\delta}$ Scuti type stars belonging to the local spiral arm, Orion spur. Among them, only two stars were previously known, and the rest are newly discovered ones. In this paper, we have performed a multiple-frequency analysis to determine frequencies of the 15 ${\delta}$ Scuti type stars, using the discrete Fourier transform and linear least-square fitting methods. One of the newly discovered variable stars is a double-mode ${\delta}$ Scuti type star with the fundamental and the first overtone modes, and two are high amplitude ${\delta}$ Scuti stars.

Effects of the Shape and the Absorption in Reverberation Rooms on the Space Variances of the Sound Pressure Level (잔향실의 형상(치수비)과 내부표면 흡음율이 음압의 공간편차에 미치는 영향)

  • 최석주;장영자
    • The Journal of the Acoustical Society of Korea
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    • v.18 no.4
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    • pp.65-70
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    • 1999
  • To examine the space variances of the sound pressure level for five different types (normal frequency spacing) of reverberation rooms, simulations were conducted using the Finite Element Method. In case of infinite surface impedance, nonrectangular reverberation rooms showed small Standard Deviations across the band of frequency, and in case of finite surface impedance, ideal rectangular reverberation rooms showed the similar results as those in irregular shaped reverberation rooms.

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A Study on the ATM Interface of Satellite TDMA Method for BISDN Services (BISDN 서비스를 위한 위성 TDMA 방법의 ATM 접속 기술 연구)

  • 홍완표;김정호;라극환
    • Journal of the Korean Professional Engineers Association
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    • v.30 no.1
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    • pp.125-136
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    • 1997
  • The satellite communications system application to the Broadband ISDN(BISDN) is now being studied. Asynchronous transfer mode(ATM) is the target for BISDN and makes it possible to offer multimedia services on the simple network structure. This paper clarifies the required functions to the ATM interface between the terrestrial network and satellite TDMA system to compensate cell delay variation caused by satellite link, to improve the transmission efficiency, to do usage parameter control and to configure TDMA/ATM hardware interface.

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Analysis of Simply Supported Rectangular Plate Using Spectral Finite Element Method (스펙트럴유한요소법을 이용한 네 변이 단순지지 된 직사각형평판의 진동해석)

  • Jo, Kyung-Lim;Hong, Suk-Yoon;Song, Ji-Hun;Kim, Dong-Jin
    • Proceedings of the Korean Society for Noise and Vibration Engineering Conference
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    • 2005.11b
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    • pp.85-89
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    • 2005
  • For the analysis of a vibrating two dimensional structure such as the simply supported rectangular plate, Spectral Finite Element Method (SFEM) has been studied. Under the condition that two parallel edges are simply supported at least and the other two edges can be arbitrary, Spectral Finite Element has been developed. Using this element SFEM is applied to the vibrating rectangular plate which all edges are simply supported, and obtain the frequency response function in frequency domain and the dynamic response in time domain. To evaluate these results normal mode method and finite element method (FEM) are also accomplished and compared. It is seen that SFEM is more powerful analysis tool than FEM in high frequency range.

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Performance Analysis of Symbol Timing and Carrier Synchronization in LMDS System (LMDS 시스템에서의 심벌타이밍과 반송파 동기의 성능분석)

  • Lim, Hyung-Rea;Park, Sol;Cho, Byung-Lok
    • Proceedings of the Korean Institute of Information and Commucation Sciences Conference
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    • 1998.11a
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    • pp.383-388
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    • 1998
  • 본 논문에서는 LMDS(Local Multipoint Distributed Services) 시스템의 역방향 채널에서 TDMA(Time Division Multiple Access) 방식으로 ATM(Asynchronous Transfer Mode) 셀을 효율적으로 전송하기 위해 전치부호를 줄일 수 있는 블록복조 알고리즘을 적용한 $\pi$/4 QPSK 변복조 방식 시스템을 제안하고, 블록복조의 동기성능을 향상시키기 위해 새로운 반송파 동기회로를 설계하였다. 제안한 블록동기복조 알고리즘을 적용한 $\pi$/4 QPSK 변복조 방식 시스템은 LMDS 환경에서 ATM 셀 단위의 버스트 데이터로 반송파 위상동기, 심벌 타이밍 동기, 슬롯 타이밍 동기 둥을 수행할 때 전치부호를 아주 적게 사용하므로 효율적인 프레임 전송을 얻어질 수 있도록 하고 있다. 제안한 방식의 성능평가를 위한 모의실험은 LMDS 채널환경과 프레임 구조의 버스트 모드 전송환경에서 심벌 타이밍 동기, 주파수 오프셋, 반송파 위상동기, 페이딩 채널에 따라 수행하였다. 본 논문에서 제안한 블록동기복조 알고리즘을 적용한 $\pi$/40 QPSK 변복조 방식 시스템을 모의수행을 통하여 분석한 결과, 페이딩 환경에서 심벌 타이밍 동기, 주파수 오프셋, 반송파 위상동기할 때 전치부호를 아주 적게까지 줄이더라도 좋은 성능을 발휘함을 확인할 수 있었다.

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