• 제목/요약/키워드: 관계이탈

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Solvolysis of Substituted Benzyl Benzenesulfonates in MeOH-MeCN Mixtures (MeOH-MeCN 혼합용매계에서 치환된 벤젠술폰산벤질의 가용매 분해반응)

  • Ikchoon Lee;Won Hee Lee;Chul Hyun Kang;Se Chul Sohn;Choong Shik Kim
    • Journal of the Korean Chemical Society
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    • v.28 no.6
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    • pp.366-373
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    • 1984
  • Methanolysis rates of benzylbenzenesulfonates, substituted both on the substrate (Y) and on the leaving group (Z), were determined in MeOH-MeCN mixtures. The results showed that the reaction proceeds via the dissociative $S_N2$ mechanism, in which bond breaking proceeds in greater degree compared to bond formation at the transition state(TS). Multiple Hammett correlation analysis showed that the cross term, ${\rho}_{YZ}$, is very small and hence the cross interaction of two substituents, Y and Z, at the TS is not important, supporting the dissociative $S_N2 $ type mechanism. While transition state variations predicted by the quantum mechanical model is shown to agree in general with the experimental results, those predicted by the potential energy surface model failed to account for the leaving group effect properly.

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Study on Experience Courses of Families Reorganization of North Korean Refugees: Focused on the Deduction of the Political Implication (북한이탈주민의 가족재구성 경험과정연구 -정책적시사점 도출을 중심으로-)

  • Lee, Duk-Nam
    • Journal of the Korea Society of Computer and Information
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    • v.18 no.11
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    • pp.201-212
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    • 2013
  • This study divides and traces experience courses of families' disorganization and reorganization of North Korean refugees in North Korea, China, and South Korea after settlement respectively, from the course of their escaping North Korea to entering South Korea. Through these results, the study is to propose political implications. Main data for the study were analyzed through a case study as a qualitative study method, targeting eight people from July in 2012 to March in 2013. From the study result, though North Korean refugees seemed to disorganize and leave family relations in the course of escaping North Korea, it was found out that this is not disorganization but a preparatory stage which saves families standing at the crossroads of life and death and makes a chance to live with them someday. In these courses, in order for them to overcome their situations and survive, while repeating disorganization and reorganization of families, they used them as a way of saving themselves and their families. It was discovered that these phenomena always occurred simultaneously.

The Estimation of Collision Speed at the Intersection using Simulation (시뮬레이션을 통한 교차로 충돌 속도 추정)

  • Han, Chang-Pyoung;Cheon, Jeong-Hwan;Choi, Hong Ju
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.22 no.2
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    • pp.514-521
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    • 2021
  • When calculating an intersection collision speed using a formula, it is very difficult to grasp the degree of deceleration of a vehicle after the collision unless there is road surface trace in the entire section where each vehicle moved from the point of collision to their final positions after the collision. A vehicle's motion trajectory shows an irregular curve after a collision due to the effects of inertia based on the driving characteristics of the vehicle, the eccentric force according to the collision site, and the collision speed. Therefore, it is very important to set the appropriate departure angle after a collision for accurate collision speed analysis. In this study, based on experimental collision data using a computer simulation (PC-Crash), the correlation between an appropriate vehicle departure angle and the post-collision speed was analyzed, and then, a regression analysis model was derived. Through this, we propose a method to calculate collision speed by applying only the vehicle departure angle in some types of collisions for traffic accidents at intersections.

A Study on the recovery predictive factors for North Korean refugees with torture experience (북한이탈주민의 고문으로 인한 외상 후 충격에 영향을 미치는 요인)

  • Kim, Hyun Kyoung
    • Korean Journal of Social Welfare Studies
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    • v.41 no.3
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    • pp.81-106
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    • 2010
  • The purpose of this study was to find out correlation and predictors of recovery predictive factors for North Korean refugees experienced torture in South Korea. This survey was conducted on 205 North Korean refugees with questions on socio-demographic variables, mental health & personality variables, and social & economical variables. The influence of these variables was analysed. Result indicated that sex, age, disease, child living in the North, marriage experience in the North and the China were associated with post-traumatic stress of torture. Also, depression, rumination, self-efficacy, resilience, secure-attachment, social support from the South, economic difficulties predicted the recovery for North Korean refugees with torture experience. Finally, clinical intervention with healing relationship and human rights for North Korean refugees were discussed.

Determinants of Female-salaried Workers' Career Interruption (여성의 경력단절과 육아휴직 제도와의 관계)

  • Cho, Donghun
    • Journal of Labour Economics
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    • v.39 no.4
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    • pp.79-98
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    • 2016
  • This study empirically estimates the determinants of career interruption by married women. Using the survey of economic activities related to women's decision for career interruption, we consider the effect of maternity leave in workplace as well as individual characteristics on determining women's decision out of labor force. We found out that both existence and use of maternity leave in workplace seems to play an very important role in reducing women's career interruption.

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이달의통계 / 온라인게임,3파전

  • Korea Database Promotion Center
    • Digital Contents
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    • no.11 s.126
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    • pp.18-19
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    • 2003
  • 이동통신 시장에서 SKT의 시장 점유율이 점차 높아지면서 KTF와 LGT의 가입자 이탈 막기에 비상이 걸렸다.지난 9월말 기준 이동전화 가입자 현황을 살펴보면 SKT는 전달에 비해 6만2,868명이 늘어난 데 반해 KTF와 LGT는 각각 2,053명과 7,541명이 줄어든 것으로 나타났다. 이 같은 현상은 올해 내내 이어지고 있는 상황으로 LGT의 경우 지난 3월 이후 약 11만6,000여명의 가입자가 이탈한 것으로 나타났다.이에 따라 KTF와 LGT는 SKT의 독주체제를 막기 위해 모바일 뱅킹 사업에 대한 전략적 제휴를 체결하는 등 방안 마련에 부심하고 있는 것으로 알려 졌다. KTF의 한 관계자는“이동통신시장의 특성상 지배적 사업자가 갖는 이점으로 인해 이 같은 현상이 나타나고 있지만 한발 앞선 모바일 콘텐츠 서비스 등으로 가입자 기반을 점차 늘려 나갈 계획”이라고 밝혔다.한편, 초고속인터넷 서비스 가입자수의 경우 지난달에 약 5만여명이 늘어나 증가세가 계속되고 있는 것으로 나타났다.

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Long-term Relationships of KOSPI, BSI, and Macro Economic variables (주가.기대심리.거시경제변수의 장기균형 관계 :Cointegration을 중심으로)

  • Chang, Byoung-Ky;Choi, Jong-Il
    • The Korean Journal of Financial Management
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    • v.18 no.2
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    • pp.125-144
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    • 2001
  • 본 연구는 선행연구들과 달리 경제변수로 설명할 수 없는 경제주체들의 심리적 요소가 주가에 영향을 미칠 수 있다는 관점에서 주가와 거시경제변수 및 경제주체들의 기대심리간의 장기 균형 및 동학구조관계를 분석한다. 주가는 기업의 내재가치를 나타내며 이는 상당부분 현재와 미래의 경제상황에 의해 영향을 받을 것이다. 미래경제상황을 정확히 예측할 수는 없으나 경제 주체들은 미래경제상황을 예측하게 되며 그 예측은 주가에 반영될 수 있다. 검증결과 BSI 전망치와 같은 경제주체들의 기대심리가 주가결정에 가장 중요한 단일 변수인 것으로 나타났다. 이변량 공적분검증을 실시한 결과 실질주가지수는 BSI와 장기균형관계에 있는 반면 다른 거시경제변수와는 공적분관계에 있지 않은 것으로 나타났다. 다변량 공적분분석에서도 BSI가 포함된 경우에만 KOSPI/P와 장기균형관계에 있는 것으로 나타났다. 벡터오차수정모형으로 동태적 관계를 분석한 결과, 이변량과 다변량 분석 모두에서 이들 두 변수의 오차수정항이 통계적으로 유의하여 장기균형으로부터 이탈에 대하여 상호 조정하는 것으로 나타났다.

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Difficulties that Female North Korean Defector Cyber University Students Experienced in their Social Work Field Practicum and Support Plan (여성 북한이탈주민 사이버대학생이 경험한 사회복지실습의 어려움과 지원방안)

  • Bae, Jin-Hyung;Park, Mee-Hyun
    • The Journal of the Korea Contents Association
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    • v.16 no.1
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    • pp.60-74
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    • 2016
  • There are increasing numbers of North Korean defectors. Many of them enter universities and major in social welfare in order to get jobs. As a required course, they must participate in field practicum and many difficulties are expected. This study aims to examine the North Korean defectors' practicum experience in specific, and to support more effectively in the field work education. To achieve this purpose, female North Korean defectors who go to G cyber university and have finished their field practicums, were interviewed in an in-depth interview. The data were analyzed with the open coding through the constant comparison method as Grounded theory's initial analysis. As the result, the following was found: 49 concepts, 18 sub-categories, and 7 categories. The categories include difficulties in the process of preparation for and beginning with various obstacles; confusion due to the differences between the North Korean and South Korean culture; tasks and functions that were not expected, personal relationships which were burdensome to them; feeling a lack of professional competence; inevitable environmental circumstances, and personal problems. Based on the results, suggestions for better support in field practice education in the side of universities, community agencies, individual students and the general society were addressed.

Follow-up Study on the Acculturation and Adataption to South Korea among North Korean Defecting Adolescents (북한이탈청소년의 문화변용 추적과 남한사회 적응에 관한 연구)

  • Hong, Soon-Hae;Lee, Sook-Young;Kim, Sun-Hwa
    • Korean Journal of Social Welfare
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    • v.62 no.1
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    • pp.343-365
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    • 2010
  • It is a follow-up study on acculturation types and adaptation level to South Korea among North Korean defecting adolescents who participated in the study with the same purpose five years ago(2003). The study of 2003(1st year study) was done with 90 adolescents, out of whom 46 participated in this study(2nd year study). The data from 46 subjects who participated in both 1st and 2nd studies were analyzed. The results on individual acculturation type showed that 40% of the respondents who belonged to 'marginal' or 'separated' types in the 1st study were changed to 'assimilated' or 'integrated' types in the 2nd. Twenty percent changed from 'assimilated' or 'integrated' types in the 1st study to 'marginal' or 'separated' in the 2nd. Furthermore, the higher is the acceptance level of South Korean culture, the lower are their psycho-social problems and the higher is the satisfaction level of daily lives in South Korea. While the higher is the preservation level of North Korean culture, the higher is aggression. Based on the results, the study developed discussion on diverse alternative plans for helping North Korean defecting adolescents in successfully adjusting to the South Korean society.

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A Study on the Relationship Between the Off-Axis Cylinder and Corrected Vision of Astigmatism (난시안의 교정축 이탈과 교정시력과의 관계 연구)

  • Kim, Jung Hee;Kang, Sue Ah
    • Journal of Korean Ophthalmic Optics Society
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    • v.12 no.3
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    • pp.83-87
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    • 2007
  • This study was classified and compared astigmatism's refractional abnormal degrees with visual acuity state of full correction which turned on axises of only 5 degree, 10 degree, and 15 degree. Subjects of this study were 57 college students (114 eyes) who had neither eye diseases nor binocular abnormality, were from their twenties to fifties, with myopia. It appeared that 30.8% of subjects who had astigmatism wore glasses with wrong axis of astigmatism. After accurate correction of the visual acuity and degrees of astigmatism, when we moved to corrected axises at 5 degree, 10 degree, 15 degree, failure of visual acuity with one line or more were 56.1%, 84.2%, 93.8%, respectively. When we comapre the completely-corrected visual acuity with the visual acuity with dricted axes, the bigger the width of visual acuity's weakness was the bigger the drifted angle. The change of normal visual acuity according to drifting angle of corrected axises of astigmatism, when we compared with full correction, appeared 0.94 in 5 degree, 0.87 in 10 degree, and 0.79 in 15 degree. Drift of 5 degree from fully corrected axis, corresponded to difference of visual acuity about one line, drift of 10 degree to 1.8 line difference of visual acuity, and drift of 15 degree about to 2.6 line difference. Through this study, we were sure that, in the case of drifting away from the right axis of astigmatism, it lead to visual weakness and asthenopia. Therefore we darely advise that optometrists should make mistake of axis least by confirming accucacy of corrected axis after despensing of spectacles of astigmatism.

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