• 공업화학
• /
• 제33권3호
• /
• pp.322-327
• /
• 2022

Fucoidans were degraded by hydrogen peroxide under the electron beam (2.5 MeV) with various radiation doses (5 kGy, 10 kGy, 15 kGy, and 20 kGy) at room temperature. The degradation property was analyzed with a gel permeation chromatography (GPC-MALLS) method. An average molecular weight of fucoidan decreased from 99,956 at the irradiation dose of 0 kGy to 6,725 at the irradiation dose of 20 kGy. The solution viscosity of fucoidans showed a similar pattern to the molecular weight change. The number of chain breaks per molecule (N) increased with increasing the irradiation dose and concentration of hydrogen peroxide. The radiation yield of scission value markedly increased with increasing the irradiation dose up to 15 kGy. Also a 10% hydrogen peroxide concentration was more efficient than that of 5%. The structures of degraded fucoidan samples were studied with Fourier transform infrared spectroscopy (FT-IR). The results showed that the degradation process did not significantly change the chemical structure or the content of sulfate group. The sulfur content of each sample was determined with an Elemental Analyzer. With increasing the concentration of hydrogen peroxide, the ratios of sulfur/carbon, hydrogen/carbon, and nitrogen/carbon slightly decreased. The antioxidant activities of fucoidans were investigated based on hydroxyl radical scavenging activities. The ability of fucoidan to inhibit the hydroxyl radical scavenging activity was depended on its molecular weight.

• Membrane and Water Treatment
• /
• 제13권5호
• /
• pp.227-233
• /
• 2022

The objective of the study, to develop adsorbent based purifier for removal of radiological and nuclear contaminants from contaminated water. In this regard, 3-aminopropyl silica functionalized with ethylenediamine tetraacetic acid (APS-EDTA) adsorbent prepared and characterized by Fourier Transform Infrared Spectroscopy (FT-IR), Scanning Electron Microscopy (SEM) and X-ray Diffraction (XRD). Prepared APS-EDTA used for adsorptive studies of Cs(I), Co(II), Sr(II), Ni(II) and Cd(II) from contaminated water. The effect on adsorption of various parameters viz. contact time, initial concentration of metal ions and pH were also analyzed. The batch method has been employed using metal ions in solution from 1000-10000 ㎍/L, contact time 5-60 min., pH 4-10 and material quantities 50-200 mg at room temperature. The obtained adsorption data were used for drawing Freundlich and Langmuir isotherms model and both models were found suitable for explaining the metal ions adsorption on APS-EDTA. The adsorption data were followed pseudo second order reaction kinetics. The maximum adsorption capacity obtained 1.3037-1.4974 mg/g for above said metal ions. The results show that APS-EDTA have great potential to remove Cd(II), Co(II), Cs(I), Ni(II) and Sr(II) from aqueous solutions through chemisorption and physio-sorption.

• 한국지리정보학회지
• /
• 제7권3호
• /
• pp.99-107
• /
• 2004

해수유동모델 결과를 3차원적으로 가시화하기 위한 그래픽 유저 인터페이스를 구축하는 과정에서 지리정보시스템(GIS) 기술을 활용하였다. 연안역 관리에서 GIS 기법은 산재되어 있는 방대한 자료들을 저장하고 이를 3차원으로 가시화하는 기능을 제공하며 해석적, 통계적, 모델링 도구로써 주어진 상황에 적합한 데이터 변환이 가능하도록 해준다. 해수유동모델은 개방경계에서 조석, 바람, 수온, 염분, 강물 유입 및 태양복사 등과 같은 모델입력값을 부여함으로써 구동되며 대상해역은 진해만으로 하였다. 본 연구에서는 국산 GIS 소프트웨어인 GeoMania (v2.5)를 사용하여 진해만을 대상으로 시뮬레이션된 해수유동모델 결과의 3차원 가시화 모듈을 구축하였다.

• 한국수소및신에너지학회논문집
• /
• 제27권4호
• /
• pp.421-430
• /
• 2016

To prepare mesophase pitches through low energy process, pyrolysis fuel oil with $AlCl_3$ has been modified using two-step heat treatment which is heat-treated at $330^{\circ}C$ for 3~5 h after pre-treatment at $250^{\circ}C$. The result of polarized optical microscope observation, mesophase is not observed in pitches carried out only pre-heat treatment. While mesophase content is significantly increased from 9% to 100% according to increasing secondary heat treatment time from 3 h to 5 h. Synthesizing of the mesophase pitch at low temperature of $330^{\circ}C$ is attributed to decrease of viscosity of the pitches carried out first heat treatment with $AlCl_3$. The result of Fourier-transform infrared spectroscopic analysis, it is expected that aromatization of aliphatic compounds is dominant at early secondary heat treatment, on the other hand, polycondensation reaction becomes dominant as secondary heat treatment time increases. Aromaticity and stacking height of the pitches secondary heat treated for 5 hours are more increased about 25% and 107%, respectively, than that of pitches carried out only first heat treatment.

• 한국산업보건학회지
• /
• 제5권2호
• /
• pp.212-225
• /
• 1995

This study was performed in a diatomite factory located at Pohang City, Kyeongsangbuk-Do. The major objectives were to evaluate sampling and analytical methods of diatomaceous earth dust. Concentrations of total and respirable diatomaceous earth dust were measured. Size distribution of dust was analyzed by a personal cascade impactor and the particle size analyzer which is an application of multiple diffraction method. Also crystalline silica in respirable and total dust samples was analyzed quantitatively by X-ray diffraction and Fourie Transform Infrared Spectroscopy(FTIR). The results were as follows: The airborne total and respirable dust concentrations, particle size distribution, and cristalline silica(quartz) concentrations showed approximately a log-normal distribution. The means of totaldust concentrations at flour maufacturing, fire brick grinding and packaging processes exceeded the Korean and American Conference of Governmental Industrial Hygienists standards, $10mg/m^3$. The size distribution of diatomaceous earth dust was log-normal and identified as the rspirable particle mass and thoracic particle mass. The crystalline silica in respirable and total dust samples was identified to quartz and contained about 10 % in those samples. Finally, it is necessary to study the applicability of multiple diffraction for particle size distribution to compare the ACGIH's size selective sampling with other materials containing crystalline silica. Also, advanced quantitative study to X-ray diffraction and FTIR methods shoud be carried out 10 verify general and specific characteristics for respirable crystalline silica.

• 한국음향학회지
• /
• 제7권2호
• /
• pp.26-38
• /
• 1988

이 논문은 긴 잔향을 갖는 실내의 음향전달계의 임펄스 레스폰스를 DFT(Discrete Fourier Transform)의 알고리즘으로 크로스 스펙트럼 (cross spectrum method)에 의해 구하는 3가지 방법에 대해 기술한다. 첫째의 방법은 종래부터 사용되어온 방법으로 음원신호로서 백색잡음(white noise)을 사용한다. 따라서, 임펄스 레스폰스 추정시 매우 긴 시간창의 데이터와 다수회의 DFT를 행하여야 한다. 두번째 방법은 음원신호로써 짧은 지속시간의 랜덤노이즈(random noise)를 사용하여 첫번째 방법에서 DFT수행시 데이타의 시간창의 길이를 짧게 하기 위하여 개발된 방법이다. 세번째 방법은 본 논문에서 제안한 방법으로 음원신호로써 짧은 지속시간의 두 종류의 확정산호를 교차하여 발생하는 방법이다. 이 방법은 DFT수행시 시간창의 길이는 두번째 방법과 같고 FFT 계산횟수는 5번으로 행할 수 있다. 이들 음원신호에 대해 잔향이 긴 음향전달계의 임펄스 레스폰스 측정은 전자계산기의연산처리능력과 임펄스 레스폰스 측정정도의 관점에서 비교 시험한 결과는 마지막 방법이 가장 유리하다는 결론을 얻었다.

• Advances in nano research
• /
• 제8권2호
• /
• pp.183-190
• /
• 2020

The objectives of this research were the reduction of membrane fouling and improvement of sludge properties by using synthesized H-ZSM-5 and NH₄-ZSM-5 zeolites. These two nano zeolites were synthesized and added to the membrane bioreactor (MBR). Three similar MBRs with the same operational condition were used in order to evaluate their effect on the mentioned matters. The evaluated parameters were trans-membrane pressure (TMP), Fourier-transform infrared spectroscopy (FTIR), particle size distribution (PSD), soluble microbial product (SMP), extracellular polymeric substances (EPS) and, excitation-emission matrix (EEM). The MBR₀ was without any additional zeolite while 0.4 g/L of H-ZSM-5 and NH₄-ZSM-5 were added to MBR_HZSM-5 and MBR_NH4ZSM-5, respectively. The COD removal of the MBR₀, MBR_H-ZSM-5 and MBR_NH4-ZSM-5 were 87.5%, 93.3% and 94.6%, respectively. The TMP of the MBR_H-ZSM-5 was 45% less than MBR₀ whereas the reduction for MBR_NH4-ZSM-5 was 65.5%. Also results showed that both H-ZSM-5 and NH₄-ZSM-5 caused reduction in protein and polysaccharide related EPS but the NH₄-ZSM-5 had better performance toward the elimination of organic compounds.

• 해양환경안전학회:학술대회논문집
• /
• 해양환경안전학회 2006년도 추계학술발표회
• /
• pp.213-215
• /
• 2006

해수유통모델 결과를 3차원적으로 가시화하기 위한 그래픽 유저 인터페이스를 지리정보시스템 (GIS) 기술을 활용하여 구축하였다. 연안역 관리에서 GIS기법은 산재되어 있는 방대한 자료들을 저장하고 이를 3 차원으로 가사화하는 기능을 제공하며 해석적, 통계적, 모델링 도구로써 주어진 상황에 적합한 데이터 변환이 가능하도록 해준다. 해수유동모델은 개방경제에서 조석, 바람, 수온, 염분, 장물 유업 및 태양복사 등 과 같은 모델입력값을 부여함으로써 구동되며 대상해역은 진해만으로 하였다. 본 연구에서는 국산 GIS 소프트웨어인 GeoMania (v2.5)를 사용하여 진해만을 대상으로 시뮬레이션된 해수유통모델 결과의 3차원 가시화 모듈을 구축하였다.

• Journal of the Korean Wood Science and Technology
• /
• 제52권3호
• /
• pp.205-220
• /
• 2024

Various polylactic acid (PLA) blends were reinforced with untreated or silane-treated micro-sized cellulose fiber (MCF), successfully prepared as 3D printing filaments and then printed using a fused filament fabrication (FFF) 3D printer. In this study, we focused on developing 3D-printed MCF/PLA composites through silane treatment of MCF and investigating the effect of silane treatment on the various properties of FFF 3D-printed composites. Fourier transform infrared spectra confirmed the increase in hydrophobic properties of silane-treated MCF by showing the new absorption peaks at 1,100 cm^-1, 1,030 cm^-1, and 815 cm^-1 representing C-NH₂, Si-O-Si, and Si-CH₂ bonds, respectively. In scanning electron microscope images of silane-treated MCF filled PLA composites, the improved interfacial adhesion between MCF and PLA matrix was observed. The mechanical properties of the 3D-printed MCF/PLA composites with silane-treated MCF were improved compared to those of the 3D-printed MCF/PLA composites with untreated MCF. In particular, the highest tensile and flexural modulus values were observed for S-MCF10 (5,784.77 MPa) and S-MCF5 (2,441.67 MPa), respectively. The thermal stability of silane-treated MCF was enhanced by delaying the initial thermal decomposition temperature compared to untreated MCF. The thermal decomposition temperature difference at T₉₅ was around 26℃. This study suggests that the effect of silane treatment on the 3D-printed MCF/PLA composites is effective and promising.

• 한국정보과학회:학술대회논문집
• /
• 한국정보과학회 1999년도 가을 학술발표논문집 Vol.26 No.2 (2)
• /
• pp.377-379
• /
• 1999

본 연구에서는 축구 경기 장면 분석시스템의 일부인 경기 장면에서 선수의 위치와 운동장 모델에서의 선수의 위치 간의 매핑에 관해 기술한다. 이 때 두 좌표계 간의 사상(mapping)시 발생되는 hole에 관한 문제를 주로 사용되는 보간법이 아니라 역 방향 매핑을 이용하여 해결하고, 또한 운동장 모델의 전체 영역이 아니라 원 영상에서 얻어진 정보를 이용하여 최소한의 영역만을 변환함으로써 계산의 효율성을 높였다. 본 연구에서는 PC상에서 초당 3~5 Frame로 입력된 280$\times$640 해상도의 100여개의 RGB 영상을 대상하여 실험하였다. 축구 경기장면을 분석한 결과 대부분의 경우 두 좌표계간의 매핑이 올바로 이루어 졌다.