• Proceedings of the Korean Institute of Surface Engineering Conference
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• 2017.05a
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• pp.123.2-123.2
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• 2017

Fe-Ni-Cu 합금 전주를 위하여 황화물 용액에의 상의 열역학적 안정도를 작성하고 전주 조건을 선정하였다. $Fe-Ni-Cu-S-H_2O$ 용액의 열역학적 상의 안정도를 전산모사하기 위한 프로그램은 C#으로 작성하였다. JANAF 자료를 근거한 적정 전주 조건은 $130mA/cm^2$, $50{\sim}55^{\circ}C$, pH 2.4 이었다. XRF을 이용한 Fe-Ni-Cu의 합금 도막의 평균 조성은 Fe-42Ni-1Cu [wt.%] 이었다, 전류밀도가 낮아질수록 Ni과 Cu량은 증가하였다. 구리 농도가 증가하면 표면조도는 60 nm로 변화하였다.

• Proceedings of the Korean Society of Soil and Groundwater Environment Conference
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• 2003.04a
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• pp.318-321
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• 2003

This study explored the feasibility of applying Electrokinetic-Fenton process(EK-Fenton process) to remediation of contaminant sorbed on the soil possessed low-permeability. The addition of 0.01 N H$_2$SO$_4$ in the anode reservoir for the $H_2O$$_2$stabilization improved the stabilization of $H_2O$$_2$and the treatment effect of phenanthrene across the entire soil specimen. The use of $H_2O$$_2$and dilute acid as anode purging solution is a promising method treating of HOCs in low-permeability subsurface environments.

• Bulletin of the Korean Chemical Society
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• v.31 no.4
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• pp.803-807
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• 2010

Schorl modified by $H_2SO_4$ has been successfully developed to enhance schorl-catalyzed Fenton-like reaction for removal of phenol in an aqueous solution. The phenol removal percentage can be increased from 4% to 100% by the system of modified schorl and $H_2O_2$. Batch experiments indicate that the percent increases in removal of phenol by increasing the dosage of catalyst, temperature and initial concentration of $H_2O_2$. The results of XRD, FT-IR and SEM suggest that no new phases are formed after removal of phenol by modified schorl. ICP-AES results reveal that more dissolution of iron results in higher catalytic oxidant activity in the system of modified schorl and $H_2O_2$. Besides minor adsorption, mineral-catalyzed Fenton-like reaction governs the process.

• Proceedings of the Korean Society for Agricultural Machinery Conference
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• 2002.02a
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• pp.343-348
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• 2002

생버섯의 환경기체조절저장을 위한 적정 기체조성을 예측하기 위하여 팽이버섯과 느타리 버섯을 대상으로 호흡특성치를 측정 및 모델링한 결과 두 버섯의 호흡속도는 환경기체조성에 영향을 받는 것으로 나타났다. 버섯의 산소소비속도와 이산화탄소발생속도를 반응표면분석한 결과 느타리버섯의 이산화탄소발생속도를 제외하고는 $R^2$=0.9이상의 높은 상관관계를 나타내었다. 반응표면 분석결과를 이용하여 두 버섯의 적정 기체조성은 팽이버섯의 경우 1~2.5% $O_2$와 10.5-11.5% $CO_2$, 느타리 버섯의 경우에는 2.5~4.5% $O_2$와 11.5~13%$CO_2$가 적정 기체조성 것으로 예측되었으며 일반적인 생버섯의 저장기체조건에 포함되는 농도였다. 따라서 예측된 조건에서 생버섯의 환경기체조절 저장이 가능 할 것으로 판단되었다.

• Journal of Hydrogen and New Energy
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• v.23 no.5
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• pp.429-436
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• 2012

Mg and Mg-based alloys are regarded as strong candidate hydrogen storage materials since their hydrogen capacity exceeds that of known metal hydrides. One of the approaches to improve kinetic is addition of metal oxide. In this paper, we tried to improve the hydrogenation properties of Mg-based hydrogen storage composites. The effect of transition metal oxides, such as $Nb_2O_5$ on the kinetics of the Magnesium hydrogen absorption kinetics was investigated. $MgH_x$-5wt.% $Nb_2O_5$ composites have been synthesized by hydrogen induced mechanical alloying. The powder fabricated was characterized by X-ray diffraction (XRD), Field Emission-Scanning Electron Microscopy (Fe-SEM), Energy Dispersive X-ray (EDX), BET and simultaneous Thermo Gravimetric Analysis / Differential Scanning Calorimetry (TG/DSC) analysis. The Absorption / desorption kinetics of $MgH_x$-5wt.% $Nb_2O_5$ (type I and II) are determined at 423, 473, 523, 573 and 623 K.

• Journal of Conservation Science
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• v.30 no.1
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• pp.27-32
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• 2014

The sample book was printed in 1935. Since the books in the early twentieth century were printed using acidic paper, the color of the paper would change to brown over time due to iron corrosion. In addition to corroding iron cores, the acidity of the paper (pH 3.2) also made the paper brown and fragile, as was true in the case of the sample book. To clean the paper of the sample book and to make it strong, we replaced the iron core and performed wet cleaning on the paper to remove contaminants. Then we pressed the sample book dry, and subsequently linening every page with Minoshi($4g/m^2$). Generally, book conservator rebinding the book using wires or threads: however we have devised a new method to rebind the book using colored iron cores. To color the iron core brown, they were dipped in an aqueous coloring solution ($H_2O$, $C_2H_5OH$, $CuSO_4{\cdot}5H_2O$, $FeCl_3{\cdot}6H_2O$); subsequently, a 20% paraloid B-72 was applied to protect the colored iron cores from corrosion.

• Journal of the Korean Crystal Growth and Crystal Technology
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• v.9 no.1
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• pp.70-73
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• 1999

Amorphous silica was hydrothermally reacted for 48~120h at $170~180^{\circ}C$ in molar ratios of $SiO_{2}/(NaOH+Na_{2}CO_{3})=2~20\;and\;H_{2}O/(NaOH+Na_{2}CO_{3})=200~250$. Na-kenyaite nuclei were formed directly from amorphous silica without formation of Na-magadiite nuclei in wide range with $SiO_{2}/(NaOH+Na_{2}CO_{3})=3~20$. Above $SiO_{2}/(NaOH+Na_{2}CO_{3})=10$, Na-kenyaite always produced with a residual amorphous silica. Well-crystallized Na-kenyaite without residual amorphous silica were obtained in the range of $SiO_{2}/(NaOH+Na_{2}CO_{3})=3~10$. Morphology of Na-kenyaite exhibited that a large spherical and loosely packed aggregates changed into the smaller and individual platelets according to increase of reaction time.

• Particle and aerosol research
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• v.13 no.1
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• pp.33-40
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• 2017

Cobalt-iron oxides have emerged as alternative electrode materials for supercapacitors because they have advantages of low cost, natural abundance, and environmental friendliness. Graphene loaded with cobalt ferrite ($CoFe_2O_4$) nanoparticles can exhibit enhanced specific capacitance. In this study, we present three-dimensional (3D) crumpled graphene (CGR) decorated with $CoFe_2O_4$ nanoparticles. The $CoFe_2O_4$-graphene composites were synthesized from a colloidal mixture of GO, iron (III) chloride hexahydrate ($FeCl_3{\cdot}6H_2O$) and cobalt chloride hexahydrate ($CoCl_2{\cdot}6H_2O$) respectively, via one step aerosol spray pyrolysis. Size of $CoFe_2O_4$ nanoparticles was ranged from 5 nm to 10 nm when loaded onto 500 nm CGR. The electrochemical performance of the $CoFe_2O_4$-graphene composites was examined. The $CoFe_2O_4$-graphene composite electrode showed the specific capacitance of $253F\;g^{-1}$.

• Journal of Microbiology and Biotechnology
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• v.13 no.4
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• pp.509-516
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• 2003

A model system for the immnunochemical detection of Escherichia coli O157:H7 using a combined immunomagnetic separation (IMS) and test-strip liposome immunoassay (LIA) procedure was developed. Immunomagnetic beads coated with anti-E. coli O157 IgG antibodies were used to separate the E. coli O157 (including the H7 serotype) from culture. Immunoliposomes, whose surface was conjugated to goat anti-E. coli O157:H7 IgG and which encapsulated the marker dye, sulforhodamine B, were used as a detection label. The test strip, onto which antibodies to goat IgG were immobilized, was the immunosensor capturing immunoliposomes that did not bind to E. coli O157:H7 on the immunomagnetic bead-E. coli O157:H7 complexes. In experiments, pure cell culture suspensions of $10^5 E.$ coli O157:H7 organisms per ml produced a measurable signal inhibition, whereas a weak yet detectable signal inhibition occurred with $10^3CFU/ml$. The inhibition signals increased, when the incubation time for IMS was extended to 90 min and higher IgG-tag density (0.4mol%) was used on the liposomes. With 0.2 and 0.4mol% IgG-tagged liposomes, the IMS-LIA procedure showed more improved signal inhibitions than those of a direct (no IMS) LIA. The combined assay, which measures the instantaneous signal from immunoliposomes, can be completed within 90 min, making it significantly faster than conventional plating methods and enzyme-linked immunosorbent assay (ELISA). Accordingly, it is quite feasible to use the combined immunoassay format of IMS and dye-loaded immunoliposomes for the detection of E. coli O157:H7.

• Fisheries and Aquatic Sciences
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• v.26 no.1
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• pp.35-47
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• 2023

Myelophycus caespitosus, a brown alga belonging to genus Myelophycus, has been traditionally used as a food and medicinal resource in Northeastern Asia. However, few studies have been conducted on its pharmacological activity. In this study, we evaluated whether methanol extract of M. caespitosus (MEMC) could protect against oxidative damage caused by hydrogen peroxide (H₂O₂) in C2C12 murine myoblasts. Our results revealed that MEMC could suppress H₂O₂-induced growth inhibition and DNA damage while blocking the production of reactive oxygen species. In H₂O₂-treated cells, cell cycle progression was halted at the G2/M phase, accompanied by changes in expression of key cell cycle regulators. However, these effects were attenuated by MEMC. In addition, we found that MEMC protected cells from induction of apoptosis associated with mitochondrial impairment caused by H₂O₂ treatment. Furthermore, MEMC enhanced the phosphorylation of nuclear factor-erythroid-2 related factor 2 (Nrf2) and expression and activity of heme oxygenase-1 (HO-1) in H₂O₂-treaetd C2C12 myoblasts. However, such anti-apoptotic and cytoprotective effects of MEMC were greatly abolished by HO-1 inhibitor, suggesting that MEMC could increase Nrf2-mediated activity of HO-1 to protect C2C12 myoblasts from oxidative stress.