DOI QR코드

DOI QR Code

Ionic Compositions of PM10 and Reactive Gases during Asian Dust Events in March 2007

2007년 3월 서울 황사 사례의 PM10 이온조성과 반응성 기체 특성

  • Park, In-Ji (Department of Earth and Environmental Sciences, Korea University) ;
  • Lim, Sae-Hee (Laboratoire de Glaciologie et Geophysique de l'Environnement (LGGE), CNRS/University of Grenoble) ;
  • Lee, Mee-Hye (Department of Earth and Environmental Sciences, Korea University) ;
  • Lee, Young-Jae (Department of Earth and Environmental Sciences, Korea University) ;
  • Kim, Jeong-Soo (Air Quality Research Division, National Institute of Environmental Research)
  • Received : 2010.05.13
  • Accepted : 2011.06.27
  • Published : 2011.08.31

Abstract

Asian dust evens took place in Seoul on 27~28 March and 31 March~1 April 2007, during which the mass and chemical compositions of $PM_{10}$ were measured at urban area in Seoul, Korea. In conjunction with $PM_{10}$ compositions, the behaviors of gas precursors such as CO, $O_3$, $SO_2$, and $NO_2$ and meteorological parameters and air mass trajectories were thoroughly examined. The earlier case was a weak dust incidence which was characterized by elevated concentrations of CO, $SO_2$ and $NO_2$ as well as secondary aerosols. In contrast, the later showed the trait of the dust aerosols associated with high $PM_{10}$ mass and $Ca^{2+}$ concentrations. In general, the fractions of ionic species against mass decreased with increase in dust loading. The ratios of ${SO_4}^{2-}$ to ${NO_3}^-$ and $SO_2$ to $NO_2$ were similar in temporal variations, suggesting the concentrations of secondary aerosols were sensitive to the level of precursor gases. In this study, $Na^+$ and $Cl^-$ were also highly elevated during the heavy dust episode, which is thought to have originated from alkaline soils spreading through the northeast regions of China.

Keywords

References

  1. 국립기상연구소(2008) 2007년도 황사보고서.
  2. 후커, 류위잉, 옌르칭, 천빙, 차오전(2009) 중국 길림성 사막화와 황사, 국립기상연구소.
  3. Choi, J.C., M. Lee, Y. Chun, J. Kim, and S. Oh (2001) Chemical composition and source signature of spring aerosol in Seoul, Korea. J. Geophys. Res.-Atmos., 106(D16), 18067-18074. https://doi.org/10.1029/2001JD900090
  4. Dentener, F.J., G.R. Carmichael, Y. Zhang, J. Lelieveld, and P.J. Crutzen (1996) Role of mineral aerosol as a reactive surface in the global troposphere, J. Geophys. Res.-Atmos., 101(D17), 22869-22889. https://doi.org/10.1029/96JD01818
  5. Han, Y.-J., T.-S. Kim, and H. Kim (2008) Ionic constituents and source analysis of PM2.5 in three Korean cities, Atmos. Environ., 42(19), 4735-4746. https://doi.org/10.1016/j.atmosenv.2008.01.047
  6. IPCC (2001) in Climate Change 2001: The Physical Science Basis (Contribution of Working Group I to the Fourth Assessment Report of the Intergovernmental Panel on Climate Change) Edited by Solomon, S., D. Qin, M. Manning, Z. Chen, M. Marquis, K.B. Averyt, M. Tignor, and H.L. Miller, Cambridge Univ. Press, New York, 289-348.
  7. Kelly, J.T., C.C. Chuang, and A.S. Wexler (2007) Influence of dust composition on cloud droplet formation, Atmos. Environ., 41(14), 2904-2916. https://doi.org/10.1016/j.atmosenv.2006.12.008
  8. Kim, B.-G. and S.-U. Park (2001) Transport and evolution of a winter-time Yellow sand observed in Korea, Atmos. Environ., 35(18), 3191-3201. https://doi.org/10.1016/S1352-2310(00)00469-6
  9. Kim, J. (2008) Transport routes and source regions of Asian dust observed in Korea during the past 40 year (1965-2004), Atmos. Environ., 42(19), 4778-4789. https://doi.org/10.1016/j.atmosenv.2008.01.040
  10. Kim, K.-H., G.-H. Choi, C.-H. Kang, J.-H. Lee, J.Y. Kim, Y.H. Youn, and S.R. Lee (2003) The chemical composition of fine and coarse particles in relation with the Asian dust events, Atmos. Environ., 37(6), 753-765. https://doi.org/10.1016/S1352-2310(02)00954-8
  11. Kim, W., S.-J. Doh, Y. Yu, and M. Lee (2008) Role of Chinese wind-blown dust in enhancing environmental pollution in Metropolitan Seoul, Environ, Pollution, 153(2), 333-341. https://doi.org/10.1016/j.envpol.2007.08.014
  12. Koehler, K.A., S.M. Kreidenweis, P.J. DeMott, A.J. Prenni, and M.D. Petters (2007) Potential impact of Owens (dry) Lake dust on warm and cold cloud formation, J. Geophys. Res.-Atmos., 112, D12210, doi:10.1029/2007JD008413.
  13. Lee, B.-K., N.-Y. Jun, and H.K. Lee (2004) Comparison of particulate matter characteristics before, during, and after Asian dust events in Incheon and Ulsan, Korea, Atmos. Environ., 38(11), 1535-1545. https://doi.org/10.1016/j.atmosenv.2003.12.021
  14. Lee, M., M. Song, K.J. Moon, J.S. Han, G. Lee, and K.-R. Kim (2007) Origins and chemical characteristics of fine aerosols during the northeastern Asia regional experiment (Atmospheric Brown Cloud-East Asia Regional Experiment 2005), J. Geophys. Res.-Atmos., 112, D22S29, doi:10.1029/2006JD008210.
  15. Ooki, A. and M. Uematsu (2005) Chemical interactions between mineral dust particles and acid gases during Asian dust events, J. Geophys. Res.-Atmos., 110, D3, doi:10.1029/2004JD004737.
  16. Prospero, J.M., P. Ginoux, O. Torres, S.E. Nicholson, and T.E. Gill (2002) Environmental characterization of global sources of atmospheric soil dust identified with the NIMBUS 7 Total Ozone Mapping Spectrometer (TOMS) absorbing aerosol product, Rev. Geoghys., 40, 1, doi:10.1029/2000RG000095.
  17. Shin, S.A., J.S. Han, Y.D. Hong, J.Y. Ahn, K.J. Moon, S.J. Lee, and S.D. Kim (2005) Chemical composition and features of Asian dust observed in Korea (2000-2002), J. KOSAE., 21(1), 119-129.
  18. Streets, D.G., T.C. Bond, G.R. Carmichael, S.D. Fernandes, Q. Fu, D. He, Z. Klimont, S.M. Nelson, N.Y. Tsai, M.Q. Wang, J.-H. Woo, and K.F. Yarber (2003) An invevtory of gaseou and primary aerosol emissions in Asia in the year 2000, J. Geophys. Res.-Atmos., 108, D21, doi:10.1029/2002JD003093.
  19. Tegen, I. and I. Fung (1995) Contribution to the atmospheric mineral aerosol load from land surface modification, J. Geophys. Res.-Atmos., 100(D9), 18707-18726. https://doi.org/10.1029/95JD02051
  20. Zhuang, G.S., J.H. Guo, H. Yuan, and C.Y. Zhao (2001) The compositions, sources, and size distribution of the dust storm from China in spring of 2000 and its impact on the global environment, Chinese Sci. Bull., 46(11), 895-901. https://doi.org/10.1007/BF02900460

Cited by

  1. A Study on Prediction of Asian Dusts Using the WRF-Chem Model in 2010 in the Korean Peninsula vol.36, pp.1, 2015, https://doi.org/10.5467/JKESS.2015.36.1.90