• Journal of Environmental Science International
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• v.20 no.12
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• pp.1617-1624
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• 2011

Caustic (NaOH) solution is used to remove $H_2S$ from hydrocarbon streams in petroleum refining industry, gradually being, so called, spent sulfidic caustic (SSC) which has high levels of $H_2S$ and alkalinity. Thus, SSC can be used as an electron donor and a buffering agent for autotrophic denitrification. As SSC, however, contains some non-biodegradable organics, air stripping was conducted to remove the non-biodegradable organics. As a result, over 93 % of the non-biodegradable organics was removed within 30 min of aeration. Then, $Na_2S_2O_3{\cdot}5H_2O$, methanol and organic matters, which are produced from a biodiesel production plant, were added to reform the air-stripped SSC and their products being referred to new sulfidic caustics (NSCs) I, II and III, respectively. Thereafter, to investigate the effect of these products on the removal of COD and TN, these products were injected to a biological nitrogen removal (BNR) process, resulting in additional 44 % TN removal without noticeable increase in the effluent COD level. Therefore, it can be said that the BNR process is a promising option to treat NSC as demonstrated in this study whose results can be useful for developing resource recovery technologies.

• Journal of Marine Bioscience and Biotechnology
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• v.9 no.1
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• pp.8-13
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• 2017

Cost-effective microalgae harvesting methods are necessary for economical production of algal biodiesel. In this study, membranes with various pore sizes and materials were examined for their potentials in application to gravity-filtration of Tetraselmis sp. KCTC12432BP. For this test, 10 L of Tetraselmis sp. culture (2 g/L) was loaded on each membrane and filtration rates were measured. Among the tested materials, a woven cotton fabric showed the fastest water drain rate (0.73 L/hr) without serious cell leakage. Cell density of the concentrates after filtration was 6.8 g/L, indicating 3.4-fold concentration compared with the initial algal culture. The result suggests that the woven cotton fabric could serve as filtration membrane for harvesting Tetraselmis sp. among the tested ones.

• Journal of the Korean Wood Science and Technology
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• v.39 no.5
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• pp.451-458
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• 2011

Adhesives derived from renewable resources allow wood panel producers to make lower cost alternatives to formaldehyde-based adhesive resins. Among them, adhesive components extracted from industrial by-products or wastes are the most important research fields in the efficient utilization of waste and cost reduction. In our study, the rapeseed flour, which is a by product from the production of biodiesel extracted from rapeseed, was introduced to develop alternative adhesives for the production of wood flooring. The rapeseed flour was hydrolyzed with 1% sodium hydroxide solution and PF prepolymers were prepared with 3-molar ratios, 1.8, 2.1 and 2.4. The linear fracture mechanics was introduced to evaluate the glue bond quality in wood flooring composed of fancy-veneered and plywood, and the formaldehyde emission and adhesive penetration were also investigated. The formaldehyde emissions of wood flooring met the requirement of the standard of $SE_0$ specified in the KS standard. The rapeseed flour adhesive penetrated sufficiently into the vessel elements and lumens in fancy veneer and plywood and gave strong bond quality to the wood flooring. The fracture mechanics was introduced to evaluate the adhesive joint between fancy veneer and plywood. The critical stress intensity factor ($K_{IC}$) of boliva overlayed wood flooring was increased with increasing molar ratio and this was the same tendency in oak overlayed wood flooring. From the results, the formulated adhesives were efficiently used to bond fancy veneer onto the plywood to make wood flooring and showed a potential to be used as a component of environmentally friendly adhesive resin systems for production of flooring.

• Transactions of the Korean hydrogen and new energy society
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• v.28 no.3
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• pp.300-307
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• 2017

This study is to investigate particle size and velocity profile of gasoline port injector using Phase Doppler Particle Analyzer (PDPA). In this experiment, a GV 250 Delphi port injector used for motorcycles was used for liquid injection. The injector consists of four holes and has a static flow rate of 2.13 g/s. The fuel used in the injection was N-heptane, which is similar to gasoline, as an alternative fuel. The test fuel was injected at an atmospheric temperature of $20^{\circ}C$ and an open atmosphere of 1 atm. The injection time was 10 ms and the injection pressure was 3.5 bar in PDPA experiment. The experimental target position was fiexd at 30, 50 and 75 mm from the nozzle tip and data were collected for a total of 10,000 samples. The experimental results show that the length diameter (D10), the Sauter mean diameter ($D_{32}$), and the mean droplet velocity (MDV) are $45-54{\mu}m$, $99-115{\mu}m$ and 15-21 m/s, respectively.

• Advances in environmental research
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• v.2 no.1
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• pp.19-33
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• 2013

Microalgae are receiving an increasing attention because of their potential use as $CO_2$ capture method and/or as feedstock for biofuels production. On the other hand the current microalgae-based technology is still not widespread since it is characterized by technical and economic constraints that hinder its full scale-up. In such contest the growth kinetics of Nannochloris eucaryotum (a relatively unknown marine strain) in batch and semi-batch photobioreactors is quantitatively investigated with the aim of obtaining the corresponding kinetic parameters suitable for process engineering and its optimization. In particular the maximum growth rate was evaluated to be 1.99 $10^{-3}\;h^{-1}$. Half saturation concentrations for nitrates ($K_N$) and phosphates uptake ($K_P$) were evaluated as 5.4 $10^{-4}\;g_N\;L^{-1}$ and 2.5 $10^{-5}\;g_P\;L^{-1}$, respectively. Yield factors for nitrogen ($Y_N$) and phosphorus ($Y_P$) resulted to be 5.9 $10^{-2}\;g_N\;g^{-1}$ biomass and 6.0 $10^{-3}\;g_P\;g^{-1}{_{biomass}}$, respectively. The possibility of using 100% (v/v) $CO_2$ gas as carbon source is also evaluated for the first time in the literature as far as N. eucaryotum is concerned. The strain showed a good adaptability to high concentrations of dissolved $CO_2$ as well as to low pH. The lipid content under 100% $CO_2$ is about 16.16 %wt $wt^{-1}$ and the fatty acid methyl esters composition of the extracted oil is in compliance with the European regulation for quality biodiesel.

• ALGAE
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• v.31 no.3
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• pp.257-266
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• 2016

Nitrogen is one of the most critical nutrients affecting cell growth and biochemical composition of microalgae, ultimately determining the lipid or carbohydrate productivity for biofuels. In order to investigate the effect of nitrogen sources on the cell growth and biochemical composition of the marine microalga Tetraselmis sp., nine different N sources, including NaNO₃, KNO₃, NH₄NO₃, NH₄HCO₃, NH₄Cl, CH₃COONH₄, urea, glycine, and yeast extract were compared at the given concentration of 8.82 mM. Higher biomass concentration was achieved under organic nitrogen sources, such as yeast extract (2.23 g L⁻¹) and glycine (1.62 g L⁻¹), compared to nitrate- (1.45 g L⁻¹) or ammonium-N (0.98 g L⁻¹). All ammonium sources showed an inhibition of cell growth, but accumulated higher lipids, showing a maximum content of 28.3% in ammonium bicarbonate. When Tetraselmis sp. was cultivated using yeast extract, the highest lipid productivity of 36.0 mg L⁻¹ d⁻¹ was achieved, followed by glycine 21.5 mg L⁻¹ d⁻¹ and nitrate 19.9 mg L⁻¹ d⁻¹. Ammonium bicarbonate resulted in the lowest lipid productivity of 14.4 mg L⁻¹ d⁻¹. The major fatty acids in Tetraselmis sp. were palmitic, oleic, linoleic and linolenic acids, regardless of the nutritional compositions, indicating the suitability of this species for biodiesel production.

• Asian-Australasian Journal of Animal Sciences
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• v.27 no.3
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• pp.365-374
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• 2014

This experiment was conducted to evaluate the effects of increasing concentrations of crude glycerin (CGLY) in diets on nutrient utilization, ruminal fermentation characteristics, and nitrogen utilization of goats. Four male crossbred (Thai Native${\times}$Anglo Nubian) goats, with an average initial weight of $26{\pm}3.0$ kg, were randomly assigned according to a $4{\times}4$ Latin square design with four 21 days consecutive periods. Treatments diets contained 0%, 5%, 10%, and 20% of dietary DM of CGLY. Based on this experiment, there were no significant differences (p>0.05) among treatment groups regarding DM intake and digestion coefficients of nutrients (DM, OM, CP, EE, NDF, and ADF). Likewise, mean serum glucose, BHBA, and PCV concentrations were not affected (p>0.05) by dietary treatments, whereas serum insulin concentration linearly increased (L, p = 0.002) with increasing the amount of CGLY supplementation. Ruminal pH, $NH_3$-N, and BUN concentration were unchanged by dietary treatments, except for 20% of CGLY, $NH_3$-N, and BUN were lower (p<0.05) than for the diets 10% of CGLY, while the difference between the diets 0%, 5%, and 20% of CGLY were not significant. The amount of N absorption and retention were similar among treatments. Based on this study, CGLY levels up to 20% in total mixed ration could be efficiently utilized for goats and this study elucidates a good approach to exploiting the use of biodiesel production for goat production.

• Journal of the Korea Organic Resources Recycling Association
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• v.14 no.4
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• pp.93-103
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• 2006

Biogas is a byproduct after anaerobic digestion of organic materials and has been used as an energy source for heating and generating electricity. Demands of methanol for fuel mixed with gasoline and reactant in biodiesel production are steadily being increased. In this review, we summarized recent advancements in direct partial oxidation of methane to methanol with the brief history of methanol synthesis. The steam reforming and the catalytic oxidation of methane to methanol were compared, the former of which are mainly used in industrial scale and the latter in a stage of research and development. On the basis of this review, the possibility of methanol conversion from biogas was proposed in the aspects of the technological feasibility and the economical practicability.

• Asian-Australasian Journal of Animal Sciences
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• v.31 no.4
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• pp.514-521
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• 2018

Objective: This experiment was conducted to investigate the effects of crude glycerin from waste vegetable oil (CGWVO) on performance, carcass traits, meat quality, and muscle chemical composition. Methods: Twenty-four crossbred (Thai Native${\times}$Anglo Nubian) uncastrated male goats ($16.8{\pm}0.46kg$ body weight [BW]) were assigned to a completely randomized design and subjected to four experimental diets containing 0%, 2%, 4%, and 6% of CGWVO (63.42% of glycerol and 47.78% of crude fat) on a dry matter (DM) basis. The diets were offered ad libitum as total mixed rations twice daily. The feed intake, feeding behavior, growth performance, carcass and meat traits, and muscle chemical composition were evaluated. Results: Based on this experiment, there were significant differences (p>0.05) among groups regarding DM intake, growth performance, and carcass traits where goats receiving 6% of CGWVO had lower daily DM intake, growth performance, and carcass traits than those fed on 0%, 2%, and 4% of CGWVO. There were no effects of CGWVO on carcass length, carcass width, Longissimus muscle (LM) area, Warner-Bratzler shear force, pH and color of LM at 45 min after slaughter, as well as on other carcass cut and muscle chemical composition. Conclusion: In conclusion, the addition of up to 4% of DM in the diets for crossbred finishing goats seems to be the most interesting strategy, since it promotes greatest animal performance. Moreover, this study was a suitable approach to exploit the use of biodiesel production from waste vegetable oil for goat production.

• Environmental and Resource Economics Review
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• v.25 no.4
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• pp.545-564
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• 2016

Recently as fine and ultra fine particles become major environmental issues in Korea, it is very important to develop effective solutions to air pollution. Accordingly this study aims at detecting causes of air pollution by using models and examining if diesel price increases contribute to reduction of diesel consumption and air pollution. TSP, PM10, $NO_X$, $SO_X$, CO, and VOC are included as major air pollutants. As a result, we found invert U shape curve between pollution and income for all air pollutants except CO. Consumer price index, coal power capacity, diesel consumption, frequency of yellow dust, number of natural gas buses, number of transport business, annual average temperature, number of manufacturing businesses are also influential in explaining causes of air pollution. As diesel price increases by 1%, air pollutants decline between 0.07~0.12% in the short run. Simultaneously, the additional revenue from increases in diesel prices might be transferred to support expansion of biofuel market. Also, stronger policy should be developed to mitigate the current air pollution problem.