• 제목/요약/키워드: zeta potential value

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유체 내 전기선폭발법에 의한 은 나노입자 유체의 제조 및 특성 (Production and Properties of Ag Metallic Nanoparticle Fluid by Electrical Explosion of Wire in Liquid)

  • 박은주;;김지순;권영순;김진천;최혜선;정용훈
    • 한국분말재료학회지
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    • 제16권3호
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    • pp.217-222
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    • 2009
  • This paper presents a novel single-step method to prepare the Ag nanometallic particle dispersed fluid (nanofluid) by electrical explosion of wire in liquid, deionized water (DI water). X-ray diffraction (XRD), field emission scanning electron microscope (FE-SEM) and transmission electron microscope (TEM) were used to investigate the characteristics of the Ag nanofluids. Zeta potential was also used to measure the dispersion properties of the as-prepared Ag nanofluid. Pure Ag phase was detected in the nanofluids using water. FE-SEM analysis shows that the size of the particles formed in DI water was about 88 nm and Zeta potential value was about -43.68 without any physical and chemical treatments. Thermal conductivity of the as-prepared Ag particle dispersed nanofluid shows much higher value than that of pure DI water.

Formulation and Antimicrobial Activity on Escherichia coli of Nanoemulsion Coated with Whey Protein Isolate

  • Bejrapha, Piyawan;Choi, Mi-Jung;Surassmo, Suvimol;Chun, Ji-Yeon;Min, Sang-Gi
    • 한국축산식품학회지
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    • 제31권4호
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    • pp.543-550
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    • 2011
  • Various concentrations of whey protein isolate (WPI), such as 0.1, 0.5, 1.0, 2.5, and 5.0%(w/v), containing 1.0%(w/v) eugenol were prepared by high speed homogenization to formulate nanoemulsions (NEs) and to investigate their antimicrobial activity. The results showed that particle size decreased according to increases in WPI concentration. Similarly, the ${\zeta}$-potential value was reduced to a negative charge when using WPI concentrations >0.1%(w/v). In contrast, no significant differences in particle size were observed during 1 mon of storage, except for the 0.1%(w/v) WPI NE. The ${\zeta}$-potential value depended on the increase in WPI concentration and storage duration, except for NE1 and NE5, suggesting that a low or high concentration of emulsifier was not effective for maintaining the droplet form of the eugenol NE. The results of an antibacterial effect investigation indicated that the growth of Escherichia coli was inhibited based on an increase in eugenol concentration in all NE formulations. Moreover, a membrane permeability study showed that total leakage content increased according to incubation time.

Phase Inversion Emulsification and Enhancement of Physical Properties for Cationic Emulsified Asphalt

  • Lee, Eun-Kyoung
    • Elastomers and Composites
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    • 제50권4호
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    • pp.265-273
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    • 2015
  • In this work, the emulsified asphalt with high phase stability and storage stability was prepared by using phase inversion emulsification and the surfactant mixed with cationic and nonionic surfactants. It was found that the asphalt together with Span 20, nonionic surfactant and DDA (Dimethyl Dodecyl Amine), cationic surfactant showed the most stable phase. The phase stability of the emulsified asphalt, therefore, was investigated through the particle size with mixed surfactant content, rheology behavior and Zeta potential value; the particle size decreased with the increase of the mixed surfactant content but the viscosity increased. The shear thinning behaviors and the Zeta potential value with 50 mV~60 mV were shown, which was found to be considered stable. In addition, SBR latex(Styrene-butadiene-rubber) and water dispersed Epoxy (EPD) were used to enhance the physical properties of the emulsified asphalt. The swelling and adhesion features of the emulsified asphalt were also studied with $CaCO_3$, Silica, and Montmorillonite (MMT). It was shown that the addition of SBR latex and MMT can be another way to improve the physical properties of the emulsified asphalt in that the lowest swelling feature was found.

Preparation and Characterization of Resveratrol Nanoemulsions Stabilized by Self-assembly and Complex Coacervation Consisting of Sodium Alginate, Chitosan, and β-Cyclodextrin

  • Choi, Ae-Jin;Jo, Younghee;Cho, Yong-Jin;Kim, Tae-Eun;Kim, Chong-Tai
    • 산업식품공학
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    • 제21권3호
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    • pp.215-224
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    • 2017
  • Resveratrol was incorporated into various combinations of single- and double-layer nanoemulsions, prepared by self-assembly emulsification and complex coacervation with chitosan, alginate, and ${\beta}$-cyclodextrin, respectively. Resveratrol nanoemulsions were composed of medium-chain trigacylglycerols (MCTs), $Tween^{(R)}$ 80, water, chitosan, alginate, and ${\beta}$-cyclodextrin. The corresponding mixtures were formulated for the purpose of being used as a nutraceutical delivery system. Resveratrol nanoemulsions were obtained with particle sizes of 10-800 nm, with the size variation dependent on the emulsification parameters including the ratio of aqueous phase and surfactant ratio. Resveratrol nanoemulsions were characterized by evaluating particle size, zeta-potential value, stability, and release rate. There were no significant changes in particle size and zeta-potential value of resveratrol nanoemulsions during storage for 28 days at $25^{\circ}C$. The stability of resveratrol in the double-layer nanoemulsions complexed with chitosan or ${\beta}$-cyclodextrin was higher, compared with the single-layer nanoemulsions.

수중 콘크리트의 분리 저항성에 미치는 중점제의 영향 (The Influence of Viscosity Agent on Non-Segregation Property in Underwater Concrete)

  • 김선만;김영수
    • 한국콘크리트학회:학술대회논문집
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    • 한국콘크리트학회 1996년도 봄 학술발표회 논문집
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    • pp.117-122
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    • 1996
  • The purpose of this study is to investigate the properties of underwater concrete using three kinds of cellulose ether which has viscosity and water retention. The result is that water retention in underwater concrete shows in inverse proportion to PH value and the compressive strength is almostly effected by water retention. It can be certificated by the zeta electro potential value of an undispersed underwater concrete.

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Cetyl alcohol 함량에 따른 크림 제형 Henna 천연 염모제의 안정성 (Stability of Henna Natural Hair Dye Cream Formulation According to Cetyl Alcohol Contents)

  • 강이영;이승희;김운중;정종진
    • 한국응용과학기술학회지
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    • 제38권4호
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    • pp.1176-1182
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    • 2021
  • 본 연구에서는 유화안정제 중 하나인 cetyl alcohol 함량에 따른 천연 염모제 헤나의 유화 안정성을 분석하고 가장 안정한 유화를 나타내는 cetyl alcohol 함량을 확인하였다. 유화 안정성을 분석하기 위해 cetyl alcohol의 함량에 따른 입자 크기, 입자 형태, 점도 및 염색 후 색상의 차이를 비교하였다. Dynamic light scattering (DLS) zeta 분석 결과, cetyl alcohol 3 % 가 zeta potential 값이 115.9 mV로 가장 높은 값을 보였으며, 입자크기분포는 cetyl alcohol의 함량이 3 %인 크림 제형 염모제가 증류수에 분산된 헤나와 비교해 입도분포의 폭이 좁았다. 점도계 분석 결과 cetyl alcohol의 함량이 증가할수록 점도가 증가하였고, 크림 제형의 헤나 pH 측정 결과 두피에 적합한 pH 범위로 측정되었다. 또한 헤나 크림 제형 염모제에서는 cetyl alcohol의 함량이 증가할수록 유화 안정성이 증가하였다.

Morphological, Physical Characterization of Poly(acrylic acid) Nanogel Prepared by Electron Beam Irradiation

  • Park, Jong-Seok;Choi, Jong-Bae;Gwon, Hui-Jeong;Lim, Youn-Mook;Jeong, Sung-In;Shin, Young-Min;Kang, Phil-Hyun;Nho, Young-Chang
    • 방사선산업학회지
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    • 제8권1호
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    • pp.29-34
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    • 2014
  • Nanogels are internally cross-linked particles of sub-micrometer size made of hydrophilic polymers and are considered a distinct type of macromolecules, compared with linear and branched polymers or macroscopic gels. In this study, we studied a method of radiation induced synthesis of nanogels, which allows us to obtain tailored intra-molecularly crosslinked macromolecules of independently chosen molecular weight and dimensions. Thus, we report the possibility of applying the prepared nanogels using poly(acrylic acid) through electron beam irradiation for potential application as biomaterials. The nanogels were characterized by scanning electron microscopy (SEM). In addition, the size and zeta-potential of nanogels were measured by a particle size analyzer (PSA). The nanogels were prepared at an approximate size of 180 nm at 100 kGy and were spherical in shapes. The size of the nanogels decreased with increasing irradiation doses, and the absolute value of zeta potential increased with increasing irradiation doses.

수열합성법으로 합성된 나노 SmxCe1-xO2-2/x 분말의 수계 분산 (Dispersion of SmxCe1-xO2-2/x Nanoparticles which is Synthesized by Hydrothermal Process in Aqueous System)

  • 배동식;김은정;한경섭
    • 한국재료학회지
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    • 제15권2호
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    • pp.112-114
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    • 2005
  • Dispersion stability of the $Sm_xCe_{1-x}O_{2-2/x}$ nanoparticles, which was produced by hydrothermal process, was studied in aqueous suspension using ESA (Eletrokinetic Sonic Amplitude). The average particle size of the synthesized $Sm_xCe_{1-x}O_{2-2/x}$ at nanoparticles was about $5{\pm}2nm$. The dispersion and rheological behavior of the $Sm_xCe_{1-x}O_{2-2/x}$ nanoparticles aqueous suspension was investigated using $NH_4OH\;and\;HNO_3$ as a disperse agent. The colloidal stability of aqueous suspensions with $Sm_xCe_{1-x}O_{2-2/x}$ nanoparticles at different pH values has been investigated by means of zeta potential, average particle size, and the distribution of synthesized $Sm_xCe_{1-x}O_{2-2/x}$ nanoparticles. The isoelectric point of the $Sm_xCe_{1-x}O_{2-2/x}$ nanoparticles was at pH around 11 and the value of zeta potential was at its maximum near pH 6.5.

분별침전에서 친수성 고분자 물질을 이용한 (+)-dihydromyricetin의 입자크기 감소 (Decreasing Particle Size of (+)-Dihydromyricetin Using Hydrophilic Polymer in Fractional Precipitation)

  • 지성빈;김진현
    • Korean Chemical Engineering Research
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    • 제56권3호
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    • pp.370-375
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    • 2018
  • 본 연구에서는 생리활성물질 (+)-dihydromyricetin의 입자크기 감소를 위하여 친수성 고분자 물질을 첨가하여 분별침전을 수행하였다. 고분자 물질(HPMC 2910, PVP K90, PVA)이 첨가된 분별침전을 통해 (+)-dihydromyricetin 입자크기를 감소시킬 수 있었다. 특히 분별침전 시 HPMC 2910 (0.1%, w/v)을 첨가할 경우, 대조군에 비하여 입자크기가 $38-68{\mu}m$ (32-40%) 정도 감소하여 입자크기 감소에 가장 효과적이었다. 또한 (+)-dihydromyricetin침전물의 입자크기는 친수성 고분자 물질 첨가에 따른 침전용액의 제타전위 절대값에 반비례함을 알 수 있었다.

The Influence of Functionalization of the Fe3O4 Nanoparticle on its Dispersion Property

  • Han, Jin Soon;An, Gye Seok;Park, Bong Geun;Choi, Sung-Churl
    • 한국세라믹학회지
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    • 제55권1호
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    • pp.80-84
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    • 2018
  • In this study, to improve the dispersity of $Fe_3O_4$ nanoparticles, dispersion properties were considered with various types of functionalization of $Fe_3O_4$ nanoparticles. Due to its high surface area, the electrically neutral state of its surfaces, and its magnetic momentum, $Fe_3O_4$ nanoparticles are easily aggregated in solution. In order to prevent aggregation, $Fe_3O_4$ nanoparticles were functionalized with carboxyl and amine groups in the form of a polymer compound. Carboxyl and amine groups were attached to the surface of $Fe_3O_4$ nanoparticles and the absolute value of the zeta potential was found to be enhanced by nearly 40 eV. Furthermore, the morphology and the magnetic property were analyzed for the application of $Fe_3O_4$ nanoparticles as a magnetic fluid.