• Title/Summary/Keyword: wet chemical

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Change of Dimensional Stability and Dip Elongation of Handsheets Depending on Wet Pressing (습부압착에 따른 수초지의 치수안정성과 침지신장성의 변화)

  • Park, Chang-Soon;Lee, Jin-Ho;Kil, Jung-Ha;Park, Jong-Moon
    • Journal of Korea Technical Association of The Pulp and Paper Industry
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    • v.43 no.4
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    • pp.31-39
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    • 2011
  • One of the main drawbacks of wood fibers based composite materials are their tendency to swell due to moisture uptake in wet and moist environments. The main contribution to the hygroexpansion usually comes from the hydrophilic wood fibers. Recent trend toward the high speed printing, copying, and precision converting precesses demands a high level of dimensional stability under various environmental conditions. The purpose of this study was to investigate the dimensional stability of softwood bleached kraft pulp handsheets depending on wet pressing conditions. By increasing the number of wet pressing, dimensional stability was decreased because of increased fiber-to-fiber bonding. Hygroexpansion of handsheets had a linear relationship with the relative bonded area and equilibrium moisture contents. Dip elongation was decreased when the number of wet pressing was increased because of increased fiber-to-fiber bonding to resist low load in water.

Simultaneous Determination of Alkoxyalcohols in Wet Wipes Using Static Headspace Gas Chromatography and Mass Spectrometry

  • Lee, Soojin;Pyo, Heesoo;Chung, Bong Chul;Kim, Haidong;Lee, Jeongae
    • Bulletin of the Korean Chemical Society
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    • v.35 no.11
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    • pp.3280-3288
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    • 2014
  • Alkoxyalcohols are used as solvents or preservatives in various consumer products such as wet wipes. The metabolites of alkoxyalcohols are known to be chronically toxic and carcinogenic to animals. Thus, an analytical method is needed to monitor alkoxyalcohols in wet wipes. The aim of this study was to develop a simultaneous analytical method for 14 alkoxyalcohols using headspace gas chromatography coupled with mass spectrometry to analyze the wet wipes. This method was developed by comparing with various headspace extraction parameters. The linear calibration curves were obtained for the method ($r^2$ > 0.995). The limit of detection of alkoxyalcohols ranged from 2 to $200ng\;mL^{-1}$. The precision of the determinative method was less than 18.20% coefficient of variation both intra and inter days. The accuracy of the method ranged from 82.86% to 119.83%. (2-Methoxymethylethoxy)propanol, 2-phenoxyethanol, and 1-phenoxy-2-propanol were mainly detected in wet wipes.

The Wet Etching Rate of Metal Thin Film by Sputtering Deposition Condition (스퍼터링 증착 조건에 따른 금속 박막의 습식 식각율)

  • Hur, Chang-Wu
    • Journal of the Korea Institute of Information and Communication Engineering
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    • v.14 no.6
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    • pp.1465-1468
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    • 2010
  • The wet etching is a process using chemical solution and occurring chemical reaction on substrate surface. when we do wet etching process, we have to consider stoichiometry, etching time and temperature of etchant for good resolution. In this experiment, we used Cr, Al andIndium-tin-oxide (ITO) metal and we deposited them with DC sputtering machine. The Cr thin film metal thickness is about $1300{\AA}$, ITO films show a low electrical resistance and high transmittance in the visible range of an optical spectrum and Ai film is used for signal line. We measured and analysed wet etching properties on the metal thin films.

Evaluation of BR Blending Methods for ESBR/silica Wet Masterbatch Compounds

  • Kim, Woong;Ahn, Byungkyu;Mun, Hyunsung;Yu, Eunho;Hwang, Kiwon;Kim, Wonho
    • Elastomers and Composites
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    • v.52 no.4
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    • pp.242-248
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    • 2017
  • Wet masterbatch (WMB) technology is studied to develop high-content and highly disperse silica-filled compounds. This technology refers to the solidification of surface-modified silica with a rubber solution or latex. Until now, researchs based on styrene butadiene rubber (SBR)/silica WMB has been mainly performed. However, the blending of SBR/silica WMB and BR is not known and is currently under research and development. Therefore, in this study, the BR blending method suitable for emulsion (ESBR)/silica WMB is investigated by measuring their cure characteristics and the mechanical and dynamic viscoelastic properties. As a result, it was confirmed that the blending of ESBR/silica WMB and BR/silica dry masterbatch is most appropriate. However, it showed a disadvantage compared with the conventional mixing method, which was due to the surfactant remained and the sulfuric acid used as the coagulant.

Improvement of Multiply Board Properties with Starch Spraying (전분 분무기술을 통한 다층지의 물성개선)

  • Lee, Hak-Lae;Ryu, Jeong-Yong
    • Journal of Korea Technical Association of The Pulp and Paper Industry
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    • v.39 no.3
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    • pp.12-23
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    • 2007
  • Frequently spraying of natural starch slurry onto the formed wet web has been adopted to improve properties of paperboards. This conventional starch spraying technique, however, becomes less effective in strength improvement. In this study the effects of various factors including wet web dryness, quantity of starch slurry sprayed, and drying temperature on paperboard properties were investigated. Migration of starch granules into the webs appeared to cause a reduction in plybond strength when the web dryness was lower than this level. Wet webs should contain enough water to swell the starch granules, and at the same time they should be heated to a temperature high enough for complete cooking of the sprayed starches to occur. This suggested that preheating of the wet web can be employed to improve the plybond strength.

Fabrication of Size- and Shape- Controlled Gold Particles using Wet Chemical Process (환원 석출법을 이용한 모양과 크기가 제어된 금 입자의 제조)

  • Hong, So-Ya;Lee, Chang-Hwan;Kim, Joo-Yong
    • Textile Coloration and Finishing
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    • v.22 no.2
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    • pp.123-131
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    • 2010
  • Shape and size controlled synthesis of gold particles has been studied by using wet-chemical method. When ${AuCl_4}^-$ in aqueous $HAuCl_4$ precursor was reduced using $Na_2SO_3$ as a reducing agent, mixtures of spherical, triangular and hexagonal particles were prepared in a few minutes. It was found that the shape selective oxidative etching by ${AuCl_4}^-\;+\;Cl^-$ anions and crystal growth took place simultaneously. As the ${AuCl_4}^-$ and $Cl^-$ concentration increased, yields of large triangular and hexagonal plate type particles increased, while the spherical particles decreased in most cases. Possible etching and growth mechanisms are discussed.

Preparation of Ag Powder by Wet Reduction Method using NaBH4 Reducing Agent (습식환원법에서 NaBH4환원제를 이용한 Ag분말의 제조)

  • Won Chang-Whan;Lee Huk-Hee
    • Journal of Powder Materials
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    • v.13 no.4 s.57
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    • pp.278-284
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    • 2006
  • Spherical Ag powder was prepared in the system of $AgNO_3\;and\;NaBH_4$ by wet chemical reduction method. The size of Ag powder was increased as the reaction temperature and the concentration of reducing agent was decreased in the constant concentration of dispersion agent. Optimum conditions of producing Ag powder having $1.39{\mu}m$ of D50 was 1M of $AgNO_3$, 0.5M of $NaBH_4$, 1.5g of Gelatine in the room temperature.

Coating of Cobalt Over Tungsten Carbide Powder by Wet Chemical Reduction Method

  • Hong, Hyun-Seon;Yoon, Jin-Ho
    • Journal of Powder Materials
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    • v.21 no.2
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    • pp.93-96
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    • 2014
  • Cobalt coated tungsten carbide-cobalt composite powder has been prepared through wet chemical reduction method. The cobalt sulfate solution was converted to the cobalt chloride then the cobalt hydroxide. The tungsten carbide powders were added in to the cobalt hydroxide, the cobalt hydroxide was reduced and coated over tungsten carbide powder using hypo-phosphorous acid. Both the cobalt and the tungsten carbide phase peaks were evident in the tungsten carbide-cobalt composite powder by X-ray diffraction. The average particle size measured via scanning electron microscope, particle size analysis was around 380 nm and the thickness of coated cobalt was determined to be 30~40 nm by transmission electron microscopy.

Optimizing Oily Wastewater Treatment Via Wet Peroxide Oxidation Using Response Surface Methodology

  • Shi, Jianzhong;Wang, Xiuqing;Wang, Xiaoyin
    • Journal of the Korean Chemical Society
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    • v.58 no.1
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    • pp.80-84
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    • 2014
  • The process of petroleum involves in a large amount of oily wastewater that contains high levels of chemical oxygen demand (COD) and toxic compounds. So they must be treated before their discharge into the receptor medium. In this paper, wet peroxide oxidation (WPO) was adopted to treat the oily wastewater. Central composite design, an experimental design for response surface methodology (RSM), was used to create a set of 31 experimental runs needed for optimizing of the operating conditions. Quadratic regression models with estimated coefficients were developed to describe the COD removals. The experimental results show that WPO could effectively reduce COD by 96.8% at the optimum conditions of temperature $290^{\circ}C$, $H_2O_2$ excess (HE) 0.8, the initial concentration of oily wastewater 3855 mg/L and reaction time 9 min. RSM could be effectively adopted to optimize the operating multifactors in complex WPO process.

Carbon bead-supported copper-dispersed carbon nanofibers: An efficient catalyst for wet air oxidation of industrial wastewater in a recycle flow reactor

  • Yadav, Ashish;Verma, Nishith
    • Journal of Industrial and Engineering Chemistry
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    • v.67
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    • pp.448-460
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    • 2018
  • Copper nanoparticle-doped and graphitic carbon nanofibers-covered porous carbon beads were used as an efficient catalyst for treating synthetic phenolic water by catalytic wet air oxidation (CWAO) in a packed bed reactor over 10-30 bar and $180-230^{\circ}C$, with air and water flowing co-currently. A mathematical model based on reaction kinetics assuming degradation in both heterogeneous and homogeneous phases was developed to predict reduction in chemical oxygen demand (COD) under a continuous operation with recycle. The catalyst and process also showed complete COD reduction (>99%) without leaching of Cu against a high COD (~120,000 mg/L) containing industrial wastewater.