Journal of Industrial and Engineering Chemistry

  • Volume 67
  • /
  • Pages.448-460
  • /
  • 2018
  • /
  • 1226-086X(pISSN)
  • /
  • 1876-794X(eISSN)
The Korean Society of Industrial and Engineering Chemistry (한국공업화학회)
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Carbon bead-supported copper-dispersed carbon nanofibers: An efficient catalyst for wet air oxidation of industrial wastewater in a recycle flow reactor

  • Yadav, Ashish (Department of Chemical Engineering, Indian Institute of Technology Kanpur) ;
  • Verma, Nishith (Department of Chemical Engineering, Indian Institute of Technology Kanpur)
  • Received : 2018.03.18
  • Accepted : 2018.07.15
  • Published : 2018.11.25
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Abstract

Copper nanoparticle-doped and graphitic carbon nanofibers-covered porous carbon beads were used as an efficient catalyst for treating synthetic phenolic water by catalytic wet air oxidation (CWAO) in a packed bed reactor over 10-30 bar and $180-230^{\circ}C$, with air and water flowing co-currently. A mathematical model based on reaction kinetics assuming degradation in both heterogeneous and homogeneous phases was developed to predict reduction in chemical oxygen demand (COD) under a continuous operation with recycle. The catalyst and process also showed complete COD reduction (>99%) without leaching of Cu against a high COD (~120,000 mg/L) containing industrial wastewater.

Keywords

Acknowledgement

Supported by : Shell Technology Centre Bangalore

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