• Advances in concrete construction
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• v.8 no.3
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• pp.217-223
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• 2019

This paper presents the mechanical and microstructural properties of the geopolymer paste which was developed by utilizing the industrial by-products, rice husk ash (RHA) and ultra-fine slag. Ultra-fine slag particles with average particle size in the range of 4 to 5 microns. RHA is partially replaced with ultra-fine slag at different levels of 0 to 50%. Sodium silicate to sodium hydroxide ratio of 1.0 and alkaline liquid to binder (AL/B) ratio of 0.60 is taken. Setting time, compressive, flexural strengths were studied up to the age of 90 days with different concentrations of NaOH. The microstructure of the hybrid geopolymer paste was studied by performing the SEM, EDS, and XRD on the broken samples. RHA based geopolymer paste blended with ultrafine slag resulted in high compressive and flexural strengths and increased setting times of the paste. Strength increased with the increase in NaOH concentration at all ages. The ultra-small particles of the slag acted as a micro-filler into the paste and enhanced the properties by improving the CASH, NASH, and CSH. The maximum compressive strength of 70MPa was achieved at 30% slag content with 16M NaOH. The results of XRD, SEM, and EDS at 30% replacement of RHA with ultra-fine slag densified the paste microstructure.

• Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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• 2001.07a
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• pp.1080-1083
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• 2001

Ultrafine NiO/YSZ composite powders were prepared by using a glycine nitrate process for anode material of solid oxide fuel cells. The specific surface areas of synthesized NiO/YSZ composite powders were examined with controlling pH of a precursor solution and the content of glycine. The characteristics of synthesized composite powders were examined with X-ray diffractometer, a BET method with N$_2$absorption, scanning and transmission electron microscopy. The strongly acid precursor solution increased the specific surface area of the synthesized composite powders. This is suggested to be caused by the increased binding of metal ions and glycine under a strong acid solution of pH=0.5 that lets glycine consist of mainly the amine group of NH$_3$$\^$+/. After sintering and reducing treatment of NiO/YSZ composite powders synthesized by GNP, the Ni/YSZ pellet showed ideal micro-structure very fine Ni parties of 3-5${\mu}$m were distributed uniformly and fine pores around Ni metal particles were formed, thes, leading to an increase of the triple phase boundary among gas Ni and YSZ.

• Korean Journal of Air-Conditioning and Refrigeration Engineering
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• v.6 no.4
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• pp.417-426
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• 1994

Filter media performance was evaluated using monodisperse NaCl particles with Differential Mobility Analyzer and Ultrafine Condensation Particle Counter. Low or medium performance filters show that the most penetrating particles size(MPPS) is around $0.3{\mu}m$ in diameter and is shifted to smaller sizes as the filter face velocity increases. However, HEPA and ULPA filters show MPPS is around $0.15{\mu}m$ in diameter and is also shifted to $0.1{\mu}m$ in diameter as the face velocity increases. In case of electret filter, the MPPS is found around $0.04{\mu}m$ region for Boltzmann charge equilibrium particles. There is a tendency of strong collection efficiency decrease for large particles as the face velocity increases on the contrary to the other filters. One of the medium performance filter efficiency was compared with filtration theory and the good agreetment was found in the experimental range.

• Asian Journal of Atmospheric Environment
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• v.11 no.2
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• pp.131-137
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• 2017

A cyclone is an effective tool to facilitate the collection of aerosol particles without using filters, and in cell exposure studies is able to collect a sufficient amount of aerosol particles to evaluate their adverse health effect. In this study, we examined two different methods to improve the aerosol particle collection efficiency of a cyclone. The individual and combined effects of reducing the surface roughness of the inner wall of the cyclone and of using a circular cone attachment were tested. The collection efficiency of particles of diameter $0.2{\mu}m$ was improved by approximately 10% when using a cyclone with a smoothened inner wall (average roughness $Ra=0.08{\mu}m$) compared with the original cyclone ($Ra=5.1{\mu}m$). A circular cone attachment placed between the bottom section of the cyclone and the top section of a collection bottle, resulted in improved collection of smaller particles without the attachment. The 50% cutoff diameter of the modified cyclone (combined use of smoothened inner wall and attachment) was $0.23{\mu}m$ compared to $0.28{\mu}m$ in the original model. The combined use of these two techniques resulted in improved collection efficiency of aerosol particles.

• Journal of Industrial Technology
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• v.17
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• pp.241-247
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• 1997

A numerical model has been proposed for a diffusion flame reactor to manufacture ultrafine $TiO_2$ powders. The model equations such as mass balance equation, the 0th, 1st, and 2nd moment equations of aerosols were considered. The phenomena such as $TiCl_4$ reaction rate, $TiO_2$ nucleation rate and the coagulation of $TiO_2$ powders were included in the aerosol dynamic equation. It is found that the $TiO_2$ particle concentration becomes higher, as the inlet $TiCl_4$ concentration and the total gas flow rate increase, and also as the flame temperature decreases. The $TiO_2$ particle size increases, as the flame temperature and the inlet $TiCl_4$ concentration increase and the total gas flow rate decreases.

• Proceedings of the Korea Association of Crystal Growth Conference
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• 1996.06a
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• pp.497-501
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• 1996

The ZnFe2O4 powder were prepared under glycothermal conditions by precipitation from metal nitrates with aqueous potassium hydroxide. Ultrafine particles of the ZnFe2O4 were obtained at temperatures as low as 225-300$^{\circ}C$. The microstructure and phase of the ZnFe2O4 powder was studied by SEM and XRD. The properties of the powder were studied as a function of various parameters (reaction temperature, reaction time, solid loading). The average particle diameter of the ZnFe2O4 increased with increasing reaction temperature. After glycothermal treatment at 270$^{\circ}C$ for 8hrs., the average particle diameter of the ZnFe2O4 was about 50 nm.

• Journal of Powder Materials
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• v.1 no.2
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• pp.208-216
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• 1994

A radically new approach to the in situ synthesis of the consituent phases of a composite structure has enabled the production of a new WC/Co materials with an ultrafine microstructure. The process for synthesizing nanophase WC/Co powders consists of spray drying from solution to form a homogeneous precursor powder, and thermochemical conversion of the precursor powder to the nanophase WC/Co powder. Near theoretical density of pure nanophase WC-10 wt%Co has been obtained in only 30 sec at 140$0^{\circ}C$. But WC particles were grown up very rapidly with longer sintering time to get full density. To overcome coarsening of WC particle during sintering, VC, TaC and VC/TaC were used as the grain growth inhibitor with different amount respectively. VC/TaC doped WC-10 wt%Co was shown superior hardness and TRS and microstructure was maintained ultrafine scale (average WC size is less than 0.1 ${\mu}{\textrm}{m}$).

• Journal of the Korean Crystal Growth and Crystal Technology
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• v.6 no.4
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• pp.509-520
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• 1996

Ultrafine calcim carbonate powders with the size of $0.05~0.1\;{\mu}m$ and the calcite phase were synthesized by the nozzle spouting method, which could be only obtained when high calcium ion concentration within slurry was maintained at the beginning of the reaction. But, in the regions of low ${Ca(OH)}_2$ concentration (0.5~1.0 wt%) or high ${Ca(OH)}_2$ concentration (<3.0 wt%), synthesized calcium carbonate powder was shown the large particle size with agglomeration. To obtain ultrafine calcium carbonate powder in this region, the methods of slurry circuation and $CO_{2}$ gas supply were changed during reaction. Resultly, it was possible to synthesize ultrafine particles (${\approx}0.05{\mu}\textrm{m}$)in the regions of low ${Ca(OH)}_2$ concentration (${\approx}0.5wt%$) and high ${Ca(OH)}_2$ concentration (${\approx}0.5wt%$), which can not be obtained the fine calcium carbonate powder still now.

• Journal of Powder Materials
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• v.17 no.2
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• pp.142-147
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• 2010

The ultrafine titanium carbonitride ($TiC_xN_y$) particles below 100 nm in mean size, including various carbon and nitrogen contents (x=0.55~0.9, y=0.1~0.5), were successfully synthesized by new Mg-thermal reduction process. Nanostructured sub-stoichiometric titanium carbide ($TiC_x$) particles were initially produced by the magnesium reduction of gaseous $TiCl_4+x/2C_2Cl_4$ at $890^{\circ}C$ and post heat treatments in vacuum were performed for 2 hrs to remove residual magnesium and magnesium chloride mixed with $TiC_x$. Finally, well C/N-controled $TiC_xN_y$ phases were successfully produced by nitrification heat treatment under normal $N_2$ gas atmosphere at $1150^{\circ}C$ for 2 hrs. The values of purity, mean particle size and oxygen content of produced particles were about 99.3%, 100 nm and 0.2 wt.%, respectively.

• Journal of Powder Materials
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• v.10 no.1
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• pp.57-62
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• 2003

The effect of bedding on the microstructure of $Si_3N_4$ added with ultra-fine SiC was investigated. The bedding and the addition of ultra-fine SiC effectively inhibited grain growth of $Si_3N_4$ matrix grain. The microstructures of the specimens sintered with bedding powder consisted of fine-grains as compared with the specimens sintered without bedding powder. In addition, the grain size and the difference of grain size between the specimens sintered with bedding and without bedding was reduced with increasing SiC content. Some ultra-fine SiC particles were trapped in the $Si_3N_4$ grains growed. The number of SiC particles trapped in the $Si_3N_4$ grains increased with increasing the grain growth. When ultra-fine SiC particles were added in the $Si_3N_4$ ceramics, the strength was improved but the toughness was decreased, which was considered to be resulted from the decrease of the grain size.