• Title/Summary/Keyword: total enthalpy

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Chromatographic Separation of Some Phenol Derivatives Using $\alpha$-Cyclodextrin in Mobile Phase ($\alpha$-씨클로덱스트린을 이동상으로 사용한 몇 가지 페놀 유도체들의 크로마토그래피적 분리)

  • 문영자;김봉희
    • Environmental Analysis Health and Toxicology
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    • v.12 no.3_4
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    • pp.75-84
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    • 1997
  • Chromatographic retention behavior and separation of various phenol derivatives on a Partisil 10 ODS 3 column-with mobile phase containing $\alpha$-cyclodextrin-were systematically studied. The decrease in k' values caused by the addition of cyclodextrins in the mobile phase was based on the formation of an inclusion complex, resulting in weakening of the hydrophobic interaction between solutes and the stationary phase. The content of the organic solvent in the mobile phase also influenced k' values of the solutes, and k' values increased with a decrease of the content of organic solvent in the mobile phase. A simple equation has been derived that reveals the hyperbolic dependence of the capacity factor on the total concentration of cyclodextrin. A plot of the reciprocal of the capacity factor against (CD)$_T$ gives a straight line and the dissociation constant, K$_D$, of the inclusion complex can be calculated from the slope. The capacity factor decreased with increasing temperature. The enthalpy was calculated from the slope of van't Hoff plots. Under optimum conditions, some mixtures of phenol derivatives were able to separated successfully.

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A Study on the Performance of Paper Heat Exchanger for Exhaust Heat Recovery (배기열 회수용 종이 열교환기의 성능에 관한 연구)

  • Yoo, Seong-Yeon;Chung, Min-Ho;Choi, Jae-Ho;Kwon, Hwa-Kil;Lee, Chun-Woo;Lee, Ki-Seong
    • 유체기계공업학회:학술대회논문집
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    • 2003.12a
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    • pp.245-250
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    • 2003
  • In order to control indoor air quality and save energy, it is needed to install a suitable ventilation system equipped with heat exchanger for heat recovery. The purpose of this research is to find the performance of paper heat exchanger for exhaust heat recovery, which exchanges latent heat as well as sensible heat. Experimental apparatus comprises heat exchanger model, constant temperature and humidity chamber, fan and measurement systems for temperature, pressure and flow rate. Thermal performance and pressure loss of the paper heat exchanger are measured and compared at various air velocities and outdoor conditions. Experimental results show that paper heat exchanger can recover $50{\sim}70%$ of the enthalpy difference between supply and exhaust air.

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용탕유동과 응고를 고려한 주조공정의 유한요소해석

  • 윤석일;김용환
    • Proceedings of the Korean Society of Precision Engineering Conference
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    • 1995.04a
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    • pp.620-625
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    • 1995
  • Finite element analysis tool was developed to analyze the casting process. Generally, casting processes consists of mold filling and solifification. In order to investigate the effects of process variables and to predict the defects, both filling and solidiffication process were simulated simultaneously. At filling process, especiallywe consider thermal coupling to investigate thermal history of material during the filling stage. And thermal condition at the final stage of filling is used as the initial conditions in a solidification process for the exact simulation of the actual casting processes. At mold filling process, Lagrangian-type finite element method with automatic remashing scheme was used to find the material flow. To avoid numerical instability in low viscous fluid, a perturbation method with artificial viscosity is adopted. At solififfication process, enthalpy-based finite element method was used to solve the heat transfer problem with phase change. And elastic stress analysis has been performed to predict the thermal residual stress. Through the FE analysis, solidiffication time, position of solidus line, liquidus line and thermal residual stress are studied. Finite element tools developed in this study will be used process design of casting process and maybe basic structure for total CAE system of castigs which will be constructed afterward.

Study on the Performance of Total Heat Exchanger with Rotating Porous Plates (다공형 전열판의 회전에 의한 열교환시스템의 성능에 관한 연구(Ⅰ) - 환기측과 외기측의 풍량 변화에 대하여 -)

  • Cho, D.H.;Lim, T.W.
    • Journal of Power System Engineering
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    • v.9 no.4
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    • pp.11-17
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    • 2005
  • This paper reports an experimental study on the performance evaluation of air-to-air heat exchanger with rotary type newly developed in this study. Air flow rate is varied from 10 to 120 m3/h. The range of RPM of the porous rotating discs mounted inside the heat exchanger unit is 0 to 50. The temperature of the return air side is set by adjusting heat supply at heater. The material of the porous rotating discs is cooper and its thickness is 1.0 mm. The heat transfer rate increased with the increase in air flow rate. It was found that the heat transfer rate, as the temperature of the return air side was increased, was improved due to higher temperature difference. The heat exchange performance increased with the increase in the temperature of the return air side at the conditions of the same RPM. The sensible heat exchange efficiency was maximum 68 to 76 percent, and enthalpy exchange efficiency 64 to 74 percent.

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Study on the Performance of Total Heat Exchanger with Rotating Porous Plates (다공형 전열판의 회전에 의한 열교환시스템의 성능에 관한 연구(Ⅱ) - 전열판의 회전수 변환에 대하여 -)

  • Lim, T.W.;Cho, D.H.
    • Journal of Power System Engineering
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    • v.9 no.4
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    • pp.18-23
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    • 2005
  • The experimental investigation was carried out to evaluate the performance of air-to-air heat exchanger with rotating porous plates newly developed in this study. The rotating porous plates are mounted with an equal interval of 18 mm inside the heat exchanger where the hot and cold airs enter at opposite ends. When flowing in opposite directions by the separating plate installed in the center of the rotating porous plates, the airs give and receive the heat each other. The material of the porous plate is cooper and its thickness is 1.0 mm. Air flow rate is varied from 10 to 120 m3/h. From the experiment of air-to-air heat exchanger with the rotating porous plates, the heat exchange performance increased with the increase in RPM of the porous rotating discs at the conditions of the same air flow rate. The sensible heat exchange efficiency was maximum 60 to 70 percent, and enthalpy exchange efficiency 50 to 60 percent.

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Experimental Study on Performance Evaluation of System Air-Conditioner using Compressor of PWM or Inverter Method (Cooling and Heating Characteristics) (PWM 방식과 인버터 방식의 압축기를 사용한 시스템 에어컨의 성능평가에 대한 실험적 연구(냉난방 특성))

  • 전용호;김대훈;허삼행;권영철;문제명;홍주태
    • Korean Journal of Air-Conditioning and Refrigeration Engineering
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    • v.15 no.9
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    • pp.738-743
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    • 2003
  • In the present study, the heating and cooling characteristics of system air-conditioner using a PWM compressor or a BLDC inverter compressor are investigated by the psychometric calorimeter using air enthalpy method. Cooling and heating capacities, power inputs and COPs are measured at the low, moderate, high loads under the cooling and heating standard conditions. At cooling conditions, the capacity of the PWM system is larger than that of the inverter case. Due to large power input, however, low COPs are measured under total load ranges. At heating conditions, the capacity of the PWM method is a little larger than that of the inverter case, except high load range. Since power input is low, large COPs are measured at moderate and high load ranges, which are different from cooling data. This shows that the PW system compared with the inverter case has good energy consumption efficiency at moderate and high load ranges except low load range. And when the system A/C is operated under the cooling and heating standard conditions, COPs are nearly uniform at total load ranges.

Study on the Frosting Phenomenon of the Fin and Tube Heat Exchanger with a Louvered Fin (루버형 휜을 가진 휜관형 열교환기의 착상현상 연구)

  • Kim, Jung-Kuk;Kuwahara, Ken;Koyama, Shigeru;Park, Byung-Duck
    • Journal of the Korean Society of Industry Convergence
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    • v.11 no.4
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    • pp.157-163
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    • 2008
  • The present study investigated the pressure drop and the total frost mass of the louvered fin type heat exchanger, which is widely used at the air-conditioning system. The pressure drop due to the frosting phenomenon and the total frost mass were investigated by changing the wet bulb temperature condition of the inlet air. Hence the brain of 55wt% was used as a cooling solution instead of a common refrigerant. The temperature difference between the brine and the tube outside wall at the outlet of heat exchanger was $10^{\circ}C$, at maximum, higher than that at the inlet of heat exchanger. As the wet bulb temperatures were increased, the pressure drop was linearly increased due to the increment of frost mass. And the increment of heat exchange rate was smaller than that of inlet air enthalpy due to the increment of frost mass. The pressure drop of air side was rapidly increased due to the progress of frosting phenomena. The run time that the pressure drop occurred rapidly was decreased by the growth of frost.

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A Study on Building Energy Saving using Outdoor Air Cooling by Load Prediction (부하예측 외기냉방에 의한 건물에너지 절약에 관한 연구)

  • Kim, Tae-Ho;Yoo, Seong-Yeon;Kim, Myung-Ho
    • Korean Journal of Air-Conditioning and Refrigeration Engineering
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    • v.29 no.2
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    • pp.43-50
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    • 2017
  • The purpose of this study is to develop a control algorithm for outdoor air cooling based on the prediction of cooling load, and to evaluate the building energy saving using outdoor air cooling. Outdoor air conditions such as temperature, humidity, and solar insolation are predicted using forecasted information provided by the meteorological agency, and the building cooling load is predicted from the obtained outdoor air conditions and building characteristics. The air flow rate induced by outdoor air is determined by considering the predicted cooling loads. To evaluate the energy saving, the benchmark building is modeled and simulated using the TRNSYS program. Energy saving by outdoor air cooling using load prediction is found to be around 10% of the total cooling coil load in all locations of Korea. As the allowable minimum indoor temperature is decreased, the total energy saving is increased and approaches close to that of the conventional enthalpy control.

Defect Structure and Electrical Conductivities of $SrCe_{0.95}Yb_{0.05}O_3$ ($SrCe_{0.95}Yb_{0.05}O_3$의 결함엄개와 전기전도 특성)

  • 최정식;이도권;유한일
    • Journal of the Korean Ceramic Society
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    • v.37 no.3
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    • pp.271-279
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    • 2000
  • 5 m/o Yb-doped SrCeO3 proton conductor was prepared by a solid state reaction method and its total electriccal conductivity measured as a function of both oxygen partial pressure and water vapor partial pressure in the temperature range of 500~100$0^{\circ}C$. From the total conductivity have been deconvoluted the partial conductivities of oxide ions, protons, and holes, respectively, on the basis of the defect model proposed. The equilibrium constant of hydrogen-dissolution reaction, proton concentration, and mobilities of oxygen vacancies and protons have subsequently been evaluated. It is verified that SrCe1-xYbxO3 is a mixed conductor of holes, protons and oxide ions and the proton conduction prevails as temperature decreases and water vapor pressure increases. The heat of water dissolution takes a representative value of $\Delta$HoH=-(140$\pm$20) kJ/mol-H2O, but tends to be less negative with increasing temperature. Migration enthalpies of proton and oxygen vacancy are extracted as 0.83$\pm$0.10 eV and 0.81$\pm$0.01 eV, respectively.

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Effect of Heating Rates on the Thermal Denaturation of Pork Loin Muscle (가열속도가 돈육 등심 근육의 열변성에 미치는 영향)

  • Kim, Cheon-Jei;Song, Min-Seok;Lee, Chang-Hyun;Lee, Eui-Soo;Cho, Jin-Kook;Choi, Do-Young
    • Korean Journal of Food Science and Technology
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    • v.31 no.3
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    • pp.678-681
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    • 1999
  • The objective of this study was to evaluate the effect of different heating rates on the thermal properties of pork loin muscle by DSC. Pork loin muscle was subjected to programmed heating at the following heating rate: 5, 10, 20, 30 and $40^{\circ}C/min$. Peaks were progressively shifted to right side as the heating rate was increased. $T_0$ was $50.39^{\circ}C$ at $5^{\circ}C/min$ and it was increased to $57.45^{\circ}C$ at $40^{\circ}C/min$ (p<0.05). Total enthalpy was 3.52 J/g at $5^{\circ}C/min$ and total enthalpy was increased to 3.60, 4.14, 4.54 and 4.61 J/g by degrees at heating rate 10, 20, 30 and $40^{\circ}C/min$ respectively.

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