• 제목/요약/키워드: systematic analytical method

검색결과 88건 처리시간 0.023초

방향족 유기화합물의 가스상 시료를 이용한 피복류의 흡착특성 비교에 대한 예비연구 (A preliminary study of sorptive characteristics of aromatic volatile organic compounds (VOC) on clothing materials)

  • 김기현;임문순;박신영;홍윤정;최여진;이유선;김성덕;남상호;옥준석
    • 분석과학
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    • 제19권3호
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    • pp.255-262
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    • 2006
  • 본 연구에서는 VOC가 옷감이나 물질소재와 접촉하여 흡착손실하는 경향을 평가하고자 하였다. 이를 위하여 필터홀더에 필터의 형식으로 비교대상 소재를 장착하고 이들에 VOC 가스를 흘려주는 방식으로 화합물의 흡착손실반응을 평가할 수 있는 기법의 적용 가능성을 다각도로 평가하였다. 테플론 소재의 필터는 양호한 안정성이나 재현성을 보여 주었다. 이러한 시스템에 각각의 소재(글래스 파이버, 면, 나일론)를 장착한 상태로 벤젠, 톨루엔, 자일렌이 혼합된 가스를 흘려 주면서 각각의 검량선을 작성하였다. 본 연구의 결과에 의하면, 각각의 소재 및 VOC 성분별로 뚜렷한 흡착특성을 확인할 수 있었다. 소재들 중에서는 글래스 파이버 < 면 < 나일론의 순서로 그리고 성분별로는 벤젠 < 톨루엔 <자일렌의 순서로 흡착손실이 증가하는 양상이 뚜렷하게 나타났다. 그 결과, 재질이나 화학물질의 특성과 같은 변수가 동시에 흡착손실의 경향성을 결정짓는다는 결론에 도달하였다.

Numerical study on the performance of semicircular and rectangular submerged breakwaters

  • Barzegar, Mohammad;Palaniappan, D.
    • Ocean Systems Engineering
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    • 제10권2호
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    • pp.201-226
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    • 2020
  • A systematic numerical comparative study of the performance of semicircular and rectangular submerged breakwaters interacting with solitary waves is the basis of this paper. To accomplish this task, Nwogu's extended Boussinesq model equations are employed to simulate the interaction of the wave with breakwaters. The finite difference technique has been used to discretize the spatial terms while a fourth-order predictor-corrector method is employed for time discretization in our numerical model. The proposed computational scheme uses a staggered-grid system where the first-order spatial derivatives have been discretized with fourth-order accuracy. For validation purposes, five test cases are considered and numerical results have been successfully compared with the existing analytical and experimental results. The performances of the rectangular and semicircular breakwaters have been examined in terms of the wave reflection, transmission, and dissipation coefficients (RTD coefficients) denoted by KR, KT, KD. The latter coefficient KD emerges due to the non-energy conserving KR and KT. Our computational results and graphical illustrations show that the rectangular breakwater has higher reflection coefficients than semicircular breakwater for a fixed crest height, but as the wave height increases, the two reflection coefficients approach each other. un the other hand, the rectangular breakwater has larger dissipation coefficients compared to that of the semicircular breakwater and the difference between them increases as the height of the crest increases. However, the transmission coefficient for the semicircular breakwater is greater than that of the rectangular breakwater and the difference in their transmission coefficients increases with the crest height. Quantitatively, for rectangular breakwaters the reflection coefficients KR are 5-15% higher while the diffusion coefficients KD are 3-23% higher than that for the semicircular breakwaters, respectively. The transmission coefficients KT for rectangular breakwater shows the better performance up to 2.47% than that for the semicircular breakwaters. Based on our computational results, one may conclude that the rectangular breakwater has a better overall performance than the semicircular breakwater. Although the model equations are non-dissipative, the non-energy conserving transmission and reflection coefficients due to wave-breakwater interactions lead to dissipation type contribution.

환경대기 중 저분자 PAHs 측정을 위한 흡착-열탈착-GC/MS 방법의 적용 (Application of Adsorption Sampling and Thermal Desorption with GC/MS Analysis for the Measurement of Low-Molecular Weight PAHs in Ambient Air)

  • 서석준;서영교;황윤정;정동희;백성옥
    • 한국대기환경학회지
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    • 제30권4호
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    • pp.362-377
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    • 2014
  • Polycyclic aromatic hydrocarbons (PAHs) have been of particular concern since they are present both in the vapor and particulate phases in ambient air. In this study, a simple method was applied to determine the vapor phase PAHs, and the performance of the new method was evaluated with a conventional method. The simple method was based on adsorption sampling and thermal desorption with GC/MS analysis, which is generally applied to the determination of volatile organic compounds (VOCs) in the air. A combination of Carbotrap (300 mg) and Carbotrap-C (100 mg) sorbents was used as the adsorbent. Target compounds included two rings PAHs such as naphthalene, acenaphthylene, and acenaphthene. Among them, naphthalene was listed as one of the main HAPs together with a number of VOCs in petroleum refining industries in the USA. For comparison purposes, a method based on adsorption sampling and solvent extraction with GC/MS analysis was adopted, which is in principle same as the NIOSH 5515 method. The performance of the adsorption sampling and thermal desorption method was evaluated with respect to repeatabilities, detection limits, linearities, and storage stabilities for target compounds. The analytical repeatabilities of standard samples are all within 20%. Lower detection limits was estimated to be less than 0.1 ppbv. In the results from comparison studies between two methods for real air samples. Although the correlation coefficients were more than 0.9, a systematic difference between the two groups was revealed by the paired t-test (${\alpha}$=0.05). Concentrations of two-rings PAHs determined by adsorption and thermal desorption method consistently higher than those by solvent extraction method. The difference was caused by not only the poor sampling efficiencies of XAD-2 for target PAHs and but also sample losses during the solvent extraction and concentration procedure. This implies that the levels of lower molecular PAHs tend to be underestimated when determined by a conventional PAH method utilizing XAD-2 (and/or PUF) sampling and solvent extraction method. The adsorption sampling and thermal desorption with GC analysis is very simple, rapid, and reliable for lower-molecular weight PAHs. In addition, the method can be used for the measurement of VOCs in the air simultaneously. Therefore, we recommend that the determination of naphthalene, the most volatile PAH, will be better when it is measured by a VOC method instead of a conventional PAH method from a viewpoint of accuracy.

삭시톡신과 그 유사체: 독성, 분석법, 국내외 오염도 및 관리 동향 (Saxitoxin and Its Analogues: Toxicity, Analytical Method, Occurrence and Safety Management)

  • 이상유;임주희;우소영;최화영;박수빈;유차니;전향숙
    • 한국식품위생안전성학회지
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    • 제35권6호
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    • pp.521-534
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    • 2020
  • 마비성 패독(paralytic shellfish poisoning, PSP)에 의한 중독은 와편모조류(Dinoflagellates)가 생성하는 saxitoxin (STX)이 이매패류 등의 먹이활동에 의해 축적되고 이를 사람이 섭취함으로써 발생한다. 최근 분석기술의 발전으로 와편모조류가 STX외에도 gonyautoxin (GTX) group 및 N-sulfo carbamoyl toxins (C toxin) group 등 다양한 유사체들을 생성하는 것으로 보고되고 있다. 이에 CODEX, EFSA에서는 STX외 유사체의 안전관리를 위해 STX 및 유사체를 STX group으로 관리하고자 하는 움직임을 보이고 있다. 국내의 경우도 STX 유사체를 생성하는 조류의 발생이 이미 보고되고 있으며 실제 홍합에서 유사체의 오염사례도 소수 보고되고 있다. 따라서 국제적인 움직임에 발맞추어 국내에서도 STX 및 유사체의 group 관리를 위한 준비가 필요할 것으로 사료된다. 본 연구에서는 STX 및 유사체의 체계적인 모니터링 및 안전관리의 기반을 마련하고자 STX 및 유사체의 이화학적 특성, 생성조류, 국내외 발생현황, 독성 및 상대독성계수, 분석법, 오염현황 및 관리현황에 대한 폭넓은 검토를 수행하고자 하였다.

AHP를 이용한 도시의 삶의 질 비교 (A Comparative Evaluation of Urban Quality of Life Using AHP)

  • 김동윤
    • 한국디지털건축인테리어학회논문집
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    • 제13권1호
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    • pp.33-41
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    • 2013
  • Considering the fact that quality of life(QOL) conceptually has objective and subjective attributes but difficulties in measuring the subjective aspect cause a number of studies not to be balanced, this study exploits AHP(Analytical Hierarchy Process) which has been used for systematic decision making to include the other aspect. As the first step of the process decision making hierarchy model is set by content analysis of the UNDP QOL index and additional review of previous studies. 'Improving urban QOL' is a goal on top, 'Economical QOL', 'Environmental QOL', 'Social QOL' and 'Physical QOL' are dimensions of sub-goal(means objectives), and further decomposition follows. AHP shows that the dimensions of economical, physical, environmental and social QOL scored higher respectively. The aim of the model is to measure and prioritize the urban QOL in the two case study cities. The final score of the each city could be computed by integration of relative weights of dimensions for urban QOL. The final score of QOL for city A was 0.6642 and for city B the figure decreased to 0.3358. The method of this study could be used in stages of the process of urban planning. First stage is when planners try to have a correct and reliable perspective from the existed conditions of the city. Second stage is when the projects should be investigated to be confirmed for their efficiency. In other words planners can direct the scarce resources towards the aspects of QOL which are more important. And the results revealed that using AHP creates opportunity to involving the different groups in the stage of criteria weighting so that the attitudes of local community could be integrated well to the decision making to be suitable for a new paradigm of participatory and communicative planning.

취약청소년 자립지원을 위한 취업지원 프로그램 개선방안 연구 : 캐나다와의 비교 (Study of Improvement Plan for the Employment Support Program to Promote Self-Reliance of the Disadvantaged Youth: Compared to Canada Case)

  • 이송희;김린아
    • 한국콘텐츠학회논문지
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    • 제17권2호
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    • pp.269-277
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    • 2017
  • 본 논문은 국가차원에서 취약청소년 취업지원을 위해 다양한 개입전략 및 제도적 기반을 구축하면서 사업을 효과적으로 장기간 수행해왔던 캐나다 고용 및 사회개발부 'Skills Link'와 우리나라 여성가족부 꿈드림센터의 '두드림' 사업과 비교 분석하여, 향후 우리나라 취약청소년 자립지원을 위한 취업지원 프로그램에 대한 발전방안을 도출해내고자 한다. 연구방법으로는 각 국의 취약청소년 취업지원 프로그램의 사업배경 및 목표, 참여대상 및 선정기준, 사업내용, 지원기간 및 지원 비용, 사업 효과를 중심으로 비교 분석을 실시하였다. 연구결과 첫째, 참여대상 선정과 관련하여 우리나라는 대상이 매우 제한적이며, 둘째, 운영방식과 관련하여 지원 기간 및 비용도 매우 낮은 수준으로 파악되었다. 이를 통한 제언으로는 자립전환기 청소년에 대한 체계적 프로그램을 설계하고 지속적인 지원을 실시해야 하며, 취약청소년의 특성과 상황을 고려한 대상자 선정이 필요하겠다. 또한 사업의 연속성을 확보하고 지원기간의 확대가 필요하며, 자립지원 사업의 성공적 추진을 위해서 청소년의 동기부여와 기업의 참여 유도 방안을 도입해야 할 것이다.

Identification and Organization of Task Complexity Factors Based on a Model Combining Task Design Aspects and Complexity Dimensions

  • Ham, Dong-Han
    • 대한인간공학회지
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    • 제32권1호
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    • pp.59-68
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    • 2013
  • Objective: The purpose of this paper is to introduce a task complexity model combining task design aspects and complexity dimensions and to explain an approach to identifying and organizing task complexity factors based on the model. Background: Task complexity is a critical concept in describing and predicting human performance in complex systems such as nuclear power plants(NPPs). In order to understand the nature of task complexity, task complexity factors need to be identified and organized in a systematic manner. Although several methods have been suggested for identifying and organizing task complexity factors, it is rare to find an analytical approach based on a theoretically sound model. Method: This study regarded a task as a system to be designed. Three levels of design ion, which are functional, behavioral, and structural level of a task, characterize the design aspects of a task. The behavioral aspect is further classified into five cognitive processing activity types(information collection, information analysis, decision and action selection, action implementation, and action feedback). The complexity dimensions describe a task complexity from different perspectives that are size, variety, and order/organization. Combining the design aspects and complexity dimensions of a task, we developed a model from which meaningful task complexity factors can be identified and organized in an analytic way. Results: A model consisting of two facets, each of which is respectively concerned with design aspects and complexity dimensions, were proposed. Additionally, twenty-one task complexity factors were identified and organized based on the model. Conclusion: The model and approach introduced in this paper can be effectively used for examining human performance and human-system interface design issues in NPPs. Application: The model and approach introduced in this paper could be used for several human factors problems, including task allocation and design of information aiding, in NPPs and extended to other types of complex systems such as air traffic control systems as well.

빅데이터 역량 평가를 위한 참조모델 및 수준진단시스템 개발 (An Assessment System for Evaluating Big Data Capability Based on a Reference Model)

  • 천민경;백동현
    • 산업경영시스템학회지
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    • 제39권2호
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    • pp.54-63
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    • 2016
  • As technology has developed and cost for data processing has reduced, big data market has grown bigger. Developed countries such as the United States have constantly invested in big data industry and achieved some remarkable results like improving advertisement effects and getting patents for customer service. Every company aims to achieve long-term survival and profit maximization, but it needs to establish a good strategy, considering current industrial conditions so that it can accomplish its goal in big data industry. However, since domestic big data industry is at its initial stage, local companies lack systematic method to establish competitive strategy. Therefore, this research aims to help local companies diagnose their big data capabilities through a reference model and big data capability assessment system. Big data reference model consists of five maturity levels such as Ad hoc, Repeatable, Defined, Managed and Optimizing and five key dimensions such as Organization, Resources, Infrastructure, People, and Analytics. Big data assessment system is planned based on the reference model's key factors. In the Organization area, there are 4 key diagnosis factors, big data leadership, big data strategy, analytical culture and data governance. In Resource area, there are 3 factors, data management, data integrity and data security/privacy. In Infrastructure area, there are 2 factors, big data platform and data management technology. In People area, there are 3 factors, training, big data skills and business-IT alignment. In Analytics area, there are 2 factors, data analysis and data visualization. These reference model and assessment system would be a useful guideline for local companies.

효율적인 창정비요소개발을 위한 지침 개선적용 연구 (A Study on the Applying Improvement Method of Guide for efficient depot level maintenance)

  • 정인성;김형도
    • 한국산학기술학회논문지
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    • 제20권12호
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    • pp.789-796
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    • 2019
  • 최종의 정비 단계인 창정비 분야 ILS요소개발이 체계적이고 효율적으로 수행되면 무기체계 수명주기 연장으로 장비 가동률이 향상되고, 전투준비태세 유지에 만전을 기할 수 있게 된다. 이와 같은 창정비의 중요성에도 불구하고 창정비 수행을 위한 각 개발 요소별 적용 지침의 부실한 반영으로 인해 무기체계별 개발 기준을 상이하게 적용하고 있으며, 추가 개발비가 발생되는 등의 문제가 발생되고 있다. 이에 따라 체계개발 시의 ILS요소개발 개념과는 상이한 특성을 지닌 창정비 고유의 요소별 개발 개념, 방법, 절차를 명확화 하여 차별화된 관리가 진행될 수 있도록 개발 지침 구체화 적용 방법을 연구하였다. 창정비요소개발의 효율적인 수행을 위해 창정비 주기 결정 단계에서 반드시 고려하여야 할 추가 요소를 제시하였다. 또한 RAM, LSA, ILS 11대 요소를 창정비요소개발에 접목시키기 위한 요소별 개발 개념 해석을 통해 구체적인 적용 방법을 정리 하였다. 이를 기반으로 체계적인 개발 절차를 적용함으로써 적정 개발비 산출이 가능하다. 그리고 개발 제품의 품질 향상과 정비 현장에서의 실용적인 개발 산출물 활용에도 도움을 줄 수 있다.

유연한 단일 링크 로봇의 제어기 설계에 대한 연구 (Study on the PID Controller Design for One-Link Robot)

  • 강신천;박용운;고정호
    • 전자공학회논문지SC
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    • 제44권3호
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    • pp.9-13
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    • 2007
  • 대부분의 공학 시스템은 비선형 시스템이지만 비선형 요소가 어떤 바운드된 섹터 내에서만 존재할 때 이러한 비선형 시스템을 통상 Lure-Postnikov system이라 부르며 기계 시스템에서 자주 직면하게 된다. Lure-Postnikov system을 안정화 시키는 제어기를 해석하는 방법에 대해서는 그동안 상당한 연구가 이루어져 왔지만 PID 혹은 저차 제어기와 같은 고정된 구조를 갖는 제어기의 설계에 대한 연구는 아직 미미한 상태이다. 본 논문에서는 하나의 실수 다항식과 허수 다항식의 패밀리를 Hurwitz 다항식으로 만드는 제어 변수의 조합을 선형 부등식을 통하여 구하는 최근의 연구 결과를 이용하여 Lure-Postnikov system을 안정화 시키는 제어기를 체계적으로 설계하는 새로운 방법을 제시하고자 한다. 이 방법은 무기체계 시스템에서 흔히 쓰이는 유연한 단일 링크를 갖는 로봇 시스템에 적용하여 임의의 차수의 제어기를 체계적으로 설계할 수 있음을 보여준다.