• 제목/요약/키워드: surface active agent

검색결과 94건 처리시간 0.029초

PREPARATION OF ANISOTROPIC CONDUCTIVE FINE PARTICLES BY ELECTROLESS NICKEL PLATING.

  • Fujinami, T.;Watanabe, J.;Motizuki, I.;Honma, H.
    • 한국표면공학회지
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    • 제29권6호
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    • pp.709-713
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    • 1996
  • Mechanical solderless chip packaging with small gold bumps or metal balls has increased in the electronic devices. The preparation of conductive particles (5~7 $\mu\textrm{m}$ diamiter) by electroless nickel plating have been investigated. Generally, batch type electroless plating is applied to provide conductivity on the nonconductors. Since the surface areas of particles are much larger than the bulk substrate, accordingly the electroless plating bath becomes unstable. Thus, we applied the continuous dropping method for the preparation of conductive particles. The uniform coverage of deposited nickel on the particles was obtained by using ammonium acetate as a complexing agent, and surface coverage is further improved without coagulation of particles by the surface active agent treatment before enter the plating bath.

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탈지 유채박 중 표면활성정제물의 유화특성 및 산화 안정도에 관한 연구 (Emulsifying Properties and Oxidative Stability of Purified Surface-Active Substances from Defatted Rapeseed Cake Extract)

  • 김산성;이의석;이기택;홍순택
    • 한국응용과학기술학회지
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    • 제33권1호
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    • pp.155-167
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    • 2016
  • Surface-active substances in defatted rapeseed cake were obtained using a supercritical fluid extraction method. Then, it was purified by removing sinapine in the extract through a series of steps using a mixed solvent: diethyl ether and ethyl acetate (1:1, v/v). Emulsifying properties of purified surface-active substances were investigated, including fat globule size, zeta potentials and creaming stability and its antioxidant activity in emulsion systems were also studied by peroxide value and $^1H$-NMR spectrum. It was found that fat globules in emulsions with purified surface-active substances were much smaller than ones with the unpurified. In addition, as pH of the emulsion lowered and with increasing NaCl concentration in the emulsion, they were observed to increase, which led to worse creaming stability. These properties were reflected in changes of zeta potentials of emulsions. The oxidative stability was better in emulsions with purified surface-active substances than ones with Tween 20 or commercial lecithin, possibly resulted from the existence of sinapic acid in the extract. It was concluded that purified surface-active substances from defatted rapeseed cake could be simultaneously used as emulsifier and antioxidant agent in emulsion system.

분산제 PVA에 따른 수퍼커패시터용 이산화망간전극의 전기 화학적 특성 (Electrochemical Properties of MnO$_2$electrode for supercapactor wish a Diffuser (Polyvinylalcohol))

  • 이상오;김한주;박수길
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2001년도 하계학술대회 논문집
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    • pp.753-756
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    • 2001
  • This research made a study of MnO$_2$electrode for supercapacitor with a diffuser (Polyvinyl alcohol). Manganese dioxide was used as active material. We tried to increase specific surface area by adding PVA. Manganese dioxide was synthesized by a sol-gel method using fumaric acid and oxalic acid in low temperature with high yield. Therefore, We prepared Manganese dioxide powder. This powder was used by active materials. The electrode was made by a mixture of active material, ketjen-black which is a large specific surface area, and PVdF-co-HFP as binder agent with using Nickel mesh as current collector. Here we reported on the synthesis and electrochemical performance of a enhanced material. All active materials have been submitted to X-ray diffraction and Scanning electron microscopy.

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반응성 플라즈마 표면 처리기법을 도입한 새로운 유리섬유 강화 복합재료의 개발 및 물성연구 (New Glass Fiber Reinforced Composite Insulating Material by Reactive Plasma Surface Treatment)

  • 성열문;하흥주;문상룡;조정수;김규섭
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 1994년도 춘계학술대회 논문집
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    • pp.141-143
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    • 1994
  • One of the Principal problems encountered in the use of filer reinforced composites is to establish an active fiber surface to achieve maximum adhesion between resin and fiber surface. Now, we want to develope new process that will overcome the disadvantage of the chemical coupling agent and achieve maximum adhesion at the interface between resin and fiber by active plasma treatment on the glass fiber surface. In this study. we investigated the effect of plasma treatment on the wettability of glans surface .

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고분자 계면활성제에 관한 연구(제6보) -알파 술폰 지방산 음이온성 올리고머 계면활성제의 계면성- (Studies on the Polymeric Surface Active Agent(VI) -The Surface Activities of Anionic Oligomer Surfactant with α-Sulfo Alkanoic Acid-)

  • 정노희;박상석;정환경;조경행;남기대
    • 공업화학
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    • 제4권4호
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    • pp.683-691
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    • 1993
  • Sodium dodecyl polyoxyethylene ${\alpha}$-sulfa alkanoates류 15종에 대하여 표면장력, 기포력 및 그 안정성, 유화력, 분산성, 습윤성 및 가용화능 등의 계면활성을 실험하였다. 이들 시료의 묽은 수용액에 대한 임계미셀농도는 $10^{-4}{\sim}10^{-5}mo1/{\ell}$ 범위였고 그 농도범위에서의 표면장력은 30~47dyne/cm였으며, 일정농도 수용액에 대한 기포력 및 그 안정성, 벤젠 및 대두유에 대한 유화력, 탄산칼슘 및 산화철에 대한 분산성, 그리고 습윤력과 Orange OT에 대한 가용화능을 실험하여 검토한 결과 O/W형 유제 및 분산제로서의 응용성이 기대된다.

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양쪽성 이온 계면활성제의 유도체합성 및 계면성에 관한 연구(제2보);N-알킬 혹은 아실히드록시 술포베타인류의 계면성 (Synthesis and Surface Active Properties of Amphoteric Surfactant Derivatives(II);Surface Active Properties of N-Alkyl or Acyl Hydroxy sulfobetaines)

  • 이진희;하정욱;박홍조;노윤찬;남기대
    • 한국응용과학기술학회지
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    • 제11권1호
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    • pp.79-85
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    • 1994
  • All the activities and physical properties including surface tension' foaming power, foam stability, emulsifying power, dispersion effect of 3-(N, N-dimethyl N-alkylammonio)-2-hydroxyY-1-propane sulfonate (HSB)류와 3-CN-alkylamidopropyl-N,N-dimethylamm-onjo)-2-hydroxy-1-propane sulfonate (APSB) aquous solution were measured and critical micelle concentration was evaluated. Their cmc of hydroxy sulfobetaine derivatives evaluated by the surface tension method was $1.0{\times}10^{-3}{\sim}1.0{\times}10^{-4}$ mol/l, and surface tension of the aquous solution was decreased to $27{\sim}38dyne/cm$. The experimental results for foaming power, foam stability, emulsifying power in liquid paraffin showed a good surface active properties, especially, dispersion effect in ferric oxide exhibited some efficient surface active properties, and then it would be expected to application as detergent and dispersion agent.

Natural Dispersing Agent from Korean Seaweed Extract to Enhance the Safeness and UV Protection Properties of Inorganic Sunscreen Based on TiO2 Nanoparticles

  • Pestaria Sinaga;Sung-Hwan Bae
    • 한국재료학회지
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    • 제34권2호
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    • pp.95-104
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    • 2024
  • Nanoparticles are commonly used to avoid the opaque white color of TiO2 based sunscreen. However, a dispersing agent is typically required because of the tendency of the nanoparticles (NPs) to agglomerate. Stearic acid is one kind of dispersing agent often used for sunscreen products. However, according to the MSDS data sheet on stearic acid, stearic acid is highly hazardous to aquatic life and causes irritation on human skin. To avoid this problem, in this study a safer organic dispersing agent extracted from Korean seaweed has been studied to disperse TiO2 nanoparticles, and further use as an active agent in sunscreen products. The presence of phytochemicals in seaweed extract, especially alginate, can disperse TiO2 nanoparticles and improve TiO2 dispersion properties. Results show that seaweed extract can improve the dispersion properties of TiO2 nanoparticles and sunscreen products. Reducing the agglomeration of TiO2 nanoparticles improves sunscreen properties, by making it less opaque white in color, and increasing UV protection value. It was also confirmed that adding seaweed extract into sunscreen products had no irritating effects on the human skin, making it more desirable for cosmetics application.

가수분해된 인삼사포닌 4급 암모늄엽과 화장품으로의 응용에 관한 연구 (A Study on the Hydrolyzed Ginseng Saponin-Quaternary and its Application in Cosmetics)

  • 김영대;김창규;이정남;하병조
    • Journal of Ginseng Research
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    • 제13권2호
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    • pp.189-197
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    • 1989
  • A new quaternary ammonium compound, hydrolyzed ginseng-saponin quaternary (HGSQ), from Korean ginseng saponin and 2,3-epoxypropyltrimethylammonium chloride has been developed as a conditioning agent in cosmetics. This structure has a hydrophobic group from the aglycone of ginseng saponin which is biologically active and considered to be the most important component of the Korean ginseng. Its properties : surface tension, critical micelle concentration (CMC), eye irritation, sorption onto hair, force reduction(%) and moisture retention effect were studied. Its cationic character allows the molecule to be more substantive than ginseng saponin. HGSQ had good physical properties and was safe. enough as a cosmetic raw material. Also half-head tests of HGSQ-containing shampoo were carried out to compare the conditioning effects in shampoos. HGSQ was an excellent conditioning agent in shampoo..

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천연물질을 활용한 웰빙기법 천연염색에 관한 연구 (2) -소엽염색 면직물의 모나자이트 처리효과- (A Study on the Well-being Technique Natural Dyeing with Natural Resources (2) -Effect of Monazite Treatment on the Cotton Fabric with Natural Dyeing using Perilla frutescens var. acuta -)

  • 김상률
    • 한국의류산업학회지
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    • 제12권2호
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    • pp.240-245
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    • 2010
  • The effects of monazite and fixing agents on cotton fabric dyed with Perilla frutescens var. acuta extract were investigated. The proper monazite treatment concentration, temperature and time were 10%(o.w.b.), $50^{\circ}C$ and 60minutes. By various fixing agent treatment, $FeSO_4$ showed a relatively high K/S value and the order of K/S value decreased as follows, cation surface active agents, soybean and NaCl. And the monazite and $FeSO_4$ fixing agent showed higher anion emissity than those of untreated cotton and other fixing agents. The cotton fabrics showed improved color fastness by monazite and fixing agents treatments with the exception of light fastness. And the cotton fabrics fixed with fixing agents were showed effective bacterial reduction with the exception of NaCl.