• Ocean and Polar Research
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• v.28 no.4
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• pp.395-405
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• 2006

We measured the fugacity of $CO_2$ $(fCO_2)$, temperature, salinity, nutrients and chlorophyll a in the surface water of the western North Pacific $(4^{\circ}30'{\sim}33^{\circ}10'N,\;144^{\circ}20'{\sim}127^{\circ}35'E)$ in September 2002. There were zonally several major currents which have characteristics of specific temperature and salinity (NECC, North Equatorial Counter Current; NEC, North Equatorial Current; Kuroshio etc.). Surface $fCO_2$ distribution was clearly distinguished into two groups, tropical and subtropical areas of which boundary was $20^{\circ}N$. In the tropical Int surface $fCO_2$ was mainly controlled by temperature, while in the subtropical area, surface $fCO_2$ was dependent on total inorganic carbon contents. Air-sea $CO_2$ flux showed a large spatial variation, with a range of $-0.69{\sim}0.79 mmole\;m^{-2}day^{-1}$. In the area of AE (Anticyclonic Eddy), SM(Southern Mixed region) and NM (Northern Mixed region), the ocean acted as a weak source of $CO_2$ $(0.6{\sim}0.79 mmole\; m^{-2}day^{-1})$. In NECC, NEC, Kuroshio and ECS (East China Sea), however, the fluxes were estimated to be $-0.3mmole\; m^{-2}day^{-1})$ for the first three regions and $-1.2mmole\; m^{-2}day^{-1})$ for ECS respectively, indicating that these areas acted as sinks of $CO_2$. The average air-sea flux in the entire study area was $0.15mmole\;m^{-2}day^{-1})$, implying that the western North Pacific was a weak source of $CO_2$ during the study period.

• Journal of Environmental Science International
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• v.20 no.8
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• pp.963-975
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• 2011

For this research, they were monitored $CO_2$ flux and environmental factors ($CO_2$ concentration, soil temperature, soil moisture, soil organic carbon, soil pH, soil Eh) in foreshore, paddy field and woods sites at the winter season (January 2009) and the summer season (September 2009). Seasonal and spatial variations for monitored data were analyzed, and linear regression functions of $CO_2$ flux as environmental factors were estimated. $CO_2$ fluxes averaged between surface and atmosphere monitored in foreshore and paddy field at the winter season were shown $-8\;mgCO_2m^{-2}hr^{-1}$ and $-25\;mgCO_2m^{-2}hr^{-1}$, respectively. $CO_2$ fluxes averaged between surface and atmosphere monitored in foreshore and paddy field at the summer season were shown $47\;mgCO_2m^{-2}hr^{-1}$ and $117\;mgCO_2m^{-2}hr^{-1}$, respectively. Thus, $CO_2$ was sunk from atmosphere to surface at the winter season and it was emitted from surface to atmosphere at the summer season. $CO_2$ fluxes in woods site were emitted $145\;mgCO_2m^{-2}hr^{-1}$ at the winter season and $279\;mgCO_2m^{-2}hr^{-1}$ at the summer season.

• Ocean and Polar Research
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• v.26 no.2
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• pp.145-154
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• 2004

Surface energy and $CO_2$ fluxes have been measured over an ocean at Ieodo Ocean Research Station of KORDI since May 2003. Eddy covariance technique, which is a direct flux measurement, is used to quantitatively understand the interaction between the ocean surface and the atmospheric boundary layer. Although fluxes were continuously measured during the period from May 2003 to February 2004, the quality control of these data yielded <20% of data retrieval. The atmospheric stability did not show any distinct dirunal patterns and remained near-neutral to stable from May to June but mostly unstable during fall and winter in 2003. Sensible heat flux showed a good correlation with the difference between the sea water temperature and the air temperature. The maximum fluxes of sensible heat and latent heat were $120Wm^{-2}$ and $350Wm^{-2}$ respectively, with an averaged Bowen ratio of 0.2. The ocean around the tower absorbed $CO_2$ from the atmosphere and the uptake rates showed seasonal variations. Based our preliminary results, the daytime $CO_2$ flux was steady with an average of $-0.1 mgCO_2m^{-2}s^{-1}$ in summer and increased in winter. The nighttime $CO_2$ uptake was greater and fluctuating, reaching up to $-0.1 mgCO_2m^{-2}s^{-1}$ but these data require further examination due to weak turbulent mixing at nighttime. The magnitude of $CO_2$ flux was positively correlated with the half hourly changes in horizontal mean wind speed. Due to the paucity of quality data, further data collection is needed for more detailed analyses and interpretation.

• Ocean and Polar Research
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• v.30 no.3
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• pp.335-345
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• 2008

In order to study spatial variabilities and major controlling factors, we measured fugacity of $CO_2(fCO_2)$, temperature, salinity and nutrients in surface waters of the North Pacific($7^{\circ}30'{\sim}33^{\circ}15'N$, $123^{\circ}56'E{\sim}164^{\circ}24'W$) between September$\sim$October 2007. The North Pacific and the marginal sea were distinguished by $fCO_2$ distribution as well as unique characteristics of temperature and salinity. There was a distinct diurnal SST variation in the tropical North Pacific area, and surface $fCO_2$ coincidently showed diurnal variation. In the North Pacific area, surface $fCO_2$ was mainly controlled by temperature, while in the marginal sea area it was primarily dependent on alkalinity and dissolved inorganic carbon concentrations. Air-sea $CO_2$ flux showed a large spatial variation, with a range of $-6.10{\sim}5.06\;mmol\;m^{-2}day^{-1}$. The center of subtropical gyre of North Pacific acted as a source of $CO_2(3.09{\pm}0.95\;mmol\;m^{-2}day^{-1})$. Tropical western North Pacific (i.e. the 'warm pool' area and the subtropical western North Pacific) acted as weak sources of $CO_2$($1.07{\pm}1.20\;mmol\;m^{-2}day^{-1}$ and $0.50{\pm}0.53\;mmol\;m^{-2}day^{-1}$, respectively). In the marginal sea, however, the flux was estimated to be $-0.68{\pm}1.17\;mmol\;m^{-2}day^{-1}$, indicating that this area acted as a sink for $CO_2$.

• Atmosphere
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• v.22 no.4
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• pp.415-427
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• 2012

$CO_2$ is the most important trace gas related to climate change. Therefore, understanding surface carbon sources and sinks is important when seeking to estimate the impact of $CO_2$ on the environment and climate. CarbonTracker, developed by NOAA, is an inverse modeling system that estimates surface carbon fluxes using an ensemble Kalman filter with atmospheric $CO_2$ measurements as a constraint. In this study, to investigate the capability of CarbonTracker as an analysis tool for estimating surface carbon fluxes in Asia, an experiment with a nesting domain centered in Asia is performed. In general, the results show that setting a nesting domain centered in Asia region enables detailed estimations of surface carbon fluxes in Asia. From a rank histogram, the prior ensemble spread verified at observational sites located in Asia is well represented with a relatively flat rank histogram. The posterior flux in the Eurasian Boreal and Eurasian Temperate regions is well analyzed with proper seasonal cycles and amplitudes. On the other hand, in tropical regions of Asia, the posterior flux does not differ greatly from the prior flux due to fewer $CO_2$ observations. The root mean square error of the model $CO_2$ calculated by the posterior flux is less than the model $CO_2$ calculated by the prior flux, implying that CarbonTracker based on the ensemble Kalman filter works appropriately for the Asia region.

• Journal of Welding and Joining
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• v.3 no.1
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• pp.40-45
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• 1985

Wire meling characteristics were examined with variation of gas formers such as $MgCO_3, CaCO_3 and Li_ 2CO_ 3$ by self-shielded flux cored arc welding. The flux cored wire of overlap type was welded by DCRP. The results obtainedareas follows. 1) Drop type was observed with no gas former, repelled type with MgCO_3$ added and short circuit type with $Li_2CO_3$ added. The variation of transfer mode was related to the blowing force of $CO_2$ gas and the surface tension of the slag. 2) Droplet size increased with adding gas formers due to the effect of $CO_2$ gas cushion. 3) Core spikes were observed more frequently with increasing the amount of gas formers.

• Journal of Electrochemical Science and Technology
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• v.9 no.3
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• pp.212-219
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• 2018

Perovskite type ceramic membranes which exhibit dual ion conduction (proton and oxygen ion conduction) can permeate water and can aid solving operational problems such as temperature gradient and carbon deposition associated with a working solid oxide fuel cell. From this point of view, it is crucial to reveal water transport mechanism and especially the nature of the surface sites that is necessary for water incorporation and evolution. $BaCe_{0.8}Y_{0.2}O_{3-{\alpha}}$ (BCY20) was used as a model proton and oxygen ion conducting membrane in this work. Four different catalytically modified membrane configurations were used for the investigations and water flux was measured as a function of temperature. In addition, CO was introduced to the permeate side in order to test the stability of membrane against water and $CO/CO_2$ and post operation analysis of used membranes were carried out. The results revealed that water incorporation occurs on any exposed electrolyte surface. However, the magnitude of water permeation changes depending on which membrane surface is catalytically modified. The platinum increases the water flux on the feed side whilst it decreases the flux on the permeate side. Water flux measurements suggest that platinum can block water permeation on the permeate side by reducing the access to the lattice oxygen in the surface layer.

• Proceedings of the KSRS Conference
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• 1999.11a
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• pp.237-242
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• 1999

As one of the key parameters to determine $CO_2$ flux between air - sea interface, it is quite important to know p$CO_2$, which has involved much uncertainty, mainly due to the complex variations of sea surface p$CO_2$ and the paucity of samples, made in ocean. In order to improve the interrelationship between partial pressure (p$CO_2$) and different physical and biochemical parameters in global sea surface water, a new empirical relation is established to correlate and parameterize p$CO_2$ in the mixed layer using the data from recent WOCE cruises. Meanwhile, by new empirical relation, abundant historical hydrographic and nutrients ship data, Levitus data set and NOAA/AVHRR(SST), p$CO_2$ have been accumulated and applied. Then effort has to be made fur promotion of this study to correlate and parameterize p$CO_2$ in the mixed Layer with different physical and biochemical parameters. and further attribute this huge historical data sets and NOAA/AVHRR(SST) data to estimate p$CO_2$. In this paper we analyzed more interrelationship between the model and ship/satellite data set. Finally, the inter-annual variations of p$CO_2$ in sea are presented and discussed.

• Atmosphere
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• v.28 no.2
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• pp.113-121
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• 2018

In order to monitor greenhouse gases including $CO_2$, various types of surface-, aircraft-, and satellite-based measurement projects have been conducted. These data help understand the variations of greenhouse gases and are used in atmospheric inverse modeling systems to simulate surface fluxes for greenhouse gases. CarbonTracker is a system for estimating surface $CO_2$ flux, using an atmospheric inverse modeling method, based on only surface observation data. Because of the insufficient surface observation data available for accurate estimation of the surface $CO_2$ flux, additional observations would be required. In this study, a system that assimilates aircraft $CO_2$ measurement data in CarbonTracker (CT2013B) is developed, and the estimated results from this data assimilation system are evaluated. The aircraft $CO_2$ measurement data used are obtained from the Comprehensive Observation Network for Trace gases by the Airliner (CONTRAIL) project. The developed system includes the preprocessor of the raw observation data, the observation operator, and the ensemble Kalman filter (EnKF) data assimilation process. After preprocessing the raw data, the modeled value corresponding spatially and temporally to each observation is calculated using the observation operator. These modeled values and observations are then averaged in space and time, and used in the EnKF data assimilation process. The modeled values are much closer to the observations and show smaller biases and root-mean-square errors, after the assimilation of the aircraft $CO_2$ measurement data. This system could also be used to assimilate other aircraft $CO_2$ measurement data in CarbonTracker.

• Proceedings of The Korean Society of Agricultural and Forest Meteorology Conference
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• 2003.09a
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• pp.115-128
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• 2003

o What is the flux \ulcorner Flux is the transfer of a quantity per unit area per unit time. The quantities are mass, heat, moisture, momentum and pollutant in micrometeorology. Kinematic flux (Fluid). The reduction in wind speed due to frictional drag transfers momentum from the atmosphere to the surface, creating turbulence that mixes the air and transports heat and water from the surface into the lower atmosphere. (omitted)