• Title/Summary/Keyword: specific charge

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Pretreatment of SiO/C Composite Anode of Lithium ion Secondary Battery for High coulombic Efficiency and High Specific Capacity (리튬이차전지용 산화실리콘-흑연 복합체 고효율 음극의 전처리 특성)

  • Shin, Hye-Min;Veluchamy, Angathevar;Kim, Dong-Hun;Chung, Young-Dong;Kim, Hyo-Seok;Doh, Chil-Hoon;Jin, Bong-Soo;Kim, Hyun-Soo;Moon, Seong-In;Kim, Ki-Won;Oh, Dae-Hui
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2007.11a
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    • pp.43-44
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    • 2007
  • SiO and graphite composite has been prepared by adopting high energy ball milling technique. The anode material shows high initial discharge and charge capacity values of 1138 and 568 mAh/g, respectively. Since the materials formed during initial discharge process the nano silicon/$Li_4SiO_3\;and\;Li_2O$ remains as interdependent, it may be expected that the composite exhibiting higher amount of irreversible capacity$(Li_2O)$ will deliver higher reversible capacity. In this study, pretreatment method of constant current-constant voltage (CC-CV) Provided high coulombic efficiency of SiO/C composite electrode removing the greater part of irreversible capacity.

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Active Materials for Energy Conversion and Storage Applications of ALD

  • Sin, Hyeon-Jeong
    • Proceedings of the Korean Vacuum Society Conference
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    • 2013.08a
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    • pp.75.2-75.2
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    • 2013
  • Atomic layer deposition (ALD), utilizing self-limiting surface reactions, could offer promising perspectives for future efficient energy conversion devices. The capabilities of ALD for surface/interface modification and construction of novel architectures with sub-nanometer precision and exceptional conformality over high aspect ratio make it more valuable than any other deposition methods in nanoscale science and technology. In the context, a variety of researches on fabrication of active materials for energy conversion applications by ALD are emerging. Among those materials, one-dimensional nanotubular titanium dioxide, providing not only high specific surface area but also efficient carrier transport pathway, is a class of the most intensively explored materials for energy conversion systems, such as photovoltaic cells and photo/electrochemical devices. The monodisperse, stoichiometric, anatase, TiO2 nanotubes with smooth surface morphology and controlled wall thickness were fabricated via low-temperature template-directed ALD followed by subsequent annealing. The ALD-grown, anatase, TiO2 nanotubes in alumina template show unusual crystal growth behavior which allows to form remarkably large grains along axial direction over certain wall thickness. We also fabricated dye-sensitized solar cells (DSCs) introducing our anatase TiO2 nanotubes as photoanodes, and studied the effect of blocking layer, TiO2 thin films formed by ALD, on overall device efficiency. The photon convertsion efficiency ~7% were measured for our TiO2 nanotubebased DSCs with blocking layers, which is ~1% higher than ones without blocking layer. We also performed open circuit voltage decay measurement to estimate recombination rate in our cells, which is 3 times longer than conventional nanoparticulate photoanodes. The high efficiency of our ALD-grown, anatase, TiO2 nanotube-based DSCs may be attributed to both enhanced charge transport property of our TiO2 nanotubes photoanode and the suppression of recombination at the interface between transparent conducting electrode and iodine electrolytes by blocking layer.

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A Study on the Property of Combustion tower Dust in EAF Process (전기로 연소탑 하단에 포집되는 분진의 특성 연구)

  • Kim, Young-Hwan;Yoo, Jung-Min
    • Resources Recycling
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    • v.26 no.5
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    • pp.48-53
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    • 2017
  • During steelmaking on EAF, 1 ~ 2% of dust is generated. EAF Dust contains 20 ~ 30% of Zn and Fe. Dust contained in Off-gas is passed through combustion tower and cooling tower, and then captured in bag filter. About 15 wt.% of dust is dropped at the bottom of Combustion tower by its specific gravity, which was also carried out to recycle company with more higher charge than Bag filter dust. This study is focused on the combustion tower dust, and seperation as a function of operation period and particle size. As a result, Zn and Fe content of dust is more affected by size factor than operation period.

The Study about analyzing the Present Situation of Human Resource Outsourcing (인적자원 아웃소싱의 현황분석에 관한 연구)

  • Cha, Sung-Ho;Yang, Dong-Hoon
    • Journal of the Korea Society of Computer and Information
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    • v.13 no.5
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    • pp.279-289
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    • 2008
  • This study has the primary purpose to understanding the present situation through research on the actual condition about human resource outsourcing in the stocks and KOSDAQ enterprises, and would give the basic and useful data to develop human resource outsourcing. Data were collected from 1,500 charge of human resource management in the stocks and KOSDAQ enterprises which introduced or will be introduced human resource outsourcing. Frequencies, cross-tabs and independent-samples t-test were used to understanding the actual condition. Research findings are summarized as follows. First, as the introduction area of human resource outsourcing following training and development on the list were personnel information system, recruitment and selection. Second, tasks that transfer outsourcing supply firms owing to human resource outsourcing were common and typical operation function than complex and specific planning function.

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The effect of iron oxide ballasted flocculant on the activated sludge settleability and dewaterability (산화철계 가중응집제가 활성슬러지의 침전성 및 탈수성에 미치는 영향)

  • Yang, Hyeji;Kim, Yongbum;Choi, Younggyun
    • Journal of Korean Society of Water and Wastewater
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    • v.35 no.4
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    • pp.277-284
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    • 2021
  • The ballasted flocculation effects of the mill scale and magnetite on activated sludge were investigated. Both ballasted flocculants (BF) could remarkably improve the sludge settleability in terms of zone settling velocity (ZSV) and sludge volume index (SVI). With the BF dosage of 0.2 to 2.0 g-BF/g-SS, the magnetite particles showed better efficiency on improving settling behavior of activated sludge than the mill scale due to higher surface area and hydrophobic property. The efficiency of SVI30 with magnetite injection was 2.5 to 11.3% higher than mill scale injection and that of the ZSV appreciated from 23.7% to 44.4% for magnetite injection. Averaged floc size of the BF sludge with magnetite dosage (0.5 g-BF/g-SS) was 2.3 times higher than that of the control sludge. Dewaterability of the sludge was also greatly improved by addition of the BF. The specific resistance to filtration (SRF) was reduced exponentially with increasing the dosage of BF. However, the BF's particle size effect on the SRF looks to be marginal. Consequently, for improving the dewaterability, the BF played a physical role to remove the pore water of the biological flocs by intrusive attachment and a chemical role to induce aggregation of the flocs by charge neutralization.

Perceptions of Sign Language Interpreters, Deaf Interpreters and Deaf on Operation of Sign Language Interpreter Qualification System (수어통역사 자격제도 운영에 대한 수어통역사, 청각장애인통역사, 농인의 인식)

  • Lee, Jun-Woo;Hwang, Joon-Ho
    • The Journal of the Korea Contents Association
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    • v.21 no.9
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    • pp.543-556
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    • 2021
  • The purpose of this study is to examine possible improvements of operation of sign language interpreter qualification system through looking into specific perceptions of sign language interpreters and Deaf sign language interpreters in the field and Deaf people who use interpretation service on current sign language interpreter qualification system through focus group interview. As a result of the thematic analysis, three high-level categories were derived for each group, and as a result of recombining them, 'change to a qualification system in which sign language interpreting competency and expertise can be recognized' and 'improvement to a qualification system based on Korean Sign Language and Deaf culture' been sorted out. Based on the above research results, 'establishment of a permanent institution in charge of management and operation of sign language interpreter qualification tests', 'reorganization into a qualification system that reflects the professionalism, level and experience of sign language interpreters', 'all test questions and exam procedures are conducted mainly in sign language', 'a system in which the Deaf take the lead', and 'enactment of a code of ethics for sign language interpreters and Deaf interpreters' were suggested.

Preparation of Bi/Bi2MoO6 Plasmonic Photocatalyst with High Photocatalytic Activity Under Visible Light Irradiation

  • Zou, Chentao;Yang, Zhiyuan;Liang, Mengjun;He, Yunpeng;Yang, Yun;Yang, Shuijin
    • Nano
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    • v.13 no.11
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    • pp.1850127.1-1850127.13
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    • 2018
  • Bi metal deposited on $Bi_2MoO_6$ composite photocatalysts have been successfully synthesized via a simple reduction method at room temperature with using $NaBH_4$ as the reducing agent. The photocatalytic activity of the composite was evaluated by degradation of rhodamine B (RhB) and bisphenol A (BPA) solution under visible light. The rate constant of $Bi/Bi_2MoO_6$ composite to RhB is 10.8 times that of $Bi_2MoO_6$, and the degradation rate constant of BPA is 6.9 times of that of $Bi_2MoO_6$. Nitrogen absorption-desorption isotherm proved that the increase of specific surface area is one of the reasons for the improvement of photocatalytic degradation activity of $Bi/Bi_2MoO_6$ composites. The higher charge transfer efficiency of $Bi/Bi_2MoO_6$ is found through the characterization of the photocurrent and impedance, which are attributed to the surface plasmon resonance (SPR) effect produced by the introduction of the metal Bi monomer in the composite. Free radical capture experiments proved that cavitation is the main active species. Based on the above conclusions, a possible mechanism of photocatalytic degradation is proposed.

Controlled Synthesis of FeSe2 Nanoflakes Toward Advanced Sodium Storage Behavior Integrated with Ether-Based Electrolyte

  • Chen, Yalan;Zhang, Jingtong;Liu, Haijun;Wang, Zhaojie
    • Nano
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    • v.13 no.12
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    • pp.1850141.1-1850141.11
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    • 2018
  • Sodium ion batteries based on the more sodium source reserve than that of lithium have been designed as promising alternatives to lithium ion batteries. However, several problems including unsatisfied specific capacity and serious cyclic stability must be solved before the reality. One of the effective approaches to solve the abovementioned problems is to search for suitable anode materials. In this work, we designed and prepared $FeSe_2$ nanoflakes via a simple hydrothermal method which can be adjusted in composition by Fe precursor. As a potential anode for sodium storage, the optimized $FeSe_2$ electrode was further evaluated in different electrolytes of $NaClO_4$ in propylene carbonate/fluoroethylene carbonate and $NaCF_3SO_3$ in diethylene glycol dimethyl ether. The capacity was about $470mAh\;g^{-1}$ and $535mAh\;g^{-1}$ at $0.5A\;g^{-1}$, respectively, in the voltage between 0.5 V and 2.9 V in the cycle of stabilization phase. Superior performance both in capacity and in stability was obtained in ether-based electrolyte, which affords the property without plugging the intermediates of transition metal dichalcogenides during charge/discharge processes.

Design and 3D-printing of titanium bone implants: brief review of approach and clinical cases

  • Popov Jr, Vladimir V.;Muller-Kamskii, Gary;Kovalevsky, Aleksey;Dzhenzhera, Georgy;Strokin, Evgeny;Kolomiets, Anastasia;Ramon, Jean
    • Biomedical Engineering Letters
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    • v.8 no.4
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    • pp.337-344
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    • 2018
  • Additive manufacturing (AM) is an alternative metal fabrication technology. The outstanding advantage of AM (3D-printing, direct manufacturing), is the ability to form shapes that cannot be formed with any other traditional technology. 3D-printing began as a new method of prototyping in plastics. Nowadays, AM in metals allows to realize not only net-shape geometry, but also high fatigue strength and corrosion resistant parts. This success of AM in metals enables new applications of the technology in important fields, such as production of medical implants. The 3D-printing of medical implants is an extremely rapidly developing application. The success of this development lies in the fact that patient-specific implants can promote patient recovery, as often it is the only alternative to amputation. The production of AM implants provides a relatively fast and effective solution for complex surgical cases. However, there are still numerous challenging open issues in medical 3D-printing. The goal of the current research review is to explain the whole technological and design chain of bio-medical bone implant production from the computed tomography that is performed by the surgeon, to conversion to a computer aided drawing file, to production of implants, including the necessary post-processing procedures and certification. The current work presents examples that were produced by joint work of Polygon Medical Engineering, Russia and by TechMed, the AM Center of Israel Institute of Metals. Polygon provided 3D-planning and 3D-modelling specifically for the implants production. TechMed were in charge of the optimization of models and they manufactured the implants by Electron-Beam Melting ($EBM^{(R)}$), using an Arcam $EBM^{(R)}$ A2X machine.

Electrochemical Properties of Natural Graphite coated with PFO-based Pitch for Lithium-ion Battery Anode (리튬이차전지 음극용 석유계 피치로 코팅된 천연 흑연의 전기화학적 특성)

  • Kim, Geun Joong;Jo, Yoon Ji;Lee, Jong Dae
    • Korean Chemical Engineering Research
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    • v.57 no.5
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    • pp.672-678
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    • 2019
  • The electrochemical properties of pitch-coated natural graphite(NG) were investigated as an anode for lithium-ion batteries. The anode materials were prepared by heat-treatment of mixture of NG and petroleum pitch at $1000^{\circ}C$. The pitches with various softening points were used as carbon precursor. The physical properties of anode materials were analyzed by TGA, SEM, PSA and BET. As the softening point increased, the thickness of the coating layer increased and the specific surface area decreased. The electrochemical performances were investigated by initial charge/discharge efficiency, cycle stability, cyclic voltammetry, rate performance and electrochemical impedance spectroscopy. The carbon-coated NG using pitch with softening points of $250^{\circ}C$ showed an initial discharge capacity of 361 mAh/g and a coulombic efficiency of 92.6%. Also, the rate performance(5 C/0.2 C) was 1.6 times higher than that of NG, and it had a capacity retention (90%) after 50 cycles at 0.5 C.