• Journal of the Korean Chemical Society
• /
• v.21 no.1
• /
• pp.3-15
• /
• 1977

Crystals of salicylaldehyde-4-morpholinothiosemicarbazone, $C_{12}H_{15}O_2N_3S$, are orthorhombic with space group Pna21. Unit-cell dimensions are a = 11.85(5), b = 15.45(5) c = 7.18(3)${\AA}$ with z = 4. Three-dimensional intensity data were collected from the multiple-film equi-inclination Weissenberg photographs taken with $CuK{\alpha}$ radiation. The intensities were estimated visually. The structure was solved by Patterson and Fourier methods and refined by the block-diagonal least-squares methods until the final R value becomes 0.11 for the 1064 observed independent reflections. The morpholine ring has a chair form. The rest atoms of salicylaldehyde-4-morpholinothiosemicarbazone molecule excluding morpholine ring and sulfur atom approximately lie on a plane. The hydroxyl group of the salicylaldehyde and the nitrogen atom of the thiosemicarbazone form an intramolecular hydrogen bond, $O-H{\cdot}{\cdot}{\cdot}N$, of 2.67${\AA}$. The short intermolecular distances all appear to be normal van der Waals contacts.

• Bulletin of the Korean Chemical Society
• /
• v.27 no.11
• /
• pp.1747-1751
• /
• 2006

The dinuclear tetraazadiphenol macrocyclic nickel(II) complexes [$Ni_2$([20]-DCHDC)]$Cl_2$ (I), [$Ni_2$([20]-DCHDC)]$(ClO_4)_2{\cdot}2CH_3CN $ (II(b)) and [$Ni_2$([20]-DCHDC)$(NCS)_2$] (III) {$H_2$[20]-DCHDC = 14,29-dimethyl-3,10,18,25-tetraazapentacyclo-[25,3,1,$0^{4,9}$,$1^{12,16}$,$0^{19,24}$]ditriacontane-2,10,12,14,16(32),17,27(31), 28,30-decane-31,32-diol} have been synthesized by self-assembly and characterized by elemental analyses, conductances, FT-IR and FAB-MS spectra, and single crystal X-ray diffraction. The crystal structure of II(b) is determined. It crystallizes in the monoclinic space group P2(1)/c. The coordination geometries around Ni(II) ions in I and II(b) are identical and square planes. In complex III each Ni(II) ion is coordinated to $N_2O_2$ plane from the macrocycle and N atoms of NCS- ions occupying the axial positions, forming a square pyramidal geometry. The nonbonded Ni…Ni intermetallic separation in the complex II(b) is 2.8078(10) $\AA$. The FAB mass spectra of I, II and III display major fragments at m/z 635.1, 699.4 and 662.4 corresponding to [$Ni_2$([20]-DCHDC)(Cl + 2H)]$^+$, [$Ni_2$([20]-DCHDC)$(ClO_4\;+\;2H)]^+$ and [$Ni_2$([20]-DCHDC)(NCS) + 6H]$^+$, respectively.

• Plant Journal
• /
• v.12 no.3
• /
• pp.24-31
• /
• 2016

Wind-induced vibration is a phenomenon that a struture is oscillated due to wind force such as buffeting, vortex shedding wake and etc., which is one of important characteristics to be considered for design in case that stack has significant slenderness ratio or low natural frequency. International design standards of stack define several criteria for evaluating the suitability of stack design, which describe the required design considerations for each range of design parameters and provide the instruction to verify the stack design against wind-induced vibration simply. However, there is a limitation that they cannot provide quantitative information in case code requirement cannot be satisfied due to constraints of plant space or economical design. In order to overcome the limiation of code, integrated numerical analysis of computational fluid dynamics, harmonic analysis and finite element analysis were proposed to investigate wind-induced vibration for multiple stacks in actual plant. Simulated results of mutual wake interference effect between adjacent stacks were evaluated and compared to the criteria in international standards.

• Journal of the Society of Naval Architects of Korea
• /
• v.48 no.6
• /
• pp.569-574
• /
• 2011

In research vessels or naval ships, airborne noise from machineries such as diesel engine is the major source of underwater noise at low speed. In this paper, effect of engine noise on underwater noise is studied by considering two paths; sound radiation from hull plate and direct airborne noise transmission through hull plate. SEA (Statistical energy analysis) is used to predict hull plate vibration induced by engine noise, where SEA model consists of only two subsystems; engine room air space and hull plate. The pressure level in water is calculated from sound radiation by plate. Engine noise transmission through hull plate is obtained by assuming plane wave propagation in air-limp plate-water system. Two effects are combined and compared to the measurement, where speaker is used as a source in engine room and sound pressure levels in engine room and water are measured. The hydrophone is located 1 m away from the hull plate. It is found below 1000 Hz, prediction overestimates underwater sound pressure level by 5 to 12 dB.

• Journal of Korea Water Resources Association
• /
• v.35 no.2
• /
• pp.203-212
• /
• 2002

The purpose of this study was to examine the effect of vegetation on the flood plain in the Taewha river on the changes of flood level using a hydraulic physical model experiment. To simulate 9.0 km river, 1/300 horizontally and 1/72 vertically distorted model was used. The vegetation areas were divided by three sub -areas and the flood level changes were examined according to the locations of vegetation as well as the transverse Profile. As a result, the flood level changes were not significantly affected by the densely distributed vegetation. It was concluded that additional adjustable vegetation in urban river could make useful hydrophilic space.

• Journal of the Korean earth science society
• /
• v.30 no.4
• /
• pp.485-494
• /
• 2009

We report patterns of astronomical seeing at KSA SEMO (Korea Science Academy Space Earth and Man Observatory). Though the data of the seeing measured at the local observatory is essential in identifying the seeing of the observatory, systematic measurement of seeing has not been made in Pusan yet. For this reason, KSA SEMO adopted the Santa Barbara Instrument Group (SBIG) Seeing Monitor to constantly record the seeing. The seeing monitoring was done through an elaborate procedure involving direct CCD images in the focal plane which were subsequently analyzed for the full width at half maximum (FWHM) Gaussian widths. Based on the seeing monitoring for 8 months, we classified five patterns of the seeing at KSA SEMO: 'Sunset/Sunrise Effect', 'Extreme Fluctuation', 'Sudden Increment', 'Daily Variation' and 'Stable Condition'. Seeing was generally good from 1:00 am to 3:00 am than other times, and it was also better in Winter than in Summer.

• International Journal of Fluid Machinery and Systems
• /
• v.3 no.4
• /
• pp.315-323
• /
• 2010

This work investigates the influence of water compressibility on pressure pulsations induced by rotor-stator interaction (RSI) in hydraulic machinery, using the commercial CFD solver ANSYS-CFX. A pipe flow example with harmonic velocity excitation at the inlet plane is simulated using different grid densities and time step sizes. Results are compared with a validated code for hydraulic networks (SIMSEN). Subsequently, the solution procedure is applied to a simplified 2.5-dimensional pump-turbine configuration in prototype with different speeds of sound as well as in model scale with an adapted speed of sound. Pressure fluctuations are compared with numerical and experimental data based on prototype scale. The good agreement indicates that the scaling of acoustic effects with an adapted speed of sound works well. With respect to pressure fluctuation amplitudes along the centerline of runner channels, incompressible solutions exhibit a linear decrease while compressible solutions exhibit sinusoidal distributions with maximum values at half the channel length, coinciding with analytical solutions of one-dimensional acoustics. Furthermore, in compressible simulation the amplification of pressure fluctuations is observed from the inlet of stay vane channels to the spiral case wall. Finally, the procedure is applied to a three-dimensional pump configuration in model scale with adapted speed of sound. Normalized Pressure fluctuations are compared with results from prototype measurements. Compared to incompressible computations, compressible simulations provide similar pressure fluctuations in vaneless space, but pressure fluctuations in spiral case and penstock may be much higher.

• Journal of the Institute of Convergence Signal Processing
• /
• v.15 no.1
• /
• pp.9-14
• /
• 2014

The path loss data was re-calculated according to the distance between the base station and a mobile station in the mobile telecommunications network. In this paper, the averaged path loss data was plotted with the conventional path loss models(free space, plane earth, Hata model ${\ldots}$). The standard deviations for the 2 Km, 1 Km, 0.5 Km-interval averaged path loss were 2.29 dB, 3.39 dB, 4.75 dB, respectively. Additionally, the derivative values for the 2 Km, 1 Km, 0.5 Km-interval averaged path loss were evaluated to find the positions with more than 1 times or 2times of the standard deviation. The situations with the sharply fluctuated path loss were calculated to 5 positions in the 2 Km interval, to 7 positions in the 1 Km interval, to 19 positions in the 0.5 Km interval, respectively. And, the exact distances between the base station and a mobile station were found with the sharply fluctuated path loss.

• Journal of Elementary Mathematics Education in Korea
• /
• v.21 no.1
• /
• pp.161-194
• /
• 2017

The aim of this study is to look into sub-factors of spatial sense that can be contained in spatial sense of solid figure of mathematics curriculum and offer suggestions to improve teaching spatial sense of solid figures in the future. In order to attain these purposes, this study examined the meaning and sub-factors of spatial sense and the relations between spatial sense of solid figure and sub-factors of spatial sense through a theoretical consideration regarding various studies on spatial sense. Based on such examination, this study compared and analyzed textbooks used in South Korea, Finland and the Netherlands with respect to contents of mathematics curriculum and textbooks in grades, sub-factors of spatial sense, and realistic contexts for spatial sense of solid figure. In the light of such theoretical consideration and analytical results, this study provided suggestions for improving teaching spatial sense of solid figures in elementary schools in Korea as follows: extending contents regarding spatial sense of solid figures in mathematics curriculum and considering continuity between grades in textbooks, emphasizing spatial orientation as well as spatial visualization, underlining not only construction with blocks but also mental activities in mental rotation and mental transformation, comparing strength and weakness of diverse plane representations of three dimensional objects, and utilizing various realistic situations and objects in space.

• Journal of the Society of Disaster Information
• /
• v.13 no.4
• /
• pp.537-549
• /
• 2017

Wooden houses are classified into Traditional, Modern, Platform, Timber framing types. The most popular type is Platform framing which is come from foreign culture. The foreign and Korean tree structure tend to be incompatible with Korean culture and don't fit well with modern lifestyle. In this study, it will analyze the design characteristics of the traditional and modern wooden house to solve these problems. The design characteristics will be contributed to the development of wooden architecture which is suitable for Korean architectural style and lifestyle The research consists of space analysis, plane analysis, structural system analysis, roof type analysis, and aesthetic analysis. From the analytical results the design characteristics of traditional Hanok and modern wood structure, we propose the modular elements and the inner and outer shapes of the Korean - style wooden house.