• Title/Summary/Keyword: solid wood

검색결과 229건 처리시간 0.16초

Crystallinity of Low Molar Ratio Urea-Formaldehyde Resins Modified with Cellulose Nanomaterials

  • PARK, Seongsu;PARK, Byung-Dae
    • Journal of the Korean Wood Science and Technology
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    • 제49권2호
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    • pp.169-180
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    • 2021
  • Inherent crystalline domains present in low formaldehyde to urea (F/U) molar ratio urea-formaldehyde (UF) resins are responsible for their poor adhesion in wood-based composite panels. To modify the crystallinity of low molar ratio (LMR) UF resins, this study investigates the additional effect of cellulose nanomaterials (CNMs), such as cellulose microfibrils (CMFs), cellulose nanofibrils (CNFs), and TEMPO-oxidized CNFs (TEMPO-CNFs) on the crystallinity of modified LMR UF resins. First, two modification methods (post-mixing and in situ) were compared for modified LMR UF resins with TEMPO-CNFs. The modified UF resins with TEMPO-CNFs decreased the nonvolatile solid contents, while increasing the viscosity and gel time. However, the in situ modification of UF resins with TEMPO-CNFs showed lower crystallinity than that of post-mixing. Then, the in situ method was compared for all CNMs to modify LMR UF resins. The modified UF resins with CMFs using the in situ method increased nonvolatile solid contents and viscosity but decreased the gel time. The crystallinity of UF resins modified with TEMPO-CNFs was the lowest even though the crystalline domains were not significantly changed for all modified UF resins. These results suggest that these CNMs should be modified to prevent the formation of crystalline domains in LMR UF resins.

Evaluation of Growth and Wood Traits in E. camaldulensis and Interspecific Eucalypt Hybrid Clones Raised at Three Diverse Sites in Southern India

  • Rathinam Kamalakannan;Suraj Poreyana Ganapathy;Shri Ram Shukla;Mohan Varghese;Chandramana Easwaran Namboothiri Jayasree
    • Journal of Forest and Environmental Science
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    • 제39권1호
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    • pp.27-39
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    • 2023
  • Twenty-five Eucalyptus clones (14 E. camaldulensis - EC and 11 interspecific eucalypt hybrid clones - EH) grown in three contrasting sites were evaluated for the growth and few wood traits at 4 years of age. The stability, genotype-site interaction and suitability of these clones for pulp and solid wood industry sectors were studied. Growth of eucalypt clones was significantly higher at site 1 with higher rainfall, but wood density did not differ significantly from lower rainfall sites. Kraft pulp yield (KPY) decreased from sites 1 to 3 based on moisture availability, but not between two groups of clones. Volumetric shrinkage (VS) was significantly higher in EC clones at site 3 with lowest rainfall, but there was no specific trend at other two sites with maximum (site 1) and intermediate (site 2) rainfall. The mechanical traits modulus of rupture (MOR) and modulus of elasticity (MOE) were at par in sites 1 and 2, but significantly lower at the driest site 3. The growth rate had a significant positive correlation with KPY, MOR and MOE and a negative correlation with VS, but no significant impact on wood density in both groups of clones. Genotype×environment interaction (G×E) was evident in most traits due to the difference in response of clones to moisture availability. Since wood density was negatively correlated to KPY, it has to be kept at an optimum level for the profitability of pulp industry. There was no significant difference between EC and EH clones for most traits except VS at site 3. Stability of clones varied across sites in different traits, and hence clones may be selected for deployment at each site by screening for growth, followed by wood density, considering the relationship of growth and density with other traits required by pulp and solid wood industry sectors.

고려시대 가구재료 연구 (A Study on the Material of Furniture in Goryeo)

  • 조숙경
    • 한국가구학회지
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    • 제25권1호
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    • pp.19-27
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    • 2014
  • This paper studied the materials of the furniture which the noble men used in Goryeo, based on the furniture material category of solid wood furniture, lacquerware inlaid with mother-of-pearl and hardware. As for the solid wood furniture, the wood and furniture types are inferred based on the documents. The trees used for the wood furniture were zelkova, korean willow, pine, royal paulownia, maidenhair tree, korean pine, chinese juniper and elm. The furniture types were table, chair, wooden bench, small portable table, writing table, and folding screen. As to the types of lacquerware inlaid with mother-of-pearl, most of them were hams with top, which were made of abalone shells. The features of the lacquerware inlaid with mother-of-pearl were in detail and elaborate like the pattern of the full bloomed chrysanthemum. Writing tables were also made of lacquerware as pieces of furniture. Distinctively, the mother-of-pearl furniture material was popular enough to be used even in a horse saddle. Regarding the metal feldspar used as both a practical use and decoration, there are drop handle, hinge, the front basis, and lock seen in the artifacts, which were made of cast iron, bronze, and brass. Their manufacture techniques were eojamoon, bratticing and sheet metal. Through this study of the furniture materials used in Goryeo, it seems that Goryeo furniture focused on the functions rather than on the decorations, and in turn the forms were simple and basic. The technique of mother-of-pearl, a bit elaborate one, was used in the props furniture like kitchen wares, hams, or writing talbes. Probably, the solid wood is inferred to be used in a low wooden bench, a chair, and a table based on the documents.

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아세틸화 활엽수재의 치수변화 특성 (Dimensional Change of Acetylated Hardwood)

  • 한규성
    • 한국가구학회지
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    • 제11권2호
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    • pp.79-84
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    • 2000
  • It is well-known fact that dimensional stability of wood is greatly enhanced by acetylation of wood. This dimensional stability results from bulking of the reacted acetate within the cell wall, which reduces further swelling when the modified woods come into contact with water or water vapor. The purpose of this research was to determine the water absorption and dimensional stability of the acetylated solid wood in liquid water and in humidity tests. Beech and red oak were acetylated. Moisture and water absorption of acetylated wood were quite dependent on weight percent gain(WPG). Antiswelling efficiency(ASE) was quite dependent on WPG, but was not dependent on species.

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Improvement of Dimensional Stability of Acacia mangium Wood by Heat Treatment: A Case Study of Vietnam

  • Tran, Van Chu
    • Journal of Forest and Environmental Science
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    • 제29권2호
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    • pp.109-115
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    • 2013
  • Fast-grown wood generally contains a high proportion of juvenile wood that results in inferior dimensional stability and durability against biological deteriorations. In the present research, the Acacia mangium wood from plantation forests in Vietnam was treated with high temperature in air. The effects of heat treatment on physical properties of Acacia mangium wood, including mass loss (ML), water absorption (WA), water-repellent effectiveness (WRE) and anti-swelling efficiency (ASE) were examined. The results showed that the dimensional stability and the water-repellent effectiveness are increased by about 15-46% and 8-18%, respectively. However, the mass and dimension of wood are decreased. The results also indicated that both treatment temperature and treatment duration significantly affect the wood properties of Acacia mangium. It is thus concluded that heat treatment demonstrates an interesting potential to improve the wood quality of Acacia mangium for solid timber products. This technology provides an environmentally safe method of protecting sustainable common woods to give a new generation of value-added biomaterials with increased stability without the use of toxic chemicals.

레이저변수(變數)와 피삭재조건(被削材條件)이 목재(木材) 및 목질(木質)보드의 절삭특성(切削特性)에 미치는 영향(影響)(I) - 절삭(切削)깊이와 절삭폭(切削幅) - (Effects of Laser Parameters and Workpiece Conditions on Cutting Characteristics of Solid Wood and Wood-based Panel(I) - Cutting Depths and Kerf Widths -)

  • 심재현;정희석
    • Journal of the Korean Wood Science and Technology
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    • 제25권4호
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    • pp.75-91
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    • 1997
  • Laser cutting tests were conducted to investigate the laser cutting characteristics of solid woods such as 25mm-thick white oak(Quercus acutissima) and maple(Acer mono), and wood-based panels such as 15mm-thick medium density fiberboard and particleboard. Test variables were laser power, cutting speed, grain direction, and moisture content. Cutting depths, kerf widths and the maximum cutting speed were measured. Cutting depths were increased as focus of laser beam was moving from above the workpiece to on the surface of workpiece, and also to below the workpiece. Kerf widths were decreased as focus of laser beam was moving from above the workpiece to on the surface of workpiece, but were increased as focus of laser beam was moving from on the surface of workpiece to below the workpiece. Minimum kerf widths were obtained when focus of laser beam was positioned on the surface of workpiece. Cutting depths and kerf widths were decreased with increase in moisture content, and cutting depths and kerf widths of more dense white oak were smaller than those of maple. And also cutting depths and kerf widths of particleboard were smaller than those of medium density fiberboard.

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수치해석법을 활용한 압축부재 성능 해석의 가능성에 대한 연구 (The study on the possibility of performance analysis for the compressive member using the numerical method)

  • 김광철
    • 한국가구학회지
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    • 제21권1호
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    • pp.26-39
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    • 2010
  • This is a leading study to replace the structural analysis methodology on the specific traditional joint by a numerical analysis. Tests were carried out to test the compressive methodologies with the numerical results. The Japanese larch was used as a sample. The Orthotropic property of wood was specifically considered for the finite element numerical analysis. Linear numerical analysis and non-linear numerical analysis for the BEAM element and the two SOLID elements of ANSYS were used to analyze the compressive performance. In addition, more finely divided elements were used to raise the accuracy of the numerical result. Finally, the statistically significant differences were tested between that of the analytical and numerical results. It could be concluded that the SOLID 64 element shows the most optimum result when the non-linear analysis with the more finely divided element was used. However, finely dividing of the element is a considerable time consuming process, and it is quite difficult to raise the accuracy of the non-linear numerical analysis. Therefore, if considering the vertical displacement to be of the only interest, the BEAM element is more efficient than the SOLID element because the BEAM element is reflected as a simple line, which is less time consuming and difficult in dividing the elements. But, the BEAM element cannot accurately model the knot as a strength defect factor which is an important property in the orthotropic property of wood. Therefore, the SOLID element should be used to model the strength defect factor, knot, as it can be efficiently applied on the structural size flexure member which could be more strongly effected by the knot. In addition, it is useful at times when the failure types of members are to be more closely investigated, as the SOLID element is able to examine the local stress distribution of the member. The conclusion drawn by this study is of the good concordance between analytical results and numerical results of compressive wood members, but how orthotropic properties should only be considered. The numerical analysis on the specific Korean traditional joints will be based on the current study results.

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은수원사시나무의 무기산 가수분해에 의해 생성된 고형 부산물의 화학 구조 (Chemical Characteristics of Solid Residues Produced from Acid Hydrolysis of Hybrid Poplar Wood)

  • 오신영;김재영;황혜원;이오규;최준원
    • Journal of the Korean Wood Science and Technology
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    • 제41권1호
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    • pp.1-11
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    • 2013
  • 본 연구에서는 은수원사시나무의 산 당화공정에서 생성되는 고형 부산물의 화학적, 구조적 특성을 관찰하였다. 산 가수분해는 황산과 염산을 사용하였고, 1차 가수분해농도를 72%, 36%, 18%로 변화를 주었고, 2차 가수분해에서 4%로 동일하게 희석하였다. 가수분해 후 액상 가수분해액과 고형 부산물을 각각 분리하였고 고형 부산물을 각각 RS72, RS36, RS18, RC36, RC18이라고 하였다. 황산의 농도가 높아짐에 따라 생성된 고형부산물은 감소(71.2~21.4%)하였지만, 염산의 농도는 고형 부산물의 생성량(65.0~67.0%)에 큰 영향을 주지 않았다. 또한 RS36과 RS18은 고형 부산물 질량 대비 23.6%, RC36과 RC18은 각각 25.6%, 27.3%가 리그닌으로 이루어져 있었다. 고형 부산물의 열분해산물 분석 결과 Levoglucosan, Furfural 등 탄수화물 유래 물질과 리그닌 유래 물질인 Guaiacol, Syringol 등이 검출되었지만 RS72에서는 리그닌 유래 물질만이 검출되었다. 또한 열중량분석결과 고형 부산물 내 리그닌 함량이 높아질수록 다량의 탄이 생성되고 최대 중량 감소율이 감소하여 염산에 비해 황산이, 또한 산의 농도가 높을수록 화학적으로 축합된 구조를 형성하는 것을 확인하였다.

현사시나무 목분의 초임계수 처리 공정으로부터 유래한 미분해 고형성분의 화학적 특성 (Chemical Features of Solid Residues Obtained from Supercritical Water Treatment of Populus alba×glandulosa)

  • 김광호;엄인용;이수민;이오규;;최준원
    • Journal of the Korean Wood Science and Technology
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    • 제37권4호
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    • pp.372-380
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    • 2009
  • 현사시나무 분말(60 mesh 통과)을 압력 $220{\pm}10atm$, 온도 $325{\sim}425^{\circ}C$ 범위 내에서 60초 간 초임계수로 처리한 후에 미분해 고형잔사를 얻을 수 있었다. 고형잔사 내 섬유상 물질을 구성하는 주요 당은 글루코오스와 자일로스였으며, 가장 높은 온도인 $425^{\circ}C$에서 초임계수 처리를 하였을 때 글루코오스/자일로스 구성 비율이 가장 높게 측정되었다. 초임계수 반응온도가 높아질수록 고형 잔사를 구성하는 섬유상 물질의 비율은 감소하였으나, 리그닌의 비율은 상대적으로 증가하였다. 고형잔사에 존재하는 리그닌의 H (p-hydroxyphenyl) : G (guaiacyl) : S (syringyl) 비율은 분석형 열분해법으로 측정하였으며, 반응온도에 따른 변화 없이 비교적 일정하게 나타났다. 고형잔사를 구성하는 리그닌의 H : G : S 조성을 현사시나무에서 단리한 milled wood lignin (MWL)과 비교해보면 G 형 단량체의 비율에는 큰 변화가 없었지만, H 형 단량체 비율은 비교적 낮게 측정되었고, 반면 S 형 단량체 비율은 증가하였다. 초임계수 당화과정에 염산촉매를 첨가하면 H 비율의 감소와 S 비율의 증가는 더욱 두드러지게 나타났다. 니트로벤젠 산화법(nitrobenzene oxidation)에 의하면 현사시나무 MWL에서 획득한 vanillin과 syringaldehyde의 수율은 약 265 mg/g MWL으로 측정되었지만, 초임계수 고형성분의 NBO 분석 결과에 의하면 반응온도를 높여 주거나 염산촉매를 첨가하면 NBO 분해산물은 두드러지게 감소하였다. 이러한 결과는 초임계수 반응 조건에서 리그닌의 주요 결합 양식인 $\beta$-O-4 결합이 비교적 쉽게 끊어지는 것으로 해석되며, 따라서 초임계수 반응 후 고형성분에 존재하는 리그닌은 $\beta$-O-4 결합 대신 탄소-탄소 결합에 의한 축합형 페놀고분자로 예측되었다.

적층목질재(積層木質材)(Glulam)의 중립축(中立軸)과 강도적(强度的) 성질(性質)에 관한 연구(硏究) (Study on the Neutral Axis of Glulam and its Mechanical Properties)

  • 박헌
    • Journal of the Korean Wood Science and Technology
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    • 제18권3호
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    • pp.42-52
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    • 1990
  • In this study, thick 24mm glulams were composed of thick. 3, 4, 6, 8mm Larch laminas to study that the theoretical analysis and the experimental analysis regarding the location of neutral axis of the glulams were compared, and to study on the effect of location of neutral axis on mechanical properties of glulam. The variation of location of neutral axis after proportional limit(or elastical limit) was studied to offer basic data to make the better composition method of glulam. The result obtained can be summarized as follows: 1. The theoretical neutral axis was 0.547 in solid wood, and also 0.547 in glulams because glulams were composed of only Larch laminas. 2. In solid wood, the deviation of the theoretical and the experimental neutral axis location was 0.1%, But in glulams, the deviation from-12.2% to + 7.8% showed nonuniform pattern but no large deviation. Because laminas was only of Larch and so the mechanical properties of laminas were monotonous. 3. The neutral axis exerted no influance on the elasticity of glulam, which meaned that the maximum shear strength in the neutral axis showed no influance on elasticity limit. 4. The only minutely lower elasticities of glulam than that of solid wood were shown. This was because of influance of glue lines of glulam on the elasticlties. 5. The failure type of glulam was wholly simple tension failure and the horizontal shear failure near neutral axis was not taken place, which was that glue line was complete in bonding and the strength of the lamina was not various but uniform. 6. The ratio of tension strain($^{\varepsilon}t$) I compression strain($^{\varepsilon}c$) initially showed uniform level After the elasticity limit. the ratio was increased with the flow of time and so the tension strain was more increased than compression strain. So this proved tension lamination technique, which is that the mechanical properties of glulam could be improved, if the lamina of more superior strength would he added on the bottom side of the glulam.

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