• Journal of Korean Society for Atmospheric Environment
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• v.21 no.3
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• pp.285-293
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• 2005

This study was aimed at estimation of gas-particle partitioning of polychlorinated biphenyls (PCBs) in ambient air. The samples were collected at urban site in Japan from March 2002 to January 2003. The concentration of total PCBs (from 4 CB to 10 CB) and TEQ (Toxic equivalent) ranged from 62 to $247\;pg/m^3$ and from 2 to $14\;fgTEQ/m^3 $, respectively. The average contribution $(\%)$ of gas phase to total PCBs concentration was above $80\%$, which suggests that in the atmosphere PCBs predominantly existed in the gas phase. The weak correlations between total PCBs concentration and temperature was found. However this result was due to a typhoon during summer and raining during sampling period. The gas-particle partition coefficient (Kp) was obtained as a function of temperature. The partition ratio of gaseous and particulate phase PCBs can be estimated for an arbitrary temperature. The plot of gas/particle partition coefficient (log Kp) vs. sub-cooled liquid vapor pressure $(log\;P_L)$ had reasonable correlations for individual samples but the slope varied among the samples (coefficients of determination for log Kp versus log $P_L$ plot were> 0.76 $(p<0.0001)$, except for 3 samples). As a result, the variations in the slope among the sampling period may be due to change of temperature, raining during sampling period and wind in this study.

• Journal of the Korean Institute of Electrical and Electronic Material Engineers
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• v.11 no.4
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• pp.298-305
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• 1998

The PVC membrane electrode for measuring perchlorate ion was developed by incorporating various quaternary ammonium sallts. The effect of chemical structure, the content of active material, the kind of plasticizers, and the membrane thickness on the electrode characteristic such as the linear response range and Nernstian slope of the electrode were studied. It was obtained that the effect of the chemical structure of an active material on the electrode characteristics was improved with increasing the alkyl chain length of the quarternary ammonium salts in the ascending order of Aliquat 336P, TOAP, TDAP, and TDDAP. The optimum membrane composition was 9.09wt% of TDDAP, 30.3wt% of PVC, and 60.6wt% of plasticizer(DBP). And the optimum membrane thickness was 0.45mm at this composition. Under the above condition, the linear response range was $10^{-1}~1.2\times10^{-6}$M, and the detection limit was $5.1\times10^{-7}$M with the Nernstian slope of 57mV/decade of activity of perchlorate ion. The electrode potential was stable within the pH range from 4 to 11. The selectivity coefficient was as shown below: $SCN^->I^-NO_3^->Br^->ClO_3^->F^->Cl^->SO_4^{2-}$

• Journal of Hydrogen and New Energy
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• v.35 no.4
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• pp.363-369
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• 2024

Needle valves are instrumentation devices with quick-opening inherent flow characteristics, used in pipelines requiring rapid flow supply immediately upon opening the flow path. For needle valves applied in liquefied hydrogen plants operating in cryogenic environments, it is necessary from the initial design stage to have various inherent flow characteristics in addition to quick-opening, depending on the intended usage. In this study, the inherent flow characteristics of a 1/2'' liquid hydrogen needle valve were evaluated through computational fluid dynamics analysis. Disk shapes exhibiting various inherent flow characteristics were proposed by deriving the flow coefficient (Cv) according to changes in disk shapes. Among the disk shapes that directly affect the Cv, the disk length and slope angle were selected, and case studies were conducted with nine parameter combinations. From the results of the normalized Cv regarding to opening rates, disk lengths and slope angles exhibiting quick-opening, equal-percentage, and linear inherent flow characteristics were determined.

• The Journal of Engineering Geology
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• v.15 no.1
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• pp.9-17
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• 2005

A set of soil samples were picked up from a failed slope formed by rainfall in limestone zone in Jangseong-gun, Jeonnam, Korea, to find out its physical and mechanical characteristics for this study, and variation of safety factor depending on slope inclination was defined by analysing slope stability affected by rainfall. Decomposed limestone soil in the research area is composed of quartz, orthoclase, gibbsite, geothite, etc., with specific gravity of 2.73, and this soil is included in SC by unified soil classification system. Calcium ingredient decreased remarkably during weathering at its mother rock. Coefficient of permeability is 2.56×10/sup -4/ cm/ sec, similar to its value of silty clay. Cohesion decreases remarkably from 3.0 t/ ㎡ to 0.72 t/ ㎡, and Φ value of internal friction angle tends to decrease as it turns to be saturated soil from partial saturated soil in the shear test. To analyze slope stability affected by rainfall, it is reasonable to seek seepage depth with reference to rainfall＊ intensity. In the slope stability analysis, when the seepage depth is the larger, its safety factor is the less, which makes the slope unstable. Comparing with minimum safety factor, 1.5 of cut slope in consideration of the seep-age line, safety factor is found to be satisfactory only when inclination of cut slope of decomposed limestone soil is more than 1：1.2 slope at least considering rainfall. It is also found that decrease of cohesion has great effect on decline of safety factor of slope while partial saturated soil turns to be saturated soil.

• Journal of Korean Society of Coastal and Ocean Engineers
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• v.28 no.3
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• pp.124-131
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• 2016

In this study, a physical experiment was performed to investigate the change in the stability coefficient, defined by Hudson equation, for the tetrapod of different specific densities. The experiment was carried out once (with no repetition) for a rubble mound breakwater with 1:1.5 slope. In this experiment, the stability coefficient for the high-density tetrapod was greater than that for the normal-density tetrapod. This indicates variability of the stability coefficient according to change in the density of tetrapod. Further experiments and detailed analysis are required to investigate the effect of the density on the stability coefficient of tetrapod.

• Proceedings of the Korean Society for Technology of Plasticity Conference
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• 1999.08a
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• pp.308-312
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• 1999

Developed the model equations which calculate roll force, roll power during hot rolling in real time. The variables which mainly effect on the roll force, roll power are shape factor, reduction, roll diameter, roll velocity, strip inlet temperature, carbon content of strip and strip-roll contact friction coefficient. Among these variables roll diameter, roll velocity, inlet temperature, carbon content and friction coefficient can be excluded in interpolated model equation by introducing equation of die force(F'), power(p') of the frictionless uniform plane strain compression which can be calculated without iteration. At the case of coulomb friction coefficient of 0.3, we evaluated coefficient of polynomial equations of {{{{ { F} over {F' } }}}}, {{{{ { Pf} over {Pd }, { Pd} over {P' } }}}} from the result of finite element analysis using interpolation. It was found that the change of values of {{{{ { F} over {F' }, { P} over {P' } }}}} with the friction coefficient tend to straight line which slope depend only on shape factor. With these properties, developed model equations could be extended to other values of coulomb friction coefficient. To verify developed roll force, roll power model equation we compared the results from these model equation with the results from these model equation with the results from finite element analysis in factory process condition.

• Bulletin of the Korean Chemical Society
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• v.31 no.4
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• pp.959-964
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• 2010

In this work, equilibrium molecular dynamics (MD) simulations in a microcanonical ensemble are performed to evaluate the friction coefficient of a Brownian particle (BP) in a Lennard-Jones (LJ) solvent. The friction coefficients are determined from the time dependent friction coefficients and the momentum autocorrelation functions of the BP with its infinite mass at various ratios of LJ size parameters of the BP and solvent, ${\sigma}_B/{\sigma}_s$. The determination of the friction coefficients from the decay rates of the momentum autocorrelation functions and from the slopes of the time dependent friction coefficients is difficult due to the fast decay rates of the correlation functions in the momentum-conserved MD simulation and due to the scaling of the slope as 1/N (N: the number of the solvent particle), respectively. On the other hand, the friction coefficient can be determined correctly from the time dependent friction coefficient by measuring the extrapolation of its long time decay to t=0 and also from the decay rate of the momentum autocorrelation function, which is obtained by time integration of the time dependent friction coefficient. It is found that while the friction coefficient increases quadratically with the ratio of ${\sigma}_B/{\sigma}_s$ for all ${\sigma}_B$, for a given ${\sigma}_s$ the friction coefficient increases linearly with ${\sigma}_B$.

• Korean Journal of Agricultural and Forest Meteorology
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• v.11 no.1
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• pp.13-18
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• 2009

Accurate solar radiation data are critical to evaluate major physiological responses of plants. For most upland crops and orchard plants growing in complex terrain, however, it is not easy for farmers or agronomists to access solar irradiance data. Here we suggest a simple method using a sun-slope geometry based topographical coefficient to estimate daily solar irradiance on any sloping surfaces from global solar radiation measured at a nearby weather station. An hourly solar irradiance ratio ($W_i$) between sloping and horizontal surface is defined as multiplication of the relative solar intensity($k_i$) and the slope irradiance ratio($r_i$) at an hourly interval. The $k_i$ is the ratio of hourly solar radiation to the 24 hour cumulative radiation on a horizontal surface under clear sky conditions. The $r_i$ is the ratio of clear sky radiation on a given slope to that on a horizontal reference. Daily coefficient for slope correction is simply the sum of $W_i$ on each date. We calculated daily solar irradiance at 8 side slope locations circumventing a cone-shaped parasitic volcano(c.a., 570m diameter for the bottom circle and 90m bottom-to-top height) by multiplying these coefficients to the global solar radiation measured horizontally. Comparison with the measured slope irradiance from April 2007 to March 2008 resulted in the root mean square error(RMSE) of $1.61MJ\;m^{-2}$ for the whole period but the RMSE for April to October(i.e., major cropping season in Korea) was much lower and satisfied the 5% error tolerance for radiation measurement. The RMSE was smallest in October regardless of slope aspect, and the aspect dependent variation of RMSE was greatest in November. Annual variation in RMSE was greatest on north and south facing slopes, followed by southwest, southeast, and northwest slopes in decreasing order. Once the coefficients are prepared, global solar radiation data from nearby stations can be easily converted to the solar irradiance map at landscape scales with the operational reliability in cropping season.

• Journal of Industrial Technology
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• v.22 no.A
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• pp.153-159
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• 2002

This paper is an experimental work of estimating friction angle of very coarse grained soil such as rubble mound by performing laboratory experiments. Two crushed rocks of rubble mound were used for tests. Triaxial compression tests with drained conditions were performed to measure friction angles of soils prepared by mixing the crushed soil having an identical coefficient of uniformity with different maximum grain size distribution. Centrifuge model experiments with those soils were also performed to measure angle of repose and to estimate friction angle of soil from measuring the slope of slip line in the active stress state. Model tests were carried out by changing the G-levels of 1G and 50G. From triaxial compression tests, the measured value of friction angle of soil is in the range of $41{\sim}57^{\circ}$. The measured value of repose angle is in the range of $32{\sim}35^{\circ}$. The values of friction angle are found not so sensitive to the maximum grain size of soil as long as the coefficient of uniformity is identical. Estimated value of friction angle from measuring the slope of slip line in the active stress state is in the range of $30{\sim}46^{\circ}$. Thus, the estimated angle of friction are found to be greater in the order of the measured angle of repose, the estimated value from the slope of active state, and triaxial compression test results. On the other hand, the measured values of friction angle from triaxial tests were compared with empirical equations, based on the relation between friction angle and void ratio. Equations proposed by Helenelund(l966) and Hansen(1967) found to be relatively reliable to estimate friction angles of soil.

• Journal of Korean Society of Forest Science
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• v.106 no.4
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• pp.424-430
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• 2017

With its rapid velocity and wide deposition, debris flow is a natural disaster that causes loss of human life and destruction of facility. To design effective debris barriers, impact force of debris flow should be first considered. Debris flow velocity is one of the key features to estimate the impact force of debris flow. In this study, we conducted small-scale flume experiments to analyze flow characteristics of debris flow, and determine flow resistance coefficients with different slope gradients and sediment mixtures. Flow velocity significantly varied with flume slope and mixture type. Debris flow depth decreased as slope increased, but difference in depth between sediment mixtures was not significant. Among flow resistance coefficients, Chezy coefficient ($C_1$) showed not only relatively highest goodness of fit, but also constant value ($20.19m^{-1/2}\;s^{-1}$) regardless the scale of debris flow events. The overall results suggested that $C_1$ can be most appropriately used to estimate flow velocity, the key factor of assessing impact force, in wide range of debris flow scale.