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A Comparative Study on Strength Development, Chloride Diffusivity and Adiabatic Temperature Rise of Marine Concrete Depending on Binder Type (결합재 종류에 따른 해양 콘크리트의 강도 발현, 염화물 확산 및 단열온도 상승 특성에 대한 비교 연구)

  • Bae, Jun-Young;Cho, Sung-Hyun;Shin, Kyung-Joon;Kim, Yun-Yong
    • Journal of the Korea Concrete Institute
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    • v.25 no.4
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    • pp.411-418
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    • 2013
  • Recently, in order to reduce a damage of chloride attack and hydration heat in marine concrete structures, blended cement in mixing the marine concrete is widely used. Long term strength development is distinct in concrete with blended cement and it also has excellent resistance to chloride attack and reduction of hydration heat. However, blended cement has a characteristic of relatively low compressive strength in early age of 28 days. On the other hand, a high level of compressive strength is required in the Standard Specification for marine concrete mix design. Such concrete mix design satisfying Standard Specification is effective to chloride attack but disadvantageous for hydration heat reduction due to large quantity of binder. In this study, the material properties of marine concrete considering water-binder ratio and binder type are experimentally investigated. Through the research results, compressive strength in blended cement at the age of 56 days is similar although it has smaller compressive strength at the age of 28 days compared with result of OPC (ordinary portland cement). Even though blended cement has a large water-binder ratio and small unit of binder content, chloride ion diffusion coefficient is still small and hydration heat is also found to be reduced. For meeting the required compressive strength in Standard Specification for marine concrete at 28 days, the increased unit content of binder is needed but the increased hydration heat is also expected.

Optimization of ${\beta}$-Glucanase-assisted Extraction of Starch from Domestic Waxy Barley and Its Physicochemical Properties (${\beta}$-Glucanase를 이용한 국내산 찰보리 전분 추출공정의 최적화 및 추출 전분의 주요 이화학적 특성에 관한 연구)

  • Jeong, Yong-Seon;Bae, Jae-Seok;Kim, Jeong-Won;Lee, Eui-Seok;Lee, Ki-Teak;Lee, Mi-Ja;Hong, Soon-Taek
    • Journal of the East Asian Society of Dietary Life
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    • v.23 no.6
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    • pp.789-798
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    • 2013
  • In the present study, optimization on ${\beta}$-glucanase-assisted extraction was made in order to isolate waxy barley starch from domestic cultivar using the D-optimal design suitable for response surface methodology (RSM). The results demonstrated that the amount of enzyme was found to be a major influencing factor on the extraction yield, which was substantially increased by increasing the amount of enzyme. It was also influenced by the reaction time and amount of water addition; however, the two factors were less influential than the amount of enzyme. The optimized condition by RSM for the reaction time was found to be 2.63 hours and amount of enzyme 1.7%, and amount of water addition 4.38 times the weight of raw material. With the enzyme treatment, the starch content in residues (R), particularly in R1 and R5, was reduced considerably, resulting in an increase in the extraction yield and therefore primarily and effectively releasing B-type starch small granule confirmed by scanning electronic microscopy. In addition, the study determined the physicochemical properties of isolated waxy starch (i.e., purity, water adsorption capacity, thermal properties, rheology and starch morphology) and compared them with those from the enzyme-not treated sample. It was found that they were almost similar to each other, except for the purity of starch, which was lower in the enzyme-treated sample than in the enzyme-not treated one.

Numerical analysis of CZ growth process for sapphire crystal of 300 mm length: Part I. Influence of hot zone structure modification on crystal temperature (300 mm 길이의 사파이어 단결정 대한 CZ성장공정의 수치해석: Part I. 핫존 구조 변경이 결정 온도에 미치는 영향)

  • Shin, Ho Yong;Hong, Su Min;Kim, Jong Ho;Jeong, Dae Yong;Im, Jong In
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.23 no.6
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    • pp.265-271
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    • 2013
  • Czochralski (CZ) growth process is one of the most important techniques for growing high quality sapphire single crystal for LED application. In this study, the inductively-heated CZ growth processes for the sapphire crystal of 300 mm length have been analyzed numerically using finite element method. The hot zone structures were modified with the crucible geometry change and the additional insulation layer installed above the crucible. The results show that the solid-liquid interface height decreased from about 80 mm at initial stage to 40 mm after mid-stage due to achieve the growth speed balance. Also the optimal input power of the modified system was similar with the original one due to the compensation effects of the crucible geometry and additional insulation. The crystal temperature grown by the modified CZ grower was increased about 10 K than the original one. Therefore the sapphire crystal of 300 mm height was grown successfully.

Effect of Lithium Bis(oxalate)borate as an Electrolyte Additive on Carbon-coated SiO Negative Electrode (탄소가 코팅된 일산화규소(SiO) 음극에서 전해질 첨가제로서 Lithium Bis(oxalato)borate의 영향)

  • Kim, Kun Woo;Lee, Jae Gil;Park, Hosang;Kim, Jongjung;Ryu, Ji Heon;Kim, Young-Ugk;Oh, Seung M.
    • Journal of the Korean Electrochemical Society
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    • v.17 no.1
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    • pp.49-56
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    • 2014
  • As an electrolyte additive, the effects of lithium bis(oxalate)borate (LiBOB) on the electrochemical properties of a carbon-coated silicon monoxide (C-coated SiO) negative electrode are investigated. The used electrolyte is 1.3M $LiPF_6$ that is dissolved in ethylene carbonate (EC), fluoroethylene carbonate (FEC), and diethyl carbonate (DEC) (5:25:70 v/v/v) with or without 0.5 wt. % LiBOB. In the LiBOB-free electrolyte, the film resistance is not so high in the initial period of cycling that lithiation is facilitated to generate the crystalline $Li_{15}Si_4$ phase. Due to repeated volume change that is caused by such a deep charge/discharge, cracks form in the active material to cause a resistance increase, which eventually leads to capacity fading. When LiBOB is added into the electrolyte, however, more resistive surface film is generated by decomposition of LiBOB in the initial period. The crystalline $Li_{15}Si_4$ phase does not form, such that the volume change and crack formation are greatly mitigated. Consequently, the C-coated SiO electrode exhibits a better cycle performance in the later cycles. At an elevated temperature ($45^{\circ}C$), wherein the effect of film resistance is less critical, the alloy ($Li_{15}Si_4$ phase) formation is comparable for the LiBOB-free and added cell to give a similar cycle performance.

A Study on the Worst Stress Condition Test Evaluation of Blowers for Small Stationary Fuel Cell System (소용량 건물용 연료전지시스템 블로워의 가혹조건 평가에 관한 연구)

  • Kim, Kangsoo;Lee, Deokkwon;Lee, Jungwoon;Kim, Eunjung;Kim, Inchan;Kim, Younggyu;Shin, Hunyong
    • Journal of the Korean Institute of Gas
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    • v.16 no.6
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    • pp.34-40
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    • 2012
  • The fuel cell is one of the renewable energy sources. And it is a new source of energy that can be applied to various fuels and continuously supported by the excellent city-gas infrastructure. It is important to improve performances and reliabilities, and reduce the cost of fuel cell systems for commercialization. And, some safety performances of blower domestically produced are evaluated and some improvements are researched to save the cost of fuel cell systems. In this paper, the performance and worst stress condition of blowers are evaluated in operating environment similar to the fuel cell systems. Actually, the correlation of flow, leakage and thermal behavior are evaluated in the worst stress condition at $70^{\circ}C$ and, some major factors of blower degradation such as a motor deterioration, material and structures of the outlet are examined.

Roll Force Prediction of High-Strength Steel Using Foil Rolling Theory in Cold Skin Pass Rolling (고강도강의 냉간 조질 압연 시 호일 압연이론을 이용한 압연하중의 예측)

  • Song, Gil Ho;Jung, Jae Chook
    • Transactions of the Korean Society of Mechanical Engineers A
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    • v.37 no.2
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    • pp.271-277
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    • 2013
  • Skin pass rolling is a very important process for applying a certain elongation to a strip in the cold rolling and annealing processes, which play an important role in preventing the stretching of the yield point when the material is processed. The exact prediction of the rolling force is essential for obtaining a given elongation with the steel grade and strip size. Unlike hot rolling and cold rolling, skin pass rolling is used to apply an elongation of within 2% to the strip. Under a small reduction, it is difficult to predict the rolling force because the elastic deformation behavior of the rolls is complicated and a model for predicting the rolling force has not yet been established. Nevertheless, the exact prediction of the rolling force in skin pass rolling has gained increasing importance in recent times with the rapid development of high-strength steels for use in automobiles. In this study, the possibility of predicting the rolling force in skin pass rolling for producing various steel grades was examined using foil rolling theory, which is known to have similar elastic deformation behavior of rolls in the roll bite. It was found that a noncircular arc model is more accurate than a circular model in predicting the roll force of high-strength steel below TS 980 MPa in skin pass rolling.

Analysis of Achievement Characteristics by Achievement Standard of the Middle School Curriculum Based on the National Assessment of Educational Achievement (학업성취도 평가 결과에 기반한 중학교 교육과정 성취기준별 성취 특성 분석)

  • Lee, Jaebong;Ku, Jaok;Choi, Wonho;Shim, Kew-Cheol;Shin, Myeong-Kyeong
    • Journal of The Korean Association For Science Education
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    • v.40 no.5
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    • pp.473-483
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    • 2020
  • The purpose of this study was to analyze the characteristics of students' academic achievement of middle school science curriculum achievement standards in the 2009 revised national curriculum and to generate implications for curriculum improvement. Based on the results of the 2015-2018 National Assessment of Educational Achievement (NAEA), we analyzed middle school students' mastery of 84 curriculum achievement standards. In the analysis, we used representative item information by achievement level and correct answer rate and checked the validity of the determination of mastery. According to the results of the analysis, 15 of the 84 achievement standards could not determine the degree of achievement. In science, many achievement standards could be mastered only by above-average group students. By achievement level, there were six achievement standards that advanced achievement-level students did not achieve, 38 achievement standards judged to represent mastery by advanced achievement-level students, 23 achievement standards judged to represent mastery by proficient achievement-level students, and two achievement standards judged to represent mastery by basic achievement-level students. By content area, the number of achievement standards corresponding to advanced and proficient levels was similar in the areas of motion and energy and earth and space domains. In the material and life domains, there were more achievement standards corresponding to advanced levels. Accordingly, it is necessary to reinforce customized teaching and learning activities in relation to achievement standards that were under-achieved.

Characterization of Pine Bark Charcoal Prepared from Small and Large-Scale Carbonization Kilns (소용량 및 대용량 탄화로에서 제조된 소나무 수피탄의 특성)

  • 문성필;황의도;박상범;권수덕
    • Journal of Korea Foresty Energy
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    • v.21 no.2
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    • pp.1-9
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    • 2002
  • Pine bark was carbonized by using a small-scale experimental kiln and three different types of large-scale kilns (simple (400-$500^{\circ}C$), improved (600-$700^{\circ}C$) and special kiln (800-$1,000^{\circ}C$). The physical properties and pore structures of the bark charcoals prepared were analyzed. When the bark was carbonized at various temperatures ranging from 500 to $900^{\circ}C$in the presence of nitrogen, carbonization yield decreased rapidly with increasing carbonization temperature and it remained constant from 700 to $900^{\circ}C$. The carbonization yield of the bark was 16 - 18% higher than that of pine wood. The BET specific surface areas and iodine values increased with a decrease in carbonization yield. The BET specific surface areas of the bark charcoals reached about 400 -$500m^2/g$ for carbonization yield of 32-40%. The pine wood charcoal prepared at $600^{\circ}C$ for 30 min resulted in a more microporous structure, whereas the bark charcoal prepared at the same condition was more mesoporous. The carbonization yields and physical properties such as iodine values and BET specific surface areas of bark charcoals prepared by using the large-scale kilns were very similar to those of the small-scale kiln. The results indicated that the pine bark could be used as starting material to produce good quality charcoal having a large specific surface area and a high carbonization yield.

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THE COMPARATIVE EVALUATION USING HATCH REAMER TECHNIQUE AND OSTEOTOME TECHNIQUE IN SINUS FLOOR ELEVATION (상악동저 거상술 시 Osteotome 술식과 Hatch Reamer 술식의 비교평가)

  • Cho, Seong-Woong;Kim, Sang-Jung;Lee, Dong-Keun;Kim, Chin-Soo
    • Maxillofacial Plastic and Reconstructive Surgery
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    • v.32 no.2
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    • pp.154-161
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    • 2010
  • Many edentulous posterior maxilla are found to be compromised by alveolar resorption and increased pneumatization of the sinus. One of the surgical procedures to overcome this anatomical limitation is sinus floor elevation with bone graft, which is reported as more appropriate and more successful procedure. Commonly, if the residual bone height is over 5mm, sinus floor elevation is operated through transcrestal approach using osteotome technique. But, it is possible for patients to feel discomfort during operation and dizziness after operation while malleting, sinus floor elevation, using osteotome technique. Some instruments and methods has been used to overcome these problems and use more easily. The aim of this study is to compare between the surgical procedure of sinus floor elevation using Hatch reamer technique and that of sinus floor elevation using osteotome technique. From 2004 Feb to 2007 Oct, we investigate patients (osteotome group: 72, Hatch reamer group: 70) who were given implant surgery with sinus floor elevation (osteotome group: 92, Hatch reamer group: 98). We analysed gender, age, residual bone height, amount of sinus floor elevation, used graft material, total success rate, failure rate by residual bone height and implant type and discomfort during operation, etc. The results obtained were as follows. 1. In the amount of sinus elevation was osteotome group was $3.85{\pm}1.02\;mm$ and Hatch reamer group was $3.93{\pm}1.38\;mm$. There was no statistically significant difference between the two groups (P > 0.05). 2. At the total success rate, osteotome group was 92.4% and Hatch reamer group was 94.9%. There was no statistically significant difference between the two groups (P > 0.05). 3. On the discomfort during the operation by using numerical rating scale, osteotome group was $2.87{\pm}0.83$ and Hatch reamer group was $1.12{\pm}0.64$. There was statistically significant difference between the two groups (P < 0.05). The Hatch reamer group clinical results was similar to osteotome group and we thought that Hatch reamer technique can overcome the faults of osteotome technique.

A Study for the Relation Between Selenoproteins and Korean Rectal Cancer Using Deuterium Collision Gas HPLC-ICP/MS (HPLC와 중수소 충돌기체 ICP/MS를 이용하여 분석한 셀레노단백질과 한국인 직장암과의 상관관계 연구)

  • Lee, Seo Young;Pak, Yong-Nam
    • Journal of the Korean Chemical Society
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    • v.63 no.6
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    • pp.420-426
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    • 2019
  • Selenoproteins,in Korean blood serum, GPx, SelP, and SeAlb were separated and determined with the use of HPLC-ICP/MS. Deuterium was used as a collision gas and affinity column with ammonium formate was used as an eluting solvent for the accurate quantitation of selenoproteins in human blood serum. Certified reference material BCR 639 (133±12 ng g-1) was tested for the accuracy and the result was satisfactory 130±6 ng g-1. Blood serum for the rectal cancer and controlled groups were collected and analyzed to give 84±27 ng g-1, and 119±28 ng g-1, respectively. The difference was statistically obvious when t-test was performed (tcal 4.93 > t95% 2.04). The decrease for cancer group was more obvious for female and aged group. The distributions of three selenoproteins were similar with each other, which means rectal cancer group did not show any specificity for any selenoproteins. As cancer developed, GPx showed a slight decrease but not obvious while the total concentration was increasing particularly at the second stage of cancer.