• Title/Summary/Keyword: secondary materials

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Low temperature growth and surface analysis of $YMnO_3$ and Bi modified $YMnO_3$ films ($YMnO_3$ 와 Bi 첨가한 $YMnO_3$ 의 저온성장과 표면분석)

  • 김시원;최택집;이재찬
    • Proceedings of the Materials Research Society of Korea Conference
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    • 2003.11a
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    • pp.167-167
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    • 2003
  • Bi가 첨가된 강유전체 YMnO$_3$ (YBM)와 YMnO$_3$을 펄스 레이저 증착법을 이용하여 MgO(111)기판 위에 증착하였다. 증착시 기판온도와 산소분압에 따른 YBM 박막과 YMnO3 박막의 결정성장거동에 대하여 연구하였고, Bi의 첨가량에 따른 YBM 박막의 저온결정성화 효과에 대하여 관찰하였다. YMnO$_3$는 830 $^{\circ}C$이상에서 산소분압이 감소함에 따라서 c축 우선성장 거동을 보였다. 그에 비해 YBM은 700 $^{\circ}C$이상에서 산소분압이 증가함에 따라 c축 우선성장 하는 것을 관찰하였다. 이것은 Bi 첨가효과로 인해 저온결정화와 높은 산소분압에서 c축 우선성장을 하는 것으로 생각된다. Atomic Force Microscopy (AFM)분석과 Secondary Electron Microscopy(SEM)을 통하여 Bi의 첨가량이 증가함에 따라서 표면거칠가 감소하고 grain size가 증가함을 알 수 있었다. Bi의 거동을 살펴 보기 위해 Rutherford Backscattering spectroscopy (RBS)분석을 해보았다. 이 분석을 통해 Bi를 첨가한 YMnO$_3$는 Bi가 표면에 산화물형태로 존재함을 알 수 있었다.

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Dynamic Response Analysis of Composite H-type Cross-section Beams (복합재료 H-형 단면 보의 동적응답 해석)

  • Kim, Sung-Kyun;Song, Oh-Seop
    • Transactions of the Korean Society for Noise and Vibration Engineering
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    • v.20 no.6
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    • pp.583-592
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    • 2010
  • Equations of motion of thin-walled composite H-type cross-section beams exposed to concentrated harmonic and non-harmonic time-dependent external excitations, incorporating a number of nonclassical effects of transverse shear, primary and secondary warping, and anisotropy of constituent materials are derived. The forced vibration response characteristics of a composite H-type cross-section beam exhibiting the circumferentially asymmetric stiffness(CAS) configuration are exploited in connection with the structural bending-torsion coupling resulting from directional properties of fiber reinforced composite materials.

Hydrogen Storage Properties of Carbon Nanotube Composites (탄소나노튜브 복합재의 수소저장특성)

  • Ahn, Jung-Ho;Jang, Min-Kyu
    • Journal of Powder Materials
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    • v.15 no.3
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    • pp.188-195
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    • 2008
  • Carbon nanotube (CNT)/$Mg_2Ni$ composites were synthesized to enhance the hydrogen storage properties. The emphasis was made on the effect of different shortening methods of CNTs on the open-tip structure and the resulting properties. The use of open CNTs as a starting material resulted in an enhanced hydrogen properties of CNT/$Mg_2Ni$ composites. Among the employed methods for the shortening of CNTs, wet milling using ethanol was the most efficient, while ultrasonic acid treatment or thermal decomposition resulted in a less hydrogen storage capacity.

Development of Preparation Technique of Sintered Ni Electrode (소결식 니켈극 제조기술 개발)

  • Kim, Chan-Jung;Kim, Dai-Ryong
    • Transactions of the Korean hydrogen and new energy society
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    • v.10 no.3
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    • pp.159-170
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    • 1999
  • Recently Ni/MH secondary battery have been studied very extensively because of containing no pollutants as well as superior performance. However comparing to widely studying high capacity of hydrogen storage alloys electrode, the capacity of Ni electrode is inferior. Using for high capacity Ni/MH battery as a anodic materials, the study about high capacity Ni electrode is necessary. To making high capacity Ni electrode, active materials were impregnated in various polarization impregnation conditions. Plaque, milling for 6hr and sintered at $800^{\circ}C$, indicated porosity over 80%, and porosity were increased with proper condition electrochemical etching treatment. Proper impregnation condition was 40~80mA/cm, polarizing time was 5~10min.

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Thermal Stability Analysis of Flexible Beam Spacecraft Appendage (위성체 유연 보 구조물의 열 안정성 해석)

  • 윤일성;송오섭
    • Proceedings of the Korean Society for Noise and Vibration Engineering Conference
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    • 2001.05a
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    • pp.399-406
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    • 2001
  • Thermally induced vibration response of composite thin walled beams is investigated. The thin-walled beam model incorporates a number of nonclassical effects of transverse shear, primary and secondary warping, rotary inertia and anisotropy of constituent materials. Thermally induced vibration response characteristics of a composite thin walled beam exhibiting the circumferentially uniform system(CUS) configuration are exploited in connection with the structural bending-torsion coupling resulting from directional properties of fiber reinforced composite materials and from ply stacking sequence. A coupled thermal structure analysis that includes the effects of structural deformations on heating and temperature gradient is investigated.

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Thermally Induced Vibration Analysis of Flexible Spacecraft Appendages (위성체 유연구조물의 진동 해석)

  • Yoon, Il-Soung;Kim, Gu-Sun;Song, Oh-Seop
    • Proceedings of the Korean Society for Noise and Vibration Engineering Conference
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    • 2000.06a
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    • pp.1216-1221
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    • 2000
  • Thermally induced vibration response of composite thin walled beams is investigated. The thin-walled beam model incorporates a number of nonclassical effects of transverse shear, primary and secondary warping, 'rotary inertia' and anisotropy of constituent materials. Thermally induced vibration response characteristics of a composite thin walled beam exhibiting the circumferentially uniform system(CUS) configuration are exploited in connection with the structural coupling resulting from directional properties of fiber reinforced composite materials and from ply stacking sequence. A coupled thermal structure analysis that includes the effects of structural deformations on heating and temperature gradient is investigated.

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Dispersant Effect on Thermal Performance of SG (증기발생기 열성능에 미치는 분산제 첨가효과)

  • Lee, Jae-Keun;Moon, Jeon-Soo;Yoon, Seok-Won;Maeng, Wan-Young
    • Transactions of the Korean hydrogen and new energy society
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    • v.22 no.4
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    • pp.546-551
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    • 2011
  • The corrosion on steam generator tubes of the secondary side of pressurized water reactor inhibits heat transfer. One of the most efficient techniques improving the heat transfer performance of a nuclear electric generation is a corrosion control. The environmental parameters mostly affecting corrosion are materials and chemical additives. It seems that no further corrosion occurs in steels with Polyacrylic acid polymer dispersant treatment. Polyacrylic acid forms a protective coating with uniform thickness on metal surface. Polyacrylic treatment appears to be the most convenient way to enhance the thermal performance by the thermal conductivity improvement in steam generators.

A Study on Manufacturing Process of Hypereutectic Al-Si Alloy via Horizontal Continuous Casting (수평연속주조에 의한 과공정 Al-Si합금 제조에 관한 연구)

  • You, Bong-Sun;Ji, Mu-Sung;Park, Won-Wook
    • Journal of Korea Foundry Society
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    • v.16 no.2
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    • pp.116-123
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    • 1996
  • The equipment for the horizontal continuous casting was built to produce hyper-eutectic Al-Si bars with a small cross-section of 25mm in diameter. The manufacturing processes including withdrawal cycle and secondary cooling methods were modified to refine the primary and the eutectic Si. The longitudinal casting speeds varied over the ranges of 670-1100mm/min for pure Al, and 200-350mm/min for Al-17wt%Si alloy. Due to the difference of cooling rate in the mould, microstructural asymmetry between the lower and the upper part of bar was observed. Thus, manufacturing processes such as cooling and withdrawal method were optimally combinated to get the homogeneous cast structure. With the increase of casting speed, the primary Si size was refined down to $30{\mu}m$ near the surface, and $80{\mu}m$ in the center of the bar.

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Microstructure and Properties of High Strength High Ductility Al-Mg-Zn Casting Alloy (고강도 고인성 Al-Mg-Zn 주조합금의 미세조직 및 특성)

  • Kim, Jeong-Min;Ha, Tae-Hyung
    • Journal of Korea Foundry Society
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    • v.36 no.6
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    • pp.181-186
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    • 2016
  • The typical microstructure of Al-5%Mg-2%Zn cast alloy mainly consists of an aluminum matrix with a small amount of AlMgZn 2nd phase. The secondary dendrite arm spacing and the grain size of the cast alloy tend to be inversely proportional to the section thickness of casting; however, the tensile properties cannot be said to be clearly related to the cast microstructure. After T6 heat treatment, the tensile strength of the alloy was enhanced significantly. TEM analysis results show that very fine AlMgZn precipitates were formed after the heat treatment. The corrosion resistance, measured according to the corrosion potential, was found to increase slightly after the conducting of heat treatment.

An Overview of Chemically/Surface Modified Cubic Spinel LiMn2O4 Electrode for Rechargeable Lithium Batteries

  • Jung, Kyu-Nam;Pyun, Su-Il
    • Journal of the Korean Electrochemical Society
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    • v.9 no.4
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    • pp.158-169
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    • 2006
  • The present article is concerned with the overview of the chemically/surface modified cubic spinel $LiMn_2O_4$ as a cathode electrode far lithium ion secondary batteries. Firstly, this article presented a comprehensive survey of the cubic spinel structure and its correlated electrochemical behaviour of $LiMn_2O_4$. Subsequently, the various kinds of the chemically/surface modified $LiMn_2O_4$ and their electrochemical characteristics were discussed in detail. Finally, this article reviewed our recent research works published on the mechanism of lithium transport through the chemically/surface modified $Li_{1-\delta}Mn_2O_4$ electrode from the kinetic view point by the analyses of the experimental potentiostatic current transients and ac-impedance spectra.