• Title/Summary/Keyword: s-PDMS

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Preventing marine organisms adhesion by oil-infused PDMS (오일이 주입된 PDMS를 이용한 해양생물의 부착방지 방법에 대한 고찰)

  • Kim, Su-Yeong;Yun, Yeong-Cheol;Im, Chae-Gang;Jeong, Yong-Chan;Lee, Su-Yeol
    • Proceedings of the Korean Institute of Surface Engineering Conference
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    • 2018.06a
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    • pp.45-45
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    • 2018
  • 홍합, 따개비 등의 접착성 해양생물은 선박의 하부나 발전소 해수 공급용 튜브에 부착하여 운영 효율을 저하 시키고, 냉각기기 고장을 유발하는 파울링(Fouling) 문제를 야기시킨다. 일반적으로 이러한 문제에 대응하기 위해서 초접착성 해양생물이 주로 부착하는 부위에 $Cu_2O$, ZnO 등을 포함한 유기화합물로 표면처리를 하여 부착방지를 하고 있지만, 이 소재들을 장시간 사용 시 해양 오염 및 부식을 가속화하는 문제를 초례하기 때문에 최근에는 사용을 금지하고 있다. 이러한 유해성 소재 문제를 해결하고자 친환경적이고 부작용이 없는 초접착성 해양생물 부착방지 소재를 개발하고자 하였다. 본 연구에서는 낮은 표면장력을 갖는 PDMS(Polydimethylsiloxane) 소재를 기반으로 소수성 oil을 침투시킨 I-PDMS(Oil-Polydimethylsiloxane) 표면처리법을 고안하였고, 이 방법을 활용하여 초접착성 해양생물에 대한 부착방지 성능을 향상시키고자 하였다. 기존의 개발품들 보다 성능이 향상된 I-PDMS 제조하고자, Nano-indentation을 이용한 기계적 특성 평가, X컷 및 cross-cut을 이용한 부착력 평가, 실제 바다환경에서 해양생물의 부착력 시험, 바다 환경을 모사한 수조에서의 I-PDMS와 비교군 기판에서의 홍합 거동, 홍합과 기판의 접착강도 시험, 해양 미생물 평가를 실시하였으며, 이를 통해서 I-PDMS 성능 및 내구성을 입증하고자 하였다.

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Fabrication and Evaluation of the Flexible and Implantable Micro Electrode (생체 삽입형 유연한 마이크로 전극의 제작 및 평가)

  • Baek Ju-Yeoul;Kwon Gu-Han;Lee Sang-Woon;Lee Ky-Am;Lee Sang-Hoon
    • The Transactions of the Korean Institute of Electrical Engineers C
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    • v.55 no.2
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    • pp.93-99
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    • 2006
  • In this paper, we fabricated and evaluated polydimethylsiloxane(PDMS)-based flexible and implantable micro electrodes. The electrode patterning was carried out with the photolithography and chemical etching process after e-beam evaporation of 100 ATi and 1000 A Au. The PDMS substrate was treated by oxygen plasma using reactive ion etching(RIE) system to improve the adhesiveness of PDMS and metal layers. The minimum line width of fabricated micro electrode was 20 $\mu$m. After finished patterning, we did packaging with PDMS and then brought up the electrode's part about 40 $\mu$m with gold electroplating. The Hank's balanced salt solution(HBSS) test was carried out for 6 month for endurance of fabricated micro electrode. We carried out in-vivo test for the evaluation of biocompatibility by implanting electrodes under the ICR mouse skin for 42 days.

The Concentration of Magnolia Aroma Model Solution Using Pervaporation and Preparation of PVDF/PDMS Composite Membranes (투과증발법을 이용한 Magnolia Aroma 모델액의 농축 및 PVDF/PDMS 복합막의 제조)

  • Lee, Yong-Taek;Park, Joong-Won;Shin, Dong-Ho
    • Membrane Journal
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    • v.17 no.1
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    • pp.14-22
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    • 2007
  • This is the research about the concentration of trace Magnolia flavor components in water by pervaporation. We have investigated the change of selectivity depending on support membrane structure and active layer thickness using prepared PVDF/PDMS composite membrane. Through the pure water flux test for PVDF support membrane, we could indirectly confirm that as the coagulation temperature decreases and the polymer concentration increases, the surface porosity and pore diameter decreases. Appling these results to transport mechanism, we could explain the effect of support membrane structure for the composite membrane. The selectivity increases as the thickness of PDMS active layer increases. We could know that there is a limitation to describe the transport on the active layer by Fick's law through these results.

Variation of Elastic Stiffness of Polydimethylsiloxane (PDMS) Stretchable Substrates for Wearable Packaging Applications (웨어러블 패키징용 Polydimethylsiloxane (PDMS) 신축성 기판의 강성도 변화거동)

  • Choi, Jung-Yeol;Park, Dae-Woong;Oh, Tae Sung
    • Journal of the Microelectronics and Packaging Society
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    • v.21 no.4
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    • pp.125-131
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    • 2014
  • In order to develop stretchable substrates for wearable packaging applications, the variation behavior of elastic modulus was evaluated for transparent PDMS Sylgard 184 and black PDMS Sylgard 170 as a function of the base/curing agent mixing ratio. Both for Sylgard 184 and Sylgard 170, the true elastic modulus evaluated on a true stress-true strain curve was higher more than two times compared to the engineering elastic modulus obtained from an engineering stres-sengineering strain curve, and their difference became larger with increasing the stiffness of the PDMS. Sylgard 184 exhibited a maximum engineering elastic modulus of 1.74 MPa and a maximum true elastic modulus of 3.57 MPa at the base/curing agent mixing ratio of 10. A maximum engineering elastic modulus of 1.51 MPa and a maximum true elastic modulus of 3.64 MPa were obtained for Sylgard 170 at the base/curing agent mixing ratio of 2.

In situ reduction of gold nanoparticles in PDMS matrices and applications for large strain sensing

  • Ryu, Donghyeon;Loh, Kenneth J.;Ireland, Robert;Karimzada, Mohammad;Yaghmaie, Frank;Gusman, Andrea M.
    • Smart Structures and Systems
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    • v.8 no.5
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    • pp.471-486
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    • 2011
  • Various types of strain sensors have been developed and widely used in the field for monitoring the mechanical deformation of structures. However, conventional strain sensors are not suited for measuring large strains associated with impact damage and local crack propagation. In addition, strain sensors are resistive-type transducers, which mean that the sensors require an external electrical or power source. In this study, a gold nanoparticle (GNP)-based polymer composite is proposed for large strain sensing. Fabrication of the composites relies on a novel and simple in situ GNP reduction technique that is performed directly within the elastomeric poly(dimethyl siloxane) (PDMS) matrix. First, the reducing and stabilizing capacities of PDMS constituents and mixtures are evaluated via visual observation, ultraviolet-visible (UV-Vis) spectroscopy, and transmission electron microscopy. The large strain sensing capacity of the GNP-PDMS thin film is then validated by correlating changes in thin film optical properties (e.g., maximum UV-Vis light absorption) with applied tensile strains. Also, the composite's strain sensing performance (e.g., sensitivity and sensing range) is also characterized with respect to gold chloride concentrations within the PDMS mixture.

The Study on the Recovery of Volatile Organic Components by Pervaporation (Pervaporation을 이용한 휘발성 유기성분 회수에 관한 연구)

  • 김희진;송영석;민병렬
    • Membrane Journal
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    • v.9 no.1
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    • pp.51-62
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    • 1999
  • The recovery of trace volatile organic components from water by pervaporation was investigated. Permeation experiments through homogeneous polydimethylsiloxane(PDMS) membrane was carried out and the effect of feed concentrations and membrane thicknesses on the permeation characteristics were investigated. A solution-diffusion model is used to describe the pervaporation transport mechanism. In homogeneous PDMS membrane it appeared that the selectivities of MEK and toluene are constant, and that organic flux has a linear relationship with feed concentration. These results indicate that the coupling effects between organics were negligible. The selectivity of PDMS membranes is invariant with respect to the membrane thickness. The intrinsic membrane permeability of organic components determined by using a solution-diffusion model. Comparing with various composite type membrane, the membrane using PEG treated nonwoven fabric as sublayer showed the best performance in VOC recovery by pervaporation.

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Microstructure and Properties of Organic-Inorganic Hybrids(PDMS/SiO$_2$) Through Variations in Sol-Gel Processing (졸-겔공정의 변수조절을 통해 제조된 유기-무기복합체 (PDMS/SiO$_2$)의 미세구조와 특성)

  • Eun, Hui-Tae;Hwang, Jin-Myeong
    • Korean Journal of Materials Research
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    • v.11 no.2
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    • pp.94-103
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    • 2001
  • SiO$_2$ and PDMS/SiO$_2$ xerogels which are derived PDMS into TEOS have been synthesized by sol-gel process and controlled pore size and distribution through 2 step acid/base catalyzed processes using HCI and NH$_4$OH as a catalyst. In HCl catalyzed SiO$_2$ and PDMS/SiO$_2$ xerogels, pH and gellation time of xerogel were 2.3~2.5 and 12~13 days, respectively, and the shape of xerogel was identified to pellet type and column type. Under acidic condition of final reaction solution, the hydrolysis rate is accelerating, resulting in long gel times. The shape of xerogel is pellet type. In contrast, under less acidic condition, the condensation rate is accelerating, resulting in shorter gel times and the shape of xerogel is column type. The surface area and average Pore size were changed 400$\rightarrow$600($\m^2$/g) and 15$\rightarrow$28$\AA$, respectively, depending to the increase of the mole ratio of HCl/NH$_4$OH, and represented uniform pore size distribution. It is that all the alkoxide groups are hydrolyzed by HCl after the first step and the condensation rate is enhanced by NH$_4$OH. The regular backbone structures of silica are formed at low temperature and the uniform pores are produced by heat treatment.

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Large-strain Soft Sensors Using Elastomers Blended with Exfoliated/Fragmented Graphite Particles (탄성중합체와 박리 후 파쇄된 흑연입자 복합재를 이용한 대변형률 연성 센서)

  • Park, Sungmin;Nam, Gyungmok;Kim, Jonghun;Yoon, Sang-Hee
    • Transactions of the Korean Society of Mechanical Engineers A
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    • v.40 no.9
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    • pp.815-820
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    • 2016
  • An elastic polymer (e.g., PDMS) blended with EFG particles is a promising conductive composite for fabricating soft sensors that can detect an object's deformation up to or more than 50%. Here, we develop large-strain, sprayable soft sensors using a mixture of PDMS and EFG particles, which are used as a host elastomer and electrically conductive particles, respectively. A solution for a conductive composite mixture is prepared by the microwave-assisted graphite exfoliation, followed by ultrasonication-induced fragmentation of the exfoliated graphite and ultrasonic blending of PDMS and EFG. Using the prepared solutions for composite and pure PDMS, 1-, 2-, and 3-axis soft sensors are fabricated by airbrush stencil technique where composite mixture and pure PDMS are materials for sensing and insulating layers, respectively. We characterize the soft strain sensors after investigating the effect of PDMS/EFG wt% on mechanical compliance and electrical conductance of the conductive composite.