• Title/Summary/Keyword: rheology characteristics

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Electrorheological characteristics of poly(o-ethoxy)aniline nanocomposite

  • Sung Jun Hee;Choi Hyoung Jin
    • Korea-Australia Rheology Journal
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    • v.16 no.4
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    • pp.193-199
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    • 2004
  • Poly(o-ethoxy)aniline (PEOA)/organoclay nanocomposite was prepared via a solvent intercalation using chloroform as a cosolvent with organically modified montmorillonite (OMMT) clay. The PEOA initially synthesized from a chemical oxidation polymerization in an acidic condition at pH = 1 was intercalated into interlayers of the clay with $25\;wt{\%}$ clay content. Electrical conductivity of the PEOA/OMMT nano­composite was found to be controlled via the intercalating process. The synthesized PEOA/OMMT nano­composite was characterized via an XRD and a TGA, and then adopted as an electrorheological (ER) material. The PEOA/OMMT synthesized with controllable electrical conductivity without a dedoping pro­cess was found to show typical ER characteristics possessing a yield stress from both steady state and dynamic measurements under an applied electric field.

Numerical analysis of viscoelastic flows in a channel obstructed by an asymmetric array of obstacles

  • Kwon, Young-Don
    • Korea-Australia Rheology Journal
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    • v.18 no.3
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    • pp.161-167
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    • 2006
  • This study presents results on the numerical simulation of Newtonian and non-Newtonian flow in a channel obstructed by an asymmetric array of obstacles for clarifying the descriptive ability of current non-Newtonian constitutive equations. Jones and Walters (1989) have performed the corresponding experiment that clearly demonstrates the characteristic difference among the flow patterns of the various liquids. In order to appropriately account for flow properties, the Navier-Stokes, the Carreau viscous and the Leonov equations are employed for Newtonian, shear thinning and extension hardening liquids, respectively. Making use of the tensor-logarithmic formulation of the Leonov model in the computational scheme, we have obtained stable solutions up to relatively high Deborah numbers. The peculiar characteristics of the non-Newtonian liquids such as shear thinning and extension hardening seem to be properly illustrated by the flow modeling. In our opinion, the results show the possibility of current constitutive modeling to appropriately describe non-Newtonian flow phenomena at least qualitatively, even though the model parameters specified for the current computation do not precisely represent material characteristics.

The Rheological Behavior and Dispersion Properties of Millbase for LCD Colorfilters (LCD Colorfilter용(用) Millbase의 분산특성과 레올로지 거동)

  • Na, Dae-Yup;Jung, Il-Bong;Nam, Su-Yong;Yoo, Choon-Woo;Choi, Yong-Jung
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.20 no.5
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    • pp.450-455
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    • 2007
  • LCD color filters have been manufactured in a process called photolithography to date, but various printing methods have been studied currently in response to the trend of low-end LCD panels. Direct Printing Process is a suitable fabrication technique to develope pigment components whose dimensions are in nano. The success of this process depends on the systematic preparation of pigment millbase. Conventional millbase dispersions are constituted of the organic pigments, monomer, dispersant and solvents. An experimental study on the rheology of millbase dispersions is presented. Subsequently, this thesis attempts to find out the dispersive characteristics as well as the selection of pigments, monomers and dispersants in the part of millbase among the stages of manufacturing LCD color filters using the direct printing methods. The dispersive characteristics were shown through analytic devices such as PSA, Rheometer, etc.

Prediction of Pumping Friction Resistance Coefficient in Pipe Influenced by Concrete Rheology Properties (콘크리트의 레올로지 특성에 따른 펌핑관내 마찰저항계수의 예측에 관한 연구)

  • Kim, Hyung-Rae;Cho, Ho-Kyoo;Kim, Jung-Chul;Lee, Kewn-Chu
    • Journal of the Korea Institute of Building Construction
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    • v.14 no.2
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    • pp.118-126
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    • 2014
  • The establishment of the technology for evaluating friction resistance and pipe pressure and the relation of the fluid characteristics and pumpability of concrete is essential for concrete pumping performance for the rapid construction of super-tall buildings. In this study, a quantitative evaluation of concrete fluid characteristics and surface friction resistance was performed, applying different concrete mix proportions and pumping conditions. To achieve this, we developed a temporary horizontal pumping evaluation system to measure pipe pressure and surface friction characteristics, and performed an experiment to investigate the relations between concrete rheology characteristics and friction resistance in pipe. The experiment found that in terms of the rheology characteristics, plastic viscosity was reduced remarkably after pumping. As well, high regression between the surface friction and pressure gradient was confirmed. This means that it is possible to evaluate the friction resistance between concrete and pipe by means of a pumping system that includes a frictional resistance testing pipe. In addition, high regression between the plastic viscosity of concrete after pumping and friction resistance coefficient was confirmed. Finally, it is considered that pumping pressure can be predicted using the friction resistance coefficient derived in this study, and it has high regression.

Effects of Maesil Extract on the Quality Characteristics of Yellow Layer Cake(I) - Rheology Characteristics of Cake Batter - (매실 엑기스 첨가가 Yellow Layer Cake의 품질 특성에 미치는 영향(I) - 케이크 반죽의 리올로지 특성 -)

  • Choi, Bong-Soon;Nam, Yoon-Joo;Hwang, Seong-Yun;Kang, Kun-Og
    • Journal of the East Asian Society of Dietary Life
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    • v.18 no.4
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    • pp.539-546
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    • 2008
  • This study was conducted in order to investigate the effects of maesil extract on medium and cake flour using the falling number and RVA tests, as well as farinography, and alveography. The maesil extract were added on the medium and cake flour bases, 3% and 5% each. The falling numbers of the medium and cake flour with maesil extract were increased due to alteration of the protein in the flour. Analysis of the RVA characteristics showed that the addition of maesil extract did not have a significant effect on the initial pasting temperature. Peak viscosity, holding strength, final viscosity, and the breakdown and setback values of the medium flour were not consistent, but those of the cake flour decreased. Farinography demonstrated that the addition of maesil extract decreased water absorption and improved the stability of the medium and cake flour. The characteristics of the alveogram showed that the addition of maesil extract increased the extensibility and swelling index. Based on the experimental data, the processing rheology may be good when using maesil extract to make yellow layer cake.

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Effect of Wheat Germ on the Quality Characteristics of Sangwhabyung - Rheology Characteristics of Medium Flour with Wheat Germ - (밀 배아 첨가가 상화병의 품질 특성에 미치는 영향(I) - 밀 배아 첨가 소맥분의 리올로지 특성 -)

  • Choi, Bong-Soon;Hwang, Seong-Yun;Kang, Kun-Og
    • Journal of the East Asian Society of Dietary Life
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    • v.19 no.4
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    • pp.641-649
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    • 2009
  • This study was conducted to investigate the effects of wheat germ on medium flour using falling number and RVA tests, as well as farinogram and rheofermentometer analyses. The wheat germ was added to the medium flour on a 3, 5, and 7% basis. Falling numbers increased with increasing amounts of wheat germ. Analysis of the RVA characteristics showed that the wheat germ additions did not have significant effects on the initial pasting temperature. In the farinogram, water absorption decreased with an increasing amount of wheat germ. Also, development time was longest in the control group and shortest in the group with the highest addition of wheat germ. The results of the effects of added wheat germ on fermentation by rheofermentometer analysis showed that the H'm value reached a maximum height at 3%. Finally, the volume of $CO_2$ lost was increased whereas the retention coefficient was decreased.

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Rheology Properties of Ultrafine Blast Furnace Slag Replacement Cement Paste on Gypsum Volume Fraction (석고 혼입율에 따른 초미분 고로슬래그 치환 시멘트 페이스트의 유동특성)

  • Lee, Gun-Young;Lee, Gun-Cheol;Choi, Jung-Gu;Kim, Woo-Jae
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2014.11a
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    • pp.178-179
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    • 2014
  • The fine blast furnace slag is widely used as the admixture as it helps to increase the fluidity, long term strength of the concrete but decrease the heat of hydration. In case of the fine blast furnace slag, if the fineness of the slag is enhanced with the addition of gypsum to the concrete for the supplement of low strength in early stage and the facilitation of the initial hydration, the quality of the concrete is expected to change depending on the volume of the gypsum volume fraction. But, up to now the study on the fine blast furnace slag has only focused on the effect of fineness, replacement and admixture and there have been almost no studies on the effect of the gypsum volume fraction. Accordingly, this study focuses on what effect the gypsum volume fraction would make on the fluidity characteristics of the ultrafine furnace slag cement paste by using the rheology properties.

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EFFEECTS OF NON-NEWTONIAN FLUID MODEL ON HEMODYNAMICS IN CEREBRAL SACCULAR ANEURYSMS (낭상 뇌동맥류 혈류유동에서 비뉴우토니안 유체 모델의 영향)

  • Park, J.S.;Lee, S.W.
    • Journal of computational fluids engineering
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    • v.16 no.2
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    • pp.81-87
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    • 2011
  • The importance of shear thinning non-Newtonian blood rheology on the hemodynamic characteristics of idealized cerebral saccular aneurysms were investigated by carrying out CFD simulations assuming two different non-Newtonian rheology models (Carreau and Ballyk models). To explore effects of vessel curvature, a straight and a curved vessel geometry were considered. The wall shear stress(WSS), relative residence time(RRT) and velocity distribution were compared at the different phases of cardiac cycle. As expected, blood entered the aneurysm at the distal neck and created large vortex in both aneurysms, but with higher momentum on the curved vessel. Hemodynamic characteristics such as WSS, and RRT exhibited only minor effects by choice of different rheological models although Ballyk model produced relatively higher effects. We conclude that the assumption of Newtonian fluid is reasonable for studies aimed at quantifying the hemodynamic characteristics, in particular, WSS-based parameters, considering the current accuracy level of medical image of cerebral aneurysm.

Dilutant flow characteristics model of coarse particle suspensions with uniform size distribution

  • Ookawara, Shinichi;Ogawa, Kohei
    • Korea-Australia Rheology Journal
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    • v.15 no.1
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    • pp.35-41
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    • 2003
  • It is expected that particle size distribution of any portion obtained through screening, is of more uniform than that of the original mixture, typically following such as log-normal, Rosin-Rammler distributions and so on. In this study, therefore, a new relation between parameters of the uniform distribution and flow characteristics of the coarse particle suspensions is derived based on the continuous polydisperse model (Ookawara and Ogawa, 2002b), which is derived from the discrete polydisperse model (Ookawara and Ogawa,2002a). The derived model equation predicts a linear increase of viscosity with shear rate, viz., dilutant flow characteristics. Further, the increase of viscosity is expected to be proportional to the square of volume fraction of particles, and to show the linear dependency on density and average diameter of particles. It is also shown that the uniform distribution model includes additional term that expresses the effect of distribution width. For verification of the model, the experimental results of Clarke (1967) are cited as well as in our previous work for the monodisperse model (Ookawara and Ogawa,2000) since most parameters were varied independently in his work. It is suggested that the newly introduced term expands the applicable range compared with the monodisperse model.

Measurement of cell aggregation characteristics by analysis of laser-backscattering in a microfluidic rheometry

  • Shin, Se-Hyun;Hou, J.X.;Suh, Jang-Soo
    • Korea-Australia Rheology Journal
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    • v.19 no.2
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    • pp.61-66
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    • 2007
  • The aggregation characteristics of red blood cells (RBCs) are known as important factors in the microvascular flow system, and increased RBC aggregation has been observed in various pathological diseases, such as thrombosis and myocardial infarction. This paper describes a simple microfluidic device for measuring the RBC aggregation by integrating a microfluidic slit rheometry and laser-backscattering technique. While a decreasing-pressure mechanism was applied to the microfluidic rheometry, a syllectogram (the light intensity versus time) showed an initial increase and a peak caused by the high shear stress-induced disaggregation, immediately followed by a decrease in the light intensity due to RBC aggregation. The critical shear stress (CST) corresponding to the peak intensity was examined as a new index of the RBC aggregation characteristics. The CST of RBCs increased with increasing aggregation-dominating protein (fibrinogen) in the blood plasma. The essential feature of this design was the combination of the rheometric-optic characterization of RBC aggregation with a microfluidic chip, which may potentially allow cell aggregation measurements to be easily carried out in a clinical setting.