• 제목/요약/키워드: recycle water

검색결과 249건 처리시간 0.023초

초임계 유체를 이용한 폐페놀수지로부터 카본입자 재활용 연구 (Recycling of Carbon Particle from Phenol Resin Waste using Supercritical Fluid)

  • 조항규;임종성
    • Korean Chemical Engineering Research
    • /
    • 제55권2호
    • /
    • pp.220-224
    • /
    • 2017
  • 본 논문에서는 전기절연판이나 접착제로 널리 사용되는 페놀수지를 초임계 유체를 이용하여 카본입자로 재활용 하는방법을 연구 하였다. 폐페놀수지는 불융/불용 특성으로 대부분 매립하거나 소각처리하고 있으며, 환경오염 방지차원에서 페놀수지의 새로운 재활용 기술 개발이 매우 필요한 실정이다. 폐페놀수지를 재활용하기 위해 다양한 아/초임계 용매(에탄올, 아세톤, 물, 메탄올)를 선정하여 처리하였다. 그 결과 기존의 카본입자의 제조 방법들 보다 훨씬 낮은 온도 조건($350{\sim}380^{\circ}C$)에서 카본입자를 제조할 수 있었다. 본 연구에서는 재활용된 카본입자의 FT-IR, XRD, TGA, SEM, EDS 분석을 통하여 반응용매에 따른 카본입자의 특성을 고찰하였으며, 모든 용매에 대해 동일한 화학구조 및 비정질 구조를 가지는 카본입자를 제조 할 수 있었다.

Influence of Compost Recycling and Magnesium Supplement on Physical and Chemical Traits of Animal Manure Compost

  • Lee, Jin-Eui;Kwag, Jung-Hoon;Ra, Chang-Six
    • Journal of Animal Science and Technology
    • /
    • 제52권6호
    • /
    • pp.513-519
    • /
    • 2010
  • A series of experiments were performed to study the influence of the following parameters on the physical traits and composition of swine manure compost: (1) addition of magnesium (Mg) at a molar ratio of 1.2 with respect to $PO_4$, and (2) reutilization of compost containing $MgNH_4PO_4{\cdot}6H_2O$ (magnesium ammonium phosphate, MAP). Three independent batch tests were conducted for replication: batch test I-control (C) and Mg added (T), batch test II-C, T and compost recycle ($T_{R1}$), and batch test III-C, T and compost recycle ($T_{R2}$). Magnesium addition and compost reutilization had no adverse effect on the degradation of organic matter. Reuse of the compost, however, had a clear effect on the total nitrogen (TN) and total phosphorus (TP) contents in the final compost. Repeated compost reutilization as a bulking material was resulted in composts rich in N and P. Upon adding the Mg supplement to the composting materials, the ortho-phosphate (OP) to TP ratio decreased due to the MAP crystallization reaction. The decrease in the OP/TP ratio and the increase in the TP content of the compost indicate that water-soluble phosphate is converted into a slow-release phosphate by the formation of crystals during composting. X-ray diffraction analysis of the irregular shaped crystals in the compost indicated that they are MAP crystals and that the crystallization of MAP begins immediately after the addition of the Mg supplement. The Mg addition to composting materials and the reutilization of compost as a bulking material would be a practical means to conserve nutrient content.

물시멘트비 및 단위수량에 따른 순환콘크리트의 강도 특성과 내구성능에 관한 실험적 연구 (An Experimental Study on the Strength Properties and Durability Performance of Recycled Concrete with Water to Cement Ratio and Unit Water Content)

  • 김영선;김정진;석원균;이주호;김규용
    • 한국건설순환자원학회논문집
    • /
    • 제6권3호
    • /
    • pp.88-93
    • /
    • 2011
  • 천연골재의 고갈 및 환경규제에 의한 건설용 잔골재의 수급불균형 문제를 해결하기 위해 폐기콘크리트로부터 생산된 순환잔골재의 적용성을 위한 연구들이 수행되어 왔다. 본 연구의 목적은 W/C 및 단위수량의 변화에 따른 순환잔골재를 사용한 콘크리트의 역학적 특성 및 내구성능에 관한 이해를 높이는 것이다. 또한, 순환콘크리트의 구조적 적용을 위한 기초자료를 제시하는데 의미가 있다. 특히, 순환잔골재를 100% 대체한 순환콘크리트에 대하여 W/C 및 단위수량의 변화에 따른 영향은 공기량, 슬럼프, 응결시간, 압축강도, 인장강도, 탄산화 및 염화물 침투와 같은 항목에 대한 시험결과에 의해 분석 제시되었다.

  • PDF

A Study on Characteristics of Water Quality in Wastewater according to the Washing of Municipal Solid Waste Incinerator (MSWI) Ash

  • Byun, Mi-Young;Kim, Hyung-Seok;Ahn, Ji-Whan;Kim, Hwan
    • 대한전자공학회:학술대회논문집
    • /
    • 대한전자공학회 2001년도 The 6th International Symposium of East Asian Resources Recycling Technology
    • /
    • pp.296-300
    • /
    • 2001
  • In order to recycle the incineration ash (bottom ash and fly ash) generated from the incineration of municipal waste for a cement material, salts as well as heavy metal should be removed by the stabilization treatment. Most of these heavy metal and over 80% of salts are removed by a washing as a pre-treatment. However, wastewater which is another pollutant is generated by a washing, then proper treatment should be developed. First the characteristics of incineration ashes collected from two domestic full-sized incinerators were investigated and removal rate of salts and heavy metals from them also studied. The wastewater quality was compared to the criteria of the regulation by analyzing the characteristics of generated wastewater during the washing of incineration ash as a condition of liquid/solid ratio. Also, we tried to used this experimental results for the basic data to develop proper processing technique of municipal waste.

  • PDF

The role of macrophytes in wetland ecosystems

  • Rejmankova, Eliska
    • Journal of Ecology and Environment
    • /
    • 제34권4호
    • /
    • pp.333-345
    • /
    • 2011
  • Aquatic macrophytes, often also called hydrophytes, are key components of aquatic and wetland ecosystems. This review is to briefly summarizes various macrophyte classifications, and covers numerous aspects of macrophytes' role in wetland ecosystems, namely in nutrient cycling. The most widely accepted macrophyte classification differentiates between freely floating macrophytes and those attached to the substrate, with the attached, or rooted macrophytes further divided into three categories: floating-leaved, submerged and emergent. Biogeochemical processes in the water column and sediments are to a large extent influenced by the type of macrophytes. Macrophytes vary in their biomass production, capability to recycle nutrients, and impacts on the rhizosphere by release of oxygen and organic carbon, as well as their capability to serve as a conduit for methane. With increasing eutrophication, the species diversity of wetland macrophytes generally declines, and the speciose communities are being replaced by monoculture-forming strong competitors. A similar situation often happens with invasive species. The roles of macrophytes and sediment microorganisms in wetland ecosystems are closely connected and should be studied simultaneously rather than in isolation.

Pilot Plant Study on Biological Nutrient Removal of Wastewater

  • Ahn, Sang-Jin;Kim, Geon-Heung;Ahn, Bok-Kyoun
    • Korean Journal of Hydrosciences
    • /
    • 제1권
    • /
    • pp.99-106
    • /
    • 1990
  • An extensive biological nutrient removal pilot plant study of anoxic/anaerobic/ aerobic treatment process was conducted to eastblish an optimum operational mode using primary dffluent. Two operational modes, (1) Qr/Q was 3.0 and maintaining EMLSS of 3100 mg/L in which the best operational results were obtained from previous bench scale study using synthetic wastewater (2) Qr/Q was 0.5 and EMLSS of 2200 mg/L which was compatible with the main plant, were Compared and evaluated for removal of nitrogen and/or phosphorous under field conditions. The nitrogen removal increased with increasing recycle ratios, but the phosphorous removal revealed more consistent results with 83percent removal efficiency in the second mode compared with 80 percent in the first mode. Above all, the two modes equally showed good BOD and nitrogen removals by nitrification-denitrification processes. It was also observed that no scum formed in the pilot plant and the sludge exhibited excellent settling characteristic all the time. The modified biological nutrient removal train can be adopted to the main plant without any major changes of their operational modes.

  • PDF

폐콘크리트 미분말의 골재함유량에 따른 재생시멘트의 물성 (Properties of Recycled Cement by Content of Fine Aggregate from Waste Concrete Powder)

  • 배종건;권은희;안재철;박동천;강병희
    • 한국건축시공학회:학술대회논문집
    • /
    • 한국건축시공학회 2012년도 춘계 학술논문 발표대회
    • /
    • pp.101-102
    • /
    • 2012
  • A policy for recycling waste concrete has been extensively studied, but it is still lacking to recycle and reuse as a cementitious powder, and the property has big different depending on the aggregate rates. In this study, the amount of cement powder according to the internal properties of the aggregate were mixed. From as a result, Concrete Powder to play inside the aggregate composition of the cement composition CaO rigs that causes loss of power and strength reduction due to rising real water cement ratio will affect large.

  • PDF

폐석고의 공학적 특성 및 환경적 영향 분석에 관한 연구 (Geotechnical Properties and Environmental Effect of Waste Gymsum)

  • 신은철;오영인;이희재
    • 한국지하수토양환경학회:학술대회논문집
    • /
    • 한국지하수토양환경학회 1999년도 추계학술발표회
    • /
    • pp.90-94
    • /
    • 1999
  • Waste gypsum is produced about 2.6million tons per year as a by-product in the process of TiO$_2$production. Geotechnical properties such as natural water content, specific gravity, Atterberg limits were determined to figure out the engineering characteristics waste gypsum. Grain-size distribution, compaction, CBR tests, and unconfined compression test for various mixing ratios between waste gypsum and decomposed granite soil 8t dredged soil. The environmentally adverse effect for mixed specimen with waste gypsum is far below than those of regulatory requirement.

  • PDF

ELECTROCHEMICAL PROCESSING OF USED NUCLEAR FUEL

  • Goff, K.M.;Wass, J.C.;Marsden, K.C.;Teske, G.M.
    • Nuclear Engineering and Technology
    • /
    • 제43권4호
    • /
    • pp.335-342
    • /
    • 2011
  • As part of the Department of Energy's Fuel Cycle Research and Development Program an electrochemical technology employing molten salts is being developed for recycle of metallic fast reactor fuel and treatment of light water reactor oxide fuel to produce a feed for fast reactors. This technology has been deployed for treatment of used fuel from the Experimental Breeder Reactor II (EBR-II) in the Fuel Conditioning Facility, located at the Materials and Fuel Complex of Idaho National Laboratory. This process is based on dry (non-aqueous) technologies that have been developed and demonstrated since the 1960s. These technologies offer potential advantages compared to traditional aqueous separations including: compactness, resistance to radiation effects, criticality control benefits, compatibility with advanced fuel types, and ability to produce low purity products. This paper will summarize the status of electrochemical development and demonstration activities with used nuclear fuel, including preparation of associated high-level waste forms.

FRP폐기물 재활용을 위한 미생물 담체 제조 기술 개발 (A Manufacturing Technology Development of Microbe Carrier)

  • 김용섭
    • 대한조선학회논문집
    • /
    • 제41권1호
    • /
    • pp.82-87
    • /
    • 2004
  • The purpose of this paper is to obtain the data for manufacturing of microbe carriers as a method of FRP waste recycling technology. Since FRP waste is polymer, the experiment of the thermogravity analyzing was carried out to find thermal behavior. After that, microbe carriers were prepared from waste FRP powder, which had been decomposed, milled, and mixed with clay as a binder and CaCO3 as a flux and a loaming agent, respectively. finally it was made by filing of the sample up to 1,05$0^{\circ}C$. It was investigated how the variation of the additives and firing temperature effect apparent density, water absorption and micro structure.