• Title/Summary/Keyword: quantum phase

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Quantum-Chemical Studies on Cis-Trans Isomerization of Ac-Pro-NHMe and Its $C^\delta$-Methylated Derivatives

  • Jhon, Jong-Suk;Kang, Young-Kee
    • Proceedings of the Korean Biophysical Society Conference
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    • 1999.06a
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    • pp.38-38
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    • 1999
  • Calculations on conformational free energies of Ac-Pro-NHMe and its $C^{\delta}$-methylated derivatives have been carried out with the higher levels of quantum-chemical methods to figure out the cis-trans isomerization of the imide bond of proline and $C^{\delta}$-methylated prolines in the gas phase and in solution.(omitted)hase and in solution.(omitted)

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Role of Open Channels in Overlapping Resonances Studied by Multichannel Quantum Defect Theory in Systems Involving 2 Nondegenerate Closed and Many Open Channels

  • Lee, Chun-Woo
    • Bulletin of the Korean Chemical Society
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    • v.31 no.11
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    • pp.3201-3211
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    • 2010
  • Previous work on the phase-shifted version of the multichannel quantum-defect theory (MQDT) for a system involving 2 closed and many open channels (Lee, C.-W. Bull. Korean Chem. Soc. 2010, 31, 1669) was extended to obtain the formulae of the spectral shape parameters with the structure of a pole extracted explicitly for general cases only limited by 2 non-degenerate closed channels. The theory was applied to the narrow $6p_{1/2,3/2}np$ J = 1 autoionizing Rydberg series in barium perturbed by the $6p_{3/2}nf$ states obtained by de Graaff et al.

Multichannel Quantum Defect Study of the Perturber's Effect on the Overlapping Resonances in Rydberg Series for the Systems Involving 2 Closed and Many Open Channels

  • Lee, Chun-Woo
    • Bulletin of the Korean Chemical Society
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    • v.31 no.6
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    • pp.1669-1680
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    • 2010
  • The phase-shifted version of the multichannel quantum-defect theory (MQDT) was reformulated by disentangling the interloper spectrum from the perturbed dense Rydberg series for a systems involving 2 closed and more than 1 open channel. The theory was applied successfully to Martins and Zimmermann's photoionization spectra of the Rydberg series Cu I $3d^9\;4s(^1D_2)\;nd^2G_{9/2}$ perturbed by the interloper, $3d^9\;4p^2\;^4F_{9/2}$, for which Cohen's 4 channel QDT had failed. The zero surface graphic of the perturbed Fano's asymmetry parameter q of the autoionization spectrum of dense Rydberg series by the interloper was determined by only two parameters for this system. It was used as a map to trace the transformation route of the 3 channel autoionization spectra to the 4 channel spectra when the channel coupling of the closed channels with a newly added open channel was turned on progressively.

Decoupling of Background and Resonance Scatterings in Multichannel Quantum Defect Theory and Extraction of Dynamic Parameters from Lu-Fano Plot

  • Lee, Chun-Woo
    • Bulletin of the Korean Chemical Society
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    • v.30 no.4
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    • pp.891-896
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    • 2009
  • Giusti-Suzor and Fano introduced translations of the scales of Lu-Fano plots by phase renormalization in order to decouple the intra- and inter-channel couplings in multichannel quantum defect theory (MQDT). Their theory was further developed by others to deal with systems involving a larger number of channels. In different directions, MQDT was reformulated into forms with a one-to-one correspondence to those in Fano's configuration mixing theory of resonance for photofragmentation processes involving one closed and many open channels. In this study, the theory was further developed to fully reveal the coupling nature, decoupling of the background and resonance scattering in physical scattering matrices as well as to further extract the dynamic parameters undiscovered by Fano and his colleagues. This theory was applied to the photoabsorption spectrum of $H_2$ observed by Herzberg's group.

The Phase Sensitivity of the Coincidence Detection in one Output Port of a Mach-Zehnder Interferometer

  • Shin Harim;Kim Henoh;Park Goodong;Kim Taesoo
    • Journal of the Optical Society of Korea
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    • v.9 no.4
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    • pp.169-172
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    • 2005
  • The phase sensitivity of the coincidence detection in one output port of a Mach-Zehnder interferometer is analysed for twin Fock state inputs. Firstly, the ideal detectors with quantum efficiency of unity are assumed for the detection of the output photons. The sensitivity is found out to be independent of the photon number of input light, which means that the Heisenberg limit cannot be reached in the coincidence detection even with ideal detectors. Secondly, the practical detectors with quantum efficiencies less than unity are discussed.

A Study on Characteristics of Null Pattern Synthesis Algorithm Using Quantum-inspired Evolutionary Algorithm (양자화 진화알고리즘을 적용한 널 패턴합성 알고리즘의 특성 연구)

  • Seo, Jongwoo;Park, Dongchul
    • Journal of the Korea Institute of Military Science and Technology
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    • v.19 no.4
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    • pp.492-499
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    • 2016
  • Null pattern synthesis method using the Quantum-inspired Evolutionary Algorithm(QEA) is described in this study. A $12{\times}12$ planar array antenna is considered and each element of the array antenna is controlled by 6-bit phase shifter. The maximum number of iteration of 500 is used in simulation and the rotation angle for updating Q-bit individuals is determined to make the individual converge to the best solution and is summarized in a look-up table. In this study we showed that QEA can satisfactorily synthesize the null pattern using smaller number of individuals compared with the conventional Genetic Algorithm.

Aqueous synthesis of quantum dots using functionalized ionic liquid (이온성 액체를 이용한 수계 양자 점 합성)

  • Choi, Suk-Young;Kim, Tae-Young;Suh, Kwang-S.
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2010.06a
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    • pp.254-254
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    • 2010
  • We report aqueous synthesis of cadmium telluride (CdTe) quantum dots(QDs) using imidazolium-based ionic liquids with various functional groups. The functinalized ionic liquids were designed to have thiol groups, and then phase transfer with aqueous or organic solvents can be adjusted by changing side chain lengths of the cation and the choice of anion. The quantum yield was obtained IL-functionalized CdTe QDs reached up to 40% by post-treatment method.

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Thermal Aging Embrittlement of High Chromium Oxide Dispersion Strengthened Steels

  • Lee, J.S.;Kim, I.S.;Jang, C.H.;Kimura, A.;Kim, B.G.;Choo, K.N.;Choo, Y.S.;Kang, Y.H.
    • Proceedings of the Korean Nuclear Society Conference
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    • 2005.05a
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    • pp.471-472
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    • 2005
  • After thermal aging treatment at 693 K for 322 hours, any discernable precipitation could not be found in the $13{\sim}22$ Cr ODS steels, but showing an increase in SP-DBTT and reduction in upper shelf energy. The degree of aging embrittlement increases with Cr content such that the increases in SP-DBTT are 10, 50 and 73 K in 13, 16 and 19 Cr ODS steel, respectively. Amount of hardening also increased linearly as a function of Cr content. Based on the TEM observation, the origin of hardening must be related to the invisibly fine size of Cr-rich ${\acute{\alpha}}-phase$ (<1 nm).

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Towards searching for Majorana fermions in topological insulator nanowires

  • Kim, Hong-Seok;Doh, Yong-Joo
    • Progress in Superconductivity and Cryogenics
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    • v.21 no.1
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    • pp.6-9
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    • 2019
  • Developing a gate-tunable, scalable, and topologically-protectable supercurrent qubit and integrating it into a quantum circuit are crucial for applications in the fields of quantum information technology and topological phenomena. Here we propose that the nano-hybrid supercurrent transistors, a superconducting quantum analogue of a transistor, made of topological insulator nanowire would be a promising platform for unprecedented control of both the supercurrent magnitude and the current-phase relation by applying a voltage on a gate electrode. We believe that our experimental design will help probing Majorana state in topological insulator nanowire and establishing a solid-state platform for topological supercurrent qubit.

Charged Cluster Model as a New Paradigm of Crystal Growth

  • Nong-M. Hwang;In-D. Jeon;Kim, Doh-Y.
    • Proceedings of the Korea Association of Crystal Growth Conference
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    • 2000.06a
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    • pp.87-125
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    • 2000
  • A new paradigm of crystal growth was suggested in a charged cluster model, where charged clusters of nanometer size are suspended in the gas phase in most thin film processes and are a major flux for thin film growth. The existence of these hypothetical clusters was experimentally confirmed in the diamond and silicon CVD processes as well as in gold and tungsten evaporation. These results imply new insights as to the low pressure diamond synthesis without hydrogen, epitaxial growth, selective deposition and fabrication of quantum dots, nanometer-sized powders and nanowires or nanotubes. Based on this concept, we produced such quantum dot structures of carbon, silicon, gold and tungsten. Charged clusters land preferably on conducting substrates over on insulating substrates, resulting in selective deposition. if the behavior of selective deposition is properly controlled, charged clusters can make highly anisotropic growth, leading to nanowires or nanotubes.

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