• Title/Summary/Keyword: protection layer

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Electrochemical Characteristics in Sea Water of Al-3%Mg Arc Spray Coating Layer for Corrosion Protection with Sealing Treatment (후처리 적용에 따른 방식용 Al-3%Mg 용사코팅 층의 해수 내 전기화학적 특성)

  • Park, Il-Cho;Kim, Seong-Jong
    • The Journal of Korean Institute of Communications and Information Sciences
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    • v.40 no.5
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    • pp.974-980
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    • 2015
  • Arc thermal spray coating using Al-3%Mg thermal spray wire was carried out to prevent steel from corrosion damage under the marine environment. Post-sealing was applied to Al-3%Mg spray coating treatment using organic/inorganic composite ceramics in order to improve the corrosion resistance of the as-sprayed coating. The results of various electrochemical experiments with sealing treatment indicated that the improvement in corrosion resistance was observed due to low current density in all applied potential range during anodic and cathodic polarization experiments. Futhermore, the natural potential measurement exhibited severe potential fluctuation due to influence of micro-crack presence on the surface of sealed thermal spray coating layer. In addition, the sealed layer was easily eliminated during anodic polarization. Nevertheless, Al-3%Mg spray coating layer improved corrosion resistance by sealing treatment because the sealed coating efficiency was determined to be 92.11%, indicating the exterior environment barrier effect which is based on the Tafel analysis.

Tape-Type Liquid Leakage Film Sensor (액체누설 감지용 테이프형 필름센서)

  • Yu, D.K.;Kim, K.S.;Yub, H.K.;Han, G.H.;Jin, D.J.;Kim, J.H.;Han, S.H.;Cho, G.S.
    • Journal of the Korean Vacuum Society
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    • v.20 no.2
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    • pp.146-154
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    • 2011
  • The adhesive-tape of a liquid leak film sensor including the alarm system is developed. The sensing film is composed of three layers such as base film layer, conductive line layer, and protection film layer. The thickness of film is 300~500 um, the width is 3.55 cm, and the unit length is 200 m. On the conductive line layer, three conducting lines and one resistive line are formulated by the electronic printing method with a conducting ink of silver-nano size. When a liquid leaks for the electricity to be conducted between the conductive line and the resistive line, the position of leakage is monitored by measuring the voltage varied according to the change of resistance between two lines. The error range of sensing position of 200 m film sensor is ${\pm}1m$.

Assessment of Evaluation by Hybrid Waterproof-Roof Barrier Layer for Green System on Artificial Ground (인공지반 녹화시스템 활용을 위한 일체형 방수·방근 시트의 성능평가)

  • Oh, Chang-Won;Hong, Jong-Chul;Park, Ki-Bong
    • Journal of the Korea Institute of Building Construction
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    • v.15 no.4
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    • pp.391-396
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    • 2015
  • The demands about eco friendly space are increased as buildings are denser in downtown, and green system on the roof and the artificial ground are widely being applied. The construction of green system applies a waterproof layer, a root barrier and a protection concrete layer. Assembly of these many layers leads to a long construction term, and cause many defects. This study is to evaluate one layer-hybrid sheet which gets waterproof and root barrier performance simultaneously, which is developed to use in the new green system. As results, the performances of physical properties, durability, waterproof and root barrier not only exceeded quality standards but also showed excellent durability. In addition, mock-up test would be proceed to certify long term performance.

Study on the Compositional Characteristics of the PCS Coating Layer by Curing Treatment for the Protection of Graphite Mold Surface (흑연 금형 표면 보호용 PCS 코팅층의 열경화에 의한 조성비 조절 특성 연구)

  • Kim, Kyoung-Ho;Lee, Yoonjoo;Shin, Yun-Ji;Jeong, Seong-Min;Lee, Myung-Hyun;Bae, Si-Young
    • Journal of the Korean institute of surface engineering
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    • v.53 no.6
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    • pp.293-299
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    • 2020
  • The characteristics of the polycarbosilane (PCS)-based composite ceramic layer was studied by controlling the curing temperature. The stress at the interface of the graphite and SiOC composite layer was evaluated v ia finite element analysis. As a result, the tensile stress was released as the carbon ratio of the SiC decreases. In experiment, the SiOC layers were coated on the VDR graphite block by dip-coating process. It was revealed that the composition of Si and C was effectively adjusted depending on the curing temperature. As the solution-based process is employed, the surface roughness was reduced for the appropriate PCS curing temperature. Hence, it is expected that the cured SiOC layer can be utilized to reduce cracking and peeling of SiC ceramic composites on graphite mold by improving the interfacial stress and surface roughness.

Durability of Various Anti-Corrosive Organic Coatings in Marine Environment for Twelve Years

  • Yamamoto, Mashiro;Kajiki, Toshitaka;Kamon, Toshikuni;Yoshida, Kotaro
    • Corrosion Science and Technology
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    • v.3 no.1
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    • pp.20-25
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    • 2004
  • In order to clarify the durability of protective coatings for maritime steel structures, various anti-corrosive organic coated steel samples were exposed for twelve years in semitropical marine environment at Miyakojima Island, Okinawa, JAPAN. Samples were various organic coated steel pipes, 4.0 m in length and 150 mm in diameter. While the bare steel pipe entirely corroded in 4.5 mm thickness in four and half years, these organic coated steel pipes exhibited protective appearances after twelve-year-exposure except for the defect in the coatings. Polyethylene (PE) lining pipe exhibited a good protective performance. Urethane painted pipe was also good but some barnacles stuck to its surface. A combination of petrolatum tape and FRP cover showed sufficient corrosion resistance for steel surface. The correlation in results between exposure and laboratory acceleration test was examined. It was found that salt spray test (SST) results corresponded to rusted area of scratched portion and that adhesion change of coating layer corresponded to the rotating immersion test result. Among the on-site measured data, volume resistivity is utilized for the index of corrosion protection performance of organic coating.

A Study on the Spatial Resolution of Gas Detectors Based on EGS4 Calculations

  • Moon, B.S.;Han, S.H.;Kim, Y.K.;Chung, C.E.
    • Journal of Radiation Protection and Research
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    • v.29 no.1
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    • pp.25-31
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    • 2004
  • Results of EGS4 based calculations to study the spatial resolution of gas detectors are described. The calculations include radial distribution of electrons generated by photons of various energies penetrating into variable thickness of Ar and Xe gas layers. Given a desired spatial resolution, the maximum allowed thickness of gas layer for each energy level is determined. In order to obtain 0.1mm spatial resolution, the maximum thickness for the Ar gas is found to be 2mm for photon energies below 14keV while the optimum energy of photons for Xe gas with the same thickness is about 45keV. The results of calculations performed to compare the number of electrons generated by CsI coated micro-channel plate and the number of electrons generated by the Ar and Xe gas layers are described. The results show that the number of electrons generated by the gases is about 10 times higher than the one generated by CsI coated micro-channel plate. A few sample gray scale images generated by these calculations are included.

The Effect of Coating Thickness on the Electrochemical Properties of a Li-La-Ti-O-coated Li[Ni0.3Co0.4Mn0.3]O2 Cathode

  • Lee, Hye-Jin;Park, Yong-Joon
    • Bulletin of the Korean Chemical Society
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    • v.31 no.11
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    • pp.3233-3237
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    • 2010
  • A $Li[Ni_{0.3}Co_{0.4}Mn_{0.3}]O_2$ cathode was modified by coating with Li-La-Ti-O, and the effect of the coating thickness on their electrochemical properties was studied. The thickness of the coating on the surface of $Li[Ni_{0.3}Co_{0.4}Mn_{0.3}]O_2$ was increased by increasing the wt % of the coating material. The rate capability of the Li-La-Ti-O-coated electrode was superior to that of the pristine sample. 1- and 2-wt %-coated samples showed considerable improvement in capacity retention at high C rates. However, the rate capability of a 5-wt %-coated sample decreased. All the coated samples showed a high discharge capacity and slightly improved cyclic performance under a high cut-off voltage (4.8 V) condition. Results of a storage test confirmed that the Li-La-Ti-O coating layer was effective in suppressing the dissolution of the transition metals as it offered protection from the attack of the acidic electrolyte. In particular, the 2- and 5-wt %-coated samples showed a better protection effect than the 1-wt %-coated sample.

A Study on the Coatings for CP System in the Environment in which Thin Layer of Extremely Acidic Fluids are Formed

  • Chang, H.Y.;So, I.S.;Jin, T.F.;Kim, Y.S.;Yoo, Y.R.;Kang, M.S.
    • Corrosion Science and Technology
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    • v.5 no.1
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    • pp.5-14
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    • 2006
  • A lot of parts in FGD (Flue Gas Desulphurization) systems of fossil-fuel power plants show the environments in which are highly changeable and extremely acidic corrosive medium according to time and locations, e.g. in duct works, coolers and re-heaters etc.. These conditions are formed when system materials are immersed in fluid that flows on them or when exhausted gas is condensed into thin layered medium to contact materials of the system walls and roofs. The environments make troublesome corrosion and air pollution problems that are occurred from the leakage of the condensed solution. The frequent shut-down and repairing works of FGD systems also demand costs and low efficiencies of those facilities. In general, high corrosion resistant materials have been used to solve this problem. However, even the super alloys and Teflon linings sometimes have not been good enough to preventing corrosion. Further more, they are expensive and not easily repairable in short periods of operation stops. In this work, new technology that is effective, economical and easily repairable has proposed to solve the corrosion problems in FGD facilities. This technology contains cathodic protection, coatings and remote monitoring-controlling systems.

A Standard Test Methods of Resistance to Root Penetration for Waterproofing and Rootproofing Membrane Using Green Roof System (인공지반녹화용 멤브레인 방수 및 방근재료의 방근성능 평가 방법 제안 연구)

  • Lee, Jung-Hoon;Seon, Yun-Suk;Kwak, Kyu Sung;Oh, Sang-Keu
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2009.11a
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    • pp.141-148
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    • 2009
  • The purpose of this paper is to propose a standard test methods of resistance to root penetration for waterproofing and rootproofing membrane using green roof system. Green roof system is considered to be an important subject in construction industry for green growth project. At the same time, we have to consider the counterplan for protection the damage of waterproofing layer and concrete substrate from the penetration of plant root. But many kinds of materials for protection from root penetration are using in construction field. But the performance of those materials is not clear, and there is not test methods for the evaluation of performance. So in this paper, based on the research results of 4 institutes during four years and foreign cases, we made a standard test methods of resistance to root penetration for waterproofing and rootproofing membrane using green roof system. This test method deals with about environmental condition of laboratory, experimental facilities, kinds of plant, specimen of test, management methods, evaluation duration and documents, etc.

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Corrosion Protection Properties of Cobalt Salt for Water-Based Epoxy Coatings on 2024-T3 Aluminum Alloy

  • Thai, Thu Thuy;Trinh, Anh Truc;Pham, Gia Vu;Pham, Thi Thanh Tam;Xuan, Hoan Nguyen
    • Corrosion Science and Technology
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    • v.19 no.1
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    • pp.8-15
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    • 2020
  • In this paper, the efficiency and the inhibition mechanisms of cobalt salts (cobalt nitrate and cobalt-exchange silica Co/Si) for the corrosion protection of AA2024 were investigated in a neutral aqueous solution by using the electrochemical impedance spectroscopy (EIS) and polarization curves. The experimental measurements suggest that cobalt cation plays a role as a cathodic inhibitor. The efficiency of cobalt cation was important at the concentration range from 0.001 to 0.01 M. The formation of precipitates of oxides/hydroxides of cobalt on the surface at low inhibitor concentration was confirmed by the Scanning Electron Microscopy/Energy Dispersive X-Ray Spectroscopy (SEM/EDS) analysis. EIS measurements were also conducted for the AA2024 surface covered by water-based epoxy coating comprising Co/Si salt. The results obtained from exposure in the electrolyte demonstrated the improvement of the barrier and inhibition properties of the coating exposed in the electrolyte solution for a lengthy time. The SEM/EDS analysis in artificial scribes of the coating after salt spray testing revealed the release of cobalt cations in the coating defect to induce the barrier layer on the exposed AA2024 substrate.