• Korean Journal of Materials Research
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• v.27 no.4
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• pp.199-205
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• 2017

In this study, (3,4-epoxycyclohexane)methyl 3,4-epoxycyclohexylcarboxylate acrylate was synthesized by reacting (3,4-epoxycyclohexane)methyl 3,4-epoxycyclohexylcarboxylate with acrylic acid to minimize hardening shrinkage and to improve heat resistance, which are known as disadvantages of photopolymers for 3D printing application. Urethane acrylate was synthesized by reacting 1,3,5-triazine-2,4,6-triamino alcohol, 2-hexylethyl acrylate, and isophorone diisocyanate in order to improve the mechanical properties without deteriorating the heat resistance. The physical properties before and after the synthesis of the acrylate and the mechanical properties when the urethane acrylate was applied were investigated. The reaction progress of the composite was examined by FTIR and $^{13}C$ NMR. The heat deflection temperature, flexural strength, and surface hardness of the molding were measured. The curing behavior by Photo-DSC ultraviolet irradiation was also examined.

• Journal of the Korean Graphic Arts Communication Society
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• v.28 no.2
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• pp.1-11
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• 2010

The physicochemical characteristics, adhesion power, and conservation of imported tapes repairing documents that consisted of adhesive, carrier, and masking were investigated. Materials related to pressure sensitive adhesive produced in domestic companies were examined also. And then, the performance evaluation of prototype manufactured in our laboratory was undertaken. Both the pressure sensitive tapes were compared. The polyacrylate of adhesive agents such as polyacrylate, starch, Glue, and PVA of imported tapes was best. The adhesion strength, power, reversibility, and stability (deterioration) of imported tapes were analyzed. By comparing results of imported tapes, two adhesive agents were selected finally. The carriers of imported tapes are made of one of papers, cotton sheets, and felts. Major carrier material was a paper. The jutes, conifers, and hardwoods were main ingredient of papers. The durability of Hangi($18{\pm}2g/m^2$) was one and half times superior to imported one.

• Journal of Powder Materials
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• v.29 no.1
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• pp.28-33
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• 2022

Aluminum-based powders have attracted attention as key materials for 3D printing owing to their low density, high specific strength, high corrosion resistance, and formability. This study describes the effects of TiC addition on the microstructure of the A6013 alloy. The alloy powder was successfully prepared by gas atomization and further densified using an extrusion process. We have carried out energy dispersive X-ray spectrometry (EDS) and electron backscatter diffraction (EBSD) using scanning electron microscopy (SEM) in order to investigate the effect of TiC addition on the microstructure and texture evolution of the A6013 alloy. The atomized A6013-xTiC alloy powder is fine and spherical, with an initial powder size distribution of approximately 73 ㎛ which decreases to 12.5, 13.9, 10.8, and 10.0 ㎛ with increments in the amount of TiC.

• Textile Coloration and Finishing
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• v.34 no.1
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• pp.10-19
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• 2022

Humectants are chemical compounds which added to water based pigment inks for DTP (Digital Textile Printing) to prevent evaporation of water. The humectants usually have diol or triol type chemical structures and their -OH groups have possibility to react with functional groups of the binder polymers, such as ester, carboxylic acid, and urethane groups, acting as a crosslinking agent. The crosslinking reactions between polymer binders and humectants in inks can affect touch of the printed fabrics. In this regard, this study aims to investigate effect of chemical structures and added amounts of humectants in pigment ink on touch of dyed fabrics by using 1,6-hexanediol, ethylene glycol, diethylene glycol, and 1,4-buthanediol with various amounts added to the mixture of a black pigment and a polyurethane type binder. Then, color, rubbing strength, touch of the fabrics dyed with the prepared pigment inks were evaluated.

• Proceedings of the Korean Institute of Building Construction Conference
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• 2022.04a
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• pp.245-246
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• 2022

Recently, research on the self-healing of concrete using bacteria has been actively conducted. The self-healing method using bacteria has a low self-healing rate and the surrounding environment of the fracture site is very important. A previous study to solve this problem involves the manufacture of capsules using 3D printing. Fracture position control was an important topic in 3D printing-based capsules. In this study, to compensate for the shortcomings of existing studies, a capsule capable of selective destruction location control was produced using PDMS-based molds that are not restricted by the environment. Resin capsules were prepared for each part using several molds and a bonding surface was arranged. In order to verify this on the bonding surface, fracture strength and wave unit values were analyzed through a three-way compression experiment. It can be seen that as the curing time increases, the deviation between samples decreases. In addition, through experiments, it was confirmed that the junction surface and wave unit values coincide in all three directions. It can be used for self-healing research using various solutions.

• Journal of Powder Materials
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• v.30 no.3
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• pp.223-232
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• 2023

Metal additive manufacturing (AM) has transformed conventional manufacturing processes by offering unprecedented opportunities for design innovation, reduced lead times, and cost-effective production. Aluminum alloy, a material used in metal 3D printing, is a representative lightweight structural material known for its high specific strength and corrosion resistance. Consequently, there is an increasing demand for 3D printed aluminum alloy components across industries, including aerospace, transportation, and consumer goods. To meet this demand, research on alloys and process conditions that satisfy the specific requirement of each industry is necessary. However, 3D printing processes exhibit different behaviors of alloy elements owing to rapid thermal dynamics, making it challenging to predict the microstructure and properties. In this study, we gathered published data on the relationship between alloy composition, processing conditions, and properties. Furthermore, we conducted a sensitivity analysis on the effects of the process variables on the density and hardness of aluminum alloys used in additive manufacturing.

• Journal of Powder Materials
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• v.30 no.3
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• pp.255-261
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• 2023

Aluminum alloys are widely utilized in diverse industries, such as automobiles, aerospace, and architecture, owing to their high specific strength and resistance to oxidation. However, to meet the increasing demands of the industry, it is necessary to design new aluminum alloys with excellent properties. Thus, a new method is required to efficiently test additively manufactured aluminum alloys with various compositions within a short period during the alloy design process. In this study, a combinatory approach using a direct energy deposition system for metal 3D printing process with a dual feeder was employed. Two types of aluminum alloy powders, namely Al6061 and Al-12Cu, were utilized for the combinatory test conducted through 3D printing. Twelve types of Al-Si-Cu-Mg alloys were manufactured during this combinatory test, and the relationship between their microstructures and properties was investigated.

• The Journal of Advanced Prosthodontics
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• v.14 no.4
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• pp.262-272
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• 2022

PURPOSE. This study aimed to analyze the shear bond strength between the 3D-printed denture base and the chairside relining material, according to the surface treatment. MATERIALS AND METHODS. Cylindrical specimens were prepared using DENTCA Denture Base II. The experimental groups were divided into 6 (n = 10): no surface treatment (C), Tokuyama Rebase II Normal adhesive (A), sandblasting (P), sandblasting and adhesive (PA), sandblasting and silane (PS), and the Rocatec system (PPS). After bonding the chairside relining material to the center of the specimens in a cylindrical shape, they were stored in distilled water for 24 hours. Shear bond strength was measured using a universal testing machine, and failure mode was analyzed with a scanning electron microscope. Shear bond strength values were analyzed using one-way analysis of variance, and Tukey's honest significant difference test was used for post-hoc analysis (P < .05). RESULTS. Group PPS exhibited significantly higher shear bond strength than all other groups. Groups P and PA displayed significantly higher bond strengths than the control group. There were no significant differences between groups PS and A compared to the control group. Regarding the failure mode, adhesive failure occurred primarily in groups C and A, and mixed failure mainly in groups P, PA, PS, and PPS. CONCLUSION. The shear bond strength between the 3D-printed denture base and the chairside relining material exhibited significant differences according to the surface treatment methods. It is believed that excellent adhesive strength will be obtained when the Rocatec system is applied to 3D-printed dentures in clinical practice.

• Journal of the Korean Society of Industry Convergence
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• v.27 no.2_2
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• pp.389-395
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• 2024

The purpose of this study was to evaluate the effect of different washing solvents and washing methods on the flexural strength of 3D printed temporary resin. A bar(25 × 2 × 2 mm) was produced with a layer thickness of 50 ㎛ using an LCD-type 3D printer and divided into 15 groups(n = 10, each) according to washing solution(IPA; 99% isopropyl alcohol, TPM; 93% Tripropylene glycol monomethylether, ETL; Ethanol, TWC; Twin 3D Cleaner, and DNC; DIO navi Cleaner) and washing method(Dip; Dip washing, Ultra; Ultrasonic washing, and Auto; Automated washing). All groups were washed for 5 minutes, and post-cured for 5 minutes using a UV LED light curing machine. The Flexural strength was measured using a three-point bending test using a universal testing machine. For statistical analysis, one-way ANOVA, Tukey HSD post hoc test, Kruskal-Wallis test and post-hoc by Bonferroni-Dunn test(𝛼=.05) were performed depending on whether the normality test was satisfied. In all washing solvents except TPM and DNC, the Dip group showed the lowest flexural strength values, while the Auto group showed the highest flexural strength values except for DNC. Additionally, the washing solution showed completely different flexural strength values depending on the washing method.

• KOREAN JOURNAL OF PACKAGING SCIENCE & TECHNOLOGY
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• v.5 no.2
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• pp.38-41
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• 1999

This study was carried out to investigate improvement of kraft paper sack mixed with recycled paper for sugars and assorted feeds. Four Plies of kraft paper mixed with recycled paper(basis weight : $80g/m^2$) were taken place of two plies of kraft paper made from all pulp(basis weight : $98g/m^2$) and one ply of kraft paper mixed with recycled paper(basis weight : $80g/m^2$) for sugar 30kg. Three Plies of kraft paper mixed with recycled paper(basis weight : $80g/m^2$) were taken place of two plies of kraft paper made from all pulp(basis weight $98g/m^2$) for sugar 15kg and assorted feed 25kg. Physical properties, tensile strength, internal tearing strength and bursting strength, were improved by exchanging kraft paper mixed with recycled paper for kraft paper from all pulp and so kraft paper sacks made from all pulp were no damage in handling. They had so high friction coefficient that there was no danger of collapse on pallet by slipperiness in transportation and handling. And they had high printability so disappearance of printing by the contact with other paper sack in transportation was not found.