• Proceedings of the Korean Institute of Building Construction Conference
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• 2013.11a
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• pp.68-71
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• 2013

Reactive Powder Concrete (RPC) is an ultra high strength and high ductility cement-based composite material and has shown some promise as a new generation concrete in construction field. It is characterized by a silica fume-cement mixture with very low water-binder (w/b) ratio and very dense microstructure, which is formed using various powders such as cement, silica fume and very fine quartz sand (0.15~0.4mm) instead of ordinary coarse aggregate. However, the unit weight of cement in RPC is as high as 900~1,000 kg/㎥ due to the use of very fine sand instead of coarse aggregate, and a large volume of relatively expensive silica fume as a high reactivity pozzolan is also used, which is not produced in Korea and thus must be imported. Since the density of RPC has a heavy weight at 2.5~3.0 g/㎤. In this study, the modified RPC was made by the combination of ternary pozzolanic materials such as blast furnace slag and fly ash, silica fume in order to economically and practically feasible for Korea's situation. The fire resistance and structural behavior of the modified RPC exposed to high temperature were investigated.

• Journal of the Korean Ceramic Society
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• v.31 no.12
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• pp.1536-1544
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• 1994

DSP technique was applied to improve the high strength characteristics of hardened cement paste using pozzolan materials as blending materials, and pozzolan reactivity was investigated. Pozzolanic materials such as diatomaceous earth, fly ash and hydrated silica were used as blending material. And also superplasticizer was added to cement for molding the specimens. After curing for 60 days, the specimens substituted with 10 and 15 wt% of diatomaceous earth showed better strength characteristics than the specimen with fly ash. The specimen substituted 7 wt.% of hydrated silica exhibited excellent strength with above 800 kg/$\textrm{cm}^2$.

• Advances in concrete construction
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• v.10 no.4
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• pp.301-310
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• 2020

The following paper concentrates on the objective of studying the influences of extent of duration and temperature on the Pozzolanic properties as well as reactivity of locally existing natural clay of Nai Gaj, district Dadu, Sindh Pakistan. The activation of the clay only occurs through heating when temperature in a furnace chamber reaches 600, 700 and 800oC for 1, 2 and 3 hours and at 900 and 1000℃ for 1 and 2 hours. Furthermore, the strength activity index (SAI) of advanced pozzolanic material happens to be identified through 20% cement replacement for different samples of calcined clay as per ASTM C-618. The compressive strength test of samples had been operated for 7 and 28-days curing afterwards. The maximum compressive strength had been seen in mix E in which cement was replaced with clay calcined at 700℃ for 1 hour that is 27.05 MPa that is 24.31% more than that of control mix. The results gathered from the SAI verdicts the optimal activation temperature is 700℃ within a one-hour time period. The SAI at a temperature of 700℃ with a one-hour duration at 28 days is 124.31% which happens to satisfy the requirements of the new Pozzolanic material, in order to be applied in mortar/concrete (i.e., 75%). The Energy- dispersive spectrometry (EDS) along with the X-ray diffraction (XRD) have been carried out in means of verifying whether there is silica content or amorphous silica present in metakaolin that has been developed. The findings gathered from the SAI were validated, as the analysis of XRD verified that there is in fact Pozzolanic activity of developed metakaolin. Additionally, based on observation, the activated metakaolin holds a significant influence on the increase in mortar's compressive strength.

• Journal of the Mineralogical Society of Korea
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• v.17 no.3
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• pp.277-288
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• 2004

Alkali-silica reaction (ASR) is a chemical reaction between alkalies in cement and chemically unstable aggregates and causes expansion and cracking of concrete. In the Present study, we studied the effects of metakaolin, which is a newly introduced mineral admixture showing excellent pozzolainc reaction property, on the inhibition of ASR. We prepared mortar-bars of various replacement ratios of metakaolin and conducted alkali-silica reactivity test (ASTM C 1260), compressive strength test and flow test. We also carefully analyzed the mineralogical changes in hydrate cement paste by XRD qualitative analysis. The admixing of metakaolin caused quick pozzolanic reaction and hydration reaction that resulted in a rapid decrease in portlandite content of hydrated cement paste. The expansion by ASR was reduced effectively as metakaolin replaced cement greater than 15%. This resulted in that the amounts of available portlandite decreased to less than 10% in cement paste. It is considered that the inhibition of ASR expansion by admixing of metakaolin was resulted by the combined processes that the formation of deleterious alkali-calcium-silicate gel was inhibited and the penetration of alkali solution into concrete was retarded due to the formation of denser, more homogeneous cement paste caused by pozzolanic effect. Higher early strength (7 days) than normal concrete was developed when the replacement ratios of metakaolin were greater than 15%. And also, late strength (28 days) was far higher than normal concrete for the all the replacement ratios of metakaolin. The development patterns of mechanical strength for metakaolin admixed concretes reflect the rapid pozzolanic reaction and hydration properties of metakaolin.

• Journal of the Korea Institute of Building Construction
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• v.14 no.6
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• pp.531-536
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• 2014

Recently, the amounts of dredge sea soil in south Korea have been increasing because of various maintenance works at harbors and rivers. Dredged sea soil contains various contaminants. Hence, prior to recycling the dredged sea soil, the various contaminants should be removed to prevent a secondary contamination due to the leaching of hazardous chemicals. Pretreated dredged sea soil can be buried under the ground or used for land reclamation. In this study, however, pretreated dredged sea soil was used to investigate the level of pozzolanic activity. The properties of pretreated dredged sea soil were investigated, the method for heat treatment was determined, and the compressive strength of mortar using dredged sea soil was examined. According to the XRF result, the main components of dredged sea soil were $SiO_2$ of over 55%, and $Al_2O_3$ and $SO_3$ of some amounts. Results from XRD and TG/DTA showed that pretreated dredged sea soil can be used as a pozzolanic material. When dredged sea soil was thermally treated for 90 min at $550^{\circ}C$, a compressive strength result was similar to that of control mortar.

• Proceedings of the Korea Concrete Institute Conference
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• 1998.10c
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• pp.87-92
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• 1998

The purpose of this study is to use paper sludge ash as a material in manufacturing high strength admixture. The reactivity of paper sludge ash as iteself is low for the crystallized non-reactive $SiO_2$, but when the $SiO_2$ was removed, the phase component is mainly composed of glass phase which could react with cement hydrates. In this study, we manufactured high strength admixture using separated paper sludge ash, and examined the strength of mortar, spun concrete with and without this high strength admixture in steam curing. The strength of spun concrete with high strength admixture including paper sludge ash was more higher than that of spun concrete without admixture. As a result, it was found that paper sludge ash could be used to a pozzolanic material in manufacturing high strength admixture.

• Journal of the Korean Ceramic Society
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• v.27 no.3
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• pp.437-443
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• 1990

The resistivity of cement paste and mortar for freezing and thawing was investigated for densifying the structure of cement paste and mortor, slag, diatomaceous earth and fly ash as blending materials and superplasticizer were used, and air entraining agent was added to absorb the volume expansion by freezing and thawing reaction. And then the specimens were subjected to freeze-thaw in water. When both of air entraining agent and superplasticizer as additives were mixed to specimens, their freeze-thaw resistance was enhanced by the air entraining effect and the water reduction effect. When 4% of slag were added to cement, freeze-thaw resistance was especially excellent. In addition, it was found that the specimens with blending materials were more influenced by curing periods than those without admixture. It is assumed that the curing periods contribute to exibit the potential hydraulicity and pozzolanic reactivity of blending materials and to densify their texture.

• Journal of the Korean Society of Safety
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• v.13 no.3
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• pp.45-50
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• 1998

The low grade domestic kaoline, such as pink-C and white-D, was converted to metakaoline, which has pozzolanic reactivity by heat treatment in the temperature range of $600^{\circ}C$ to 100$0^{\circ}C$ for preparing the spacer. The spacer was used for supporting the reinforced steel rod during construction to improve the safety of architecture. Pink-C and white-D were completely dehydroxylated when burnt at 80$0^{\circ}C$ for 1 hour and converted to metakaoline. The compressive strengths of specimens added calcined pink-C were lower than those of press molding mortar products inspite of calcining conditions. When white-D with calcined 80$0^{\circ}C$ and 100$0^{\circ}C$ for 1 hour was mixed 30% in the weight ratio of cement, the specimens cured 28 days had 338 $kg/cm^2$ and 347 $kg/cm^2$ of compressive strengths, respectively.

• Computers and Concrete
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• v.13 no.6
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• pp.739-748
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• 2014

In this article, by using experimental studies and artificial neural network has been tried to investigate the use of nano-silica as concrete admixture to reduce alkali-silica reaction. If there are reactive aggregates and alkali of cement with enough moisture in concrete, a gel will be formed. Then with high reactivity between alkali of cement and existence of silica in aggregates, this gel will expand by absorption of water, and causes expansive pressure and cracks be formed. At the time passes, this gel will reduce both durability and strength of the concrete. By reducing the size of silicate to nano, specific surface area of particles and number of atoms on the surface will be increased, which causes more pozzolanic activity of them. Nano-silica can react with calcium hydroxide ($Ca(OH)_2$) and produces C-S-H gel. In this study, accelerated mortar bar specimens according to ASTM C 1260 and ASTM C 1567, with different mix proportions were prepared using aggregates of Kerman, such as: none admixture and plasticizer, different proportions of nano-silica separately. By opening the moulds after 24 hour and curing in water at $80^{\circ}C$ for 24 hour, then curing in (1N NaOH) at $80^{\circ}C$ for 14 days, length expansion of mortar bars were measured and compared. It was noted that, the lowest length expansion of a specimens shows the best proportion of admixture based on alkali-silica reactivity. Then, prediction of alkali-silica reaction of concrete has been investigated by using artificial neural network. In this study the backpropagation network has been used and compared with different algorithms to train network. Finally, the best amount of nano silica for adding to mix proportion, also the best algorithm and number of neurons in hidden layer of artificial neural network have been offered.

• Advances in concrete construction
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• v.14 no.5
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• pp.341-354
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• 2022

Treatment of solid waste building materials is a crucial method of disposal and an area of ongoing research. New standards for the treatment of solid waste building materials are necessary due to multisource features, huge quantities, and complicated compositions of solid waste. In this research, sustainable nanomaterial mixtures containing nano-paper waste (NPW) and nano-metakaolin (NMK) were used as a substitute for Portland cement. Portland cement was replaced with different ratios of NPW and NMK (0%, 4%, 8%, and 12% by weight of cement) while the cement-to-water ratio remained constant at 0.4 in all mortar mixtures. The fresh properties had a positive effect on them, and with the increase in the percentage of replacement, the fresh properties decreased. The results of compressive strength at 7 and 28 days and flexural strength at 28 days show that the nanomaterials improved the strength, but the results of NMK were better than those of NPW. The best replacement rate was 8%, followed by 4%, and finally 12% for both materials. The combination of NMK and NPW as a replacement (12% NMK + 12% NPW) showed less shrinkage than the others because of the high pozzolanic reactivity of the nanomaterials. The combination of NMK and NPW improved the microstructure by increasing the hydration volume and lowering the water in the cement matrix, as clearly observed in the C-S-H decomposition.