• Title/Summary/Keyword: pore development

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A Study on the Antibacterial Properties of Ag Electropulsed Anodized Aluminium Alloy (Pulse도금법에 의한 Ag주입 양극산화 알루미늄 합금의 항균특성에 관한 기초연구)

  • Lim, Ki-Young;Ki, Joon-Seo;Jang, Yong-Seok;Lee, Woo-Min;Yoon, Jeong-Mo
    • Korean Journal of Materials Research
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    • v.16 no.10
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    • pp.639-646
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    • 2006
  • Over the last two decades, microbiologically influenced corrosion (MIC) of metallic materials has received considerable attention due to its serious effects on industrial field. In this context, it is important to devise control methods which inhibit biofilm formation on various metallic compounds and are compatible with environment. It was change of various conditions (duty cycle, current density, $AgNO_3$ concentration and pH) for injection of Ag particles in anodized Aluminum alloy pore using pulsed current. Optimal condition was obtained by means of FE-SEM, ICP analysis etc. The antibacterial metal's specimen were manufactured under optimal condition and this specimen were tested the antibacterial characterization and anticorrosion characterization. In result of test, we can confirmed that the antibacterial characterization and anticorrosion characterization of the specimens of injected Ag particles in anodized Aluminum alloy pore using pulsed current were better than the anodized Aluminum alloy specimens.

Resistance of Cementitious Binders to Chloride Induced Corrosion of Embedded Steel by Electrochemical and Microstructural Studies

  • Song, Ha-Won;Ann, Ki-Yong;Kim, Tae-Sang
    • Corrosion Science and Technology
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    • v.8 no.2
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    • pp.74-80
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    • 2009
  • The high alkaline property in the concrete pore solution protects the embedded steel in concrete from corrosion due to aggressive ions attack. However, a continuous supply of those ions, in particular, chlorides altogether with a pH fall in electrochemical reaction on the steel surface eventually depassivate the steel to corrode. To mitigate chloride-induced corrosion in concrete structures, finely grained mineral admixtures, for example, pulverized fuel ash (PFA), ground granulated blast furnace slag (GGBS) and silica fume (SF) have been often advised to replace ordinary Portland cement (OPC) partially as binder. A consistent assessment of those partial replacements has been rarely performed with respect to the resistance of each binder to corrosion, although the studies for each binder were extensively looked into in a way of measuring the corrosion rate, influence of microstructure or chemistry of chlorides ions with cement hydrations. The paper studies the behavior of steel corrosion, chloride transport, pore structure and buffering capacity of those cementitious binders. The corrosion rate of steel in mortars of OPC, 30% PFA, 60% GGBS and 10% SF respectively, with chloride in cast ranging from 0.0 to 3.0% by weight of binder was measured at 7, 28 and 150 days to determine the chloride threshold level and the rate of corrosion propagation, using the anodic polarization technique. Mercury intrusion porosimetry was also applied to cement pastes of each binder at 7 and 28 days to ensure the development of pore structure. Finally, the release rate of bound chlorides (i.e. buffering capacity) was measured at 150 days. The chloride threshold level was determined assuming that the corrosion rate is beyond 1-2 mA/$m^3$ at corrosion and the order of the level was OPC > 10% SF > 60% GGBS > 30% PFA. Mercury intrusion porosimetry showed that 10% SF paste produced the most dense pore structure, followed by 60% GGBS, 30% PFA and OPC pastes, respectively. It was found that OPC itself is beneficial in resisting to corrosion initiation, but use of pozzolanic materials as binders shows more resistance to chloride transport into concrete, thus delay the onset of corrosion.

Development of Torsional Shear Testing System to Measure P-wave Velocity, S-wave Velocity and Pore Water Pressure Buildup on Fully and Partially Saturated Sands (포화 및 부분 포화 사질토의 Vp와 Vs 속도 및 과잉간극수압 측정을 위한 비틂전단 시험기의 개발)

  • Kim, Dong-Soo;Lee, Sei-Hyun;Choo, Yun-Wook
    • Journal of the Korean GEO-environmental Society
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    • v.7 no.1
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    • pp.55-66
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    • 2006
  • Laboratory tests have revealed that the liquefaction resistance of sands depends strongly upon the degree of saturation, which is expressed in terms of the pore pressure coefficient, B. The velocity of compression waves(i.e. P-waves), which have been known to be influenced largely by the degree of saturation and can be measured conveniently in the field, appears as an indicator of saturation. In this paper, the Stokoe type torsional shear(TS) testing equipment is modified to saturate the specimen and measure the velocities of P-wave and S-wave and pore pressure buildup. The velocities of P-wave and S-wave for Toyoura sand from Japan is measured and compared at the various B-value (degree of saturation) which are partially saturated to fully saturated conditions. Additionally, the variation of the pore water pressure induced during undrained TS tests at the various B-value is measured and analyzed.

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Development of Porous polyurethane Arterial-Venous Shunt by Thermal Control (온도 조절을 통한 다공성 폴리우레탄 동정맥 누관의 개발)

  • Jeong, J.S.;Ryu, G.H.;Kim, J.;Min, B.G.
    • Proceedings of the KOSOMBE Conference
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    • v.1997 no.11
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    • pp.478-481
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    • 1997
  • A technique or the preparation of porous polyurethane vascular prostheses was investigated. Small-diameter vessels are not in general clinical use due to their limited long-term biocompatibility and low patency rates in experimental trial. These limits are mainly due to the failure of mechanical unction of the vascular grafts. This failure has been suggested to result partially from compliance mismatch. The long-term patency is considered to depend critically on the properties of the material and the fabrication process of the graft. So the control of pores is very important and main points to develop a available vascular grafts. Two-kind polymer sheets was compared. One was the porous PU-sheet made at room temperature by the solvent/non-solvent exchange. And the other was the porous PU-sheet which was fabricated by thermal phase transition and solvent-/non-solvent exchange using the thermal controller. The polymer sheets had a uniform pore size and pore occupation. According to the result of the above experiments, polyurethane solution was injected into a mold designed or U-type tube. The average pore size and pore occupation were easily changed by changing polyurethane concentration, freezing temperature, and methods. This technique can give a proper pore size ($10{\sim}45\;{\mu}m$) or tissue in growth, and suitable compliances or matching with arteries and veins. Besides, the fabrication of more complicated shaped vessels such as the U-type vascular grafts is easily controlled by using the fixed mold. this method might give a desired compliant graft or artificial implantation with the presently valid medical polymers.

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Microstructure of Non-Sintered Inorganic Binder using Phosphogypsum and Waste Lime as Activator

  • Kim, Ji-Hoon;An, Yang-Jin;Mun, Kyung-Ju;Hyung, Won-Gil
    • Journal of the Korea Institute of Building Construction
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    • v.18 no.3
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    • pp.305-312
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    • 2018
  • This study is about the development of a non-sintered binder (NSB) which does not require a sintering process by using the industrial by-products Phosphogypsum (PG), Waste Lime (WL) and Granulated Blast Furnace Slag (GBFS). In this report, through SEM analysis of the NSB paste hardening body, micropore analysis of paste using the mercury press-in method and microstructure observation were executed to consider the influence of the formation of the pore structure and the distribution of pore volume on strength, and the following conclusions were reached. 1) Pore structure of NSB paste of early age is influenced by hydrate generation amount by GBFS and activator. 2) Through observing the internal microstructure of NSB binder paste, it was found that the strength expression at early age due to hydration reaction was achieved with a large amount of ettringite serving as the frame with C-S-H gel generated at the same time. It was confirmed that C-S-H gel wrapped around ettringite, and as time passed, the amount generated continually increased, and C-S-H gel tightly filled the pores of hardened paste, forming a dense network-type web structure. 3) For NSB-type cement, the degree of formation of gel pores below $10{\mu}m$ had a greater influence on strength improvement than simple pore reduction by charging capillary pores, and the pore size that had the greatest effect on strength was micropores with diameter below $10{\mu}m$.

Development of Modified Disturbed State Concept Model for Liquefaction Analysis (액상화 해석을 위한 수정교란상태개념 모델 개발)

  • Park, Keun-Bo;Choi, Jae-Soon;Park, Inn-Joon;Kim, Ki-Poong;Kim, Soo-Il
    • Journal of the Korean Geotechnical Society
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    • v.24 no.3
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    • pp.35-51
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    • 2008
  • In this paper, the application of the DSC model to the analysis of liquefaction potential is examined through experimental and analytical investigations. For more realistic description of dynamic responses of saturated sands, the DSC model was modified based on the dynamic effective stress path and excess pore pressure development. Both static and cyclic undrained triaxial tests were performed for sands with different relative densities and confining stresses. Based on test results, a classification of liquefaction phases in terms of the dynamic effective stress path and the excess pore pressure development was proposed and adopted into the modified DSC model. The proposed methods using the original and modified DSC models were compared with examples with different relative densities and confining stresses. Based on the comparisons between the predicted results using the original and modified DSC models and experimental data, the parameters required to define the model were simplified. It was also found that modified model more accurately simulate initial liquefaction and dynamic responses of soil under cyclic undrained triaxial tests.

Analysis of microplastics released from textiles according to filter pore size and fabric weight during washing (세탁 중 세탁물 중량과 여과 기공 크기에 따른 미세플라스틱 분석)

  • Choi, Sola;Kwon, MiYeon;Park, Myung-Ja;Kim, Juhea
    • Journal of the Korea Fashion and Costume Design Association
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    • v.23 no.1
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    • pp.37-45
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    • 2021
  • This study observed the release of microplastics according to washing weights and filtering conditions, measured microplastic generation rates, fiber lengths, and fiber diameters. This study attempted to present data for the development of filters that decrease microplastic generation. For test samples, polyester piled knit fabric (cut-pile) was selected, which currently has the highest amount of consumption in the clothing industry, but can easily cause marine pollution because of its low biodegradability. For test equipment, a drum washer was used and microplastics were collected using two filter pore sizes, 5 ㎛ and 20-25 ㎛. Microplastic fibers weights and lengths were measured. The results of the experiment showed the following: 1) The release of microplastics differed according to the fabric weights and washing process; 2) washing fabric weights showed a differences in the collection amount according to the filter pore size (5 ㎛, 20-25 ㎛); 3) observations of differences in the lengths of the microplastics that occur during the washing process by filter pore size were made. Fibers with shorter lengths appeared with filter pore sizes of 5㎛ in comparison to filter pore sizes of 20-25㎛. The results from this study on microplastic generation by fabric during washing, demonstrated the following conclusions that can be used to reduce the release of microplastics. First, the release of microplastics according to fabric weights and washing courses are affected by physical force. Therefore, it is necessary to reduce the amount of physical force due to water flow, increase the fabric weight, or wash the material in low temperatures. Second, in the manufacturing of washing machines, microplastic filtration can be promoted or legislatation supporting microplastic filtration can be introduced.

Deformation Characteristics of Non-liquefied, Reconstituted, Weathered Residual Soils due to the Cyclic Loading (반복재하에 의한 미액상화 재성형 풍화토의 변형 특성)

  • Choi Yeon-Su;Yune Chan-Young;Jang Eui-Ryong;Chung Choong-Ki
    • Journal of the Korean Geotechnical Society
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    • v.22 no.6
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    • pp.41-49
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    • 2006
  • This paper deals with development and dissipation of excess pore pressure induced by the cyclic load. Cyclic triaxial tests on reconstituted samples of weathered residual soils, which were widely used as construction materials in Korea, were performed. Test results showed that excess pore pressures developed under undrained condition increased with the increase of cyclic loads and confining pressures. And a new concept based on modified excess pore pressure ratio (MEPPR) was proposed for simply estimating excess pore pressures in terms of the number of cyclic load, irrespective of cyclic loads and confining pressures. Also, it was proposed that excess pore pressure ratio (EPPR) could be effectively utilized to estimate volumetric strains during dissipation which decreased as confining pressures increased. Consequently, concept and method to effectively estimate settlements under non-liquefied condition, induced by dynamic loads such as earthquake loads were evaluated based on laboratory test results for reconstituted weathered residual soils.

Development of control technique of nano-sized pattern for electroplating (나노급 도금공정을 위한 미세패턴 제어기술의 개발)

  • Lee, Jae-Hong;Lee, Byoung-Wook;Lee, Kyung-Ho;Kim, Chang-Kyo
    • Proceedings of the KIEE Conference
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    • 2004.07c
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    • pp.1576-1578
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    • 2004
  • The alumina membrane with nano sized pore was prepared from aluminum by anodic oxidation to apply for storage equipment, gas sensor and stamper. The pore size and cell size of the pores are controlled by anodic oxidation voltage. The alumina thickness was controlled by etching process using 0.2M $H_3PO_4$. The thickness of alumina on Si wafer was very accurately controlled by anodic oxidation time. Nickel with nano-sized grain was electroplated on the Au layer on silicon wafer. The fabricated pores on alumina membrane was the thickness of $7{\sim}10{\mu}m$ with straight nano-sized pore of 307${\sim}$120nm. The alumina by the etching process shows smooth surface. The size of Ni grain was 130nm and 250nm for 10mA/$cm^2$and 20mA/$cm^2$of electroplating currents, respectively.

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