• Title/Summary/Keyword: polymer materials

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Novel Recycling Technology of Ultra-fine Fibrous Materials

  • Kim, Seong-Hun;Oh, Kyung-Wha;Lee, Shin-Kyung
    • Proceedings of the Polymer Society of Korea Conference
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    • 2006.10a
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    • pp.209-209
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    • 2006
  • Ultra-fine fibers are spun by expensive fiber spinning technology using special spinnerets. Ultra-fine fibrous materials have attracted considerable attentions because of their potential applications as high performance wiping cloths, water absorbent sound proofing materials and moisture transfer sporting good. However, production expense of ultra-fine fibers is 5 to 7 times higher than general textile materials. The objective of this research is to develop cost-effective recycling process to produce multi-functional ultra-fine fibrous material in terms of the development of garnetting and carding machines for ultra-fine fibrous material waste and scrap. The efficiency of sound absorption for the recycled polyester nonwoven increased with decreasing length and thickness of component fibers, which was attributed to the reduction of air permeability. It is expected that high value and cost-effective textile products are developed using ultra-fine fibrous wastes and that sound proofing material and oil absorbent f

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Electrical Conductivity of Chemically Reduced Graphene Powders under Compression

  • Rani, Adila;Nam, Seung-Woong;Oh, Kyoung-Ah;Park, Min
    • Carbon letters
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    • v.11 no.2
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    • pp.90-95
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    • 2010
  • Carbon materials such as graphite and graphene exhibit high electrical conductivity. We examined the electrical conductivity of synthetic and natural graphene powders after the chemical reduction of synthetic and natural graphite oxide from synthetic and natural graphite. The trend of electrical conductivity of both graphene (synthetic and natural) was compared with different graphite materials (synthetic, natural, and expanded) and carbon nanotubes (CNTs) under compression from 0.3 to 60 MPa. We found that synthetic graphene showed a marked increment in electrical conductivity compared to natural graphene. Interestingly, the total increment in electrical conductivity was greater for denser graphite; however, an opposite behavior was observed in nanocarbon materials such as graphene and CNTs, probably due to the differing layer arrangement of nanocarbon materials.

Use of polyaryletherketone (PAEK) based polymer for implant-supported telescopic overdenture: A case report

  • Park, Chan;Jun, Dae-Jeon;Park, Sang-Won;Lim, Hyun-Pil
    • The Journal of Advanced Prosthodontics
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    • v.9 no.1
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    • pp.74-76
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    • 2017
  • Although many prosthetic materials exist for fabrication of implant-supported telescopic overdentures, available materials have not been thoroughly evaluated from a functional standpoint. This case report describes the use of polyaryletherketone (PAEK) based polymer for an implant-supported telescopic overdenture, a seldom used material in dentistry. This material is lighter than traditional materials, can accommodate changes in retentive forces, and is an easily retrievable by CAD/CAM fabrication. This case highlights the possibility of using new polymer materials for implant-supported telescopic overdentures.

Tensile Failure Characterization of Composites for Railway Vehicle (철도차량 복합소재의 인장파괴 특성분석)

  • Kim, Jeong-Guk;Kwon, Sung-Tae;Kim, Jung-Seok;Yoon, Hyuk-Jin
    • Proceedings of the KSR Conference
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    • 2010.06a
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    • pp.1231-1235
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    • 2010
  • The tensile failure behavior of polymer matrix composite materials was investigated with the aid of a nondestructive evaluation (NDE) technique. The materials, E-glass fiber reinforced epoxy matrix composites, which are applicable to carbody materials in railway vehicles to reduce weight, were used for this investigation. In order to explain stress-strain behavior of polymer matrix composite sample, the infrared thermography technique was employed. A high-speed infrared (IR) camera was used for in-situ monitoring of progressive damages of polymer matrix composite samples during tensile testing. In this investigation, the IR thermography technique was used to facilitate a better understanding of damage evolution, fracture mechanism, and failure mode of polymer matrix composite materials during monotonic loadings.

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Improvement of the mechanical performance and dyeing ability of bamboo fiber by atmospheric pressure air plasma treatment

  • Hoa, Ta Phuong;Chuong, Bui;Hung, Dang Viet;Tien, Nguyen Dung;Khanh, Vu Thi Homg
    • Proceedings of the Korean Society of Dyers and Finishers Conference
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    • 2009.03a
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    • pp.14-20
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    • 2009
  • Atmospheric pressure air plasma was applied for treatment of different kinds of natural bamboo fiber to improve their mechanical properties and surface characteristics, which are suitable for adhesion and dyeing. The tensile strength and Young modulus of bamboo fiber were significantly improved; SEM and AFM study show that the surface of fiber became cleaner and rougher after plasma treatment. Plasma treatment caused the cracking, removing of the protective skin of alkali-untreated fiber and etching to form a cleaner and rougher surface. The dyeability of both groups of bamboo fiber which are used for composite and textile purposes is significantly enhanced after treatment.

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Luminescence Properties of Anthracene Chromophores in Cyclosiloxane-Based Hybrid Polymer Films

  • Demirci, Ali;Yamamoto, Shunsuke;Matsui, Jun;Miyashita, Tokuji;Mitsuishi, Masaya
    • Rapid Communication in Photoscience
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    • v.4 no.1
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    • pp.16-18
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    • 2015
  • Luminescence properties of anthracene chromophores were investigated. Anthracene chromophores were incorporated in cyclosiloxane-based hybrid polymers through one-pot hydrosilylation reaction. Using four-armed cyclosiloxanes, divinylterminated siloxane monomers, and 9-vinylanthracenes, anthracene-labeled hybrid polymers were prepared. Free-standing hybrid polymer films were prepared successfully by doctor-blade method and thermal treatment. The polymer films exhibit strong blue fluorescence from anthracene and its fluorescence lifetime was not influenced by the temperature, indicating that the movement of anthracene chromophores was restrained in cyclosiloxane-based hybrid polymer films.

Effect of Matrix Viscosity on Clay Dispersion in Preparation of Polymer/Organoclay Nanocomposites

  • Ko, Moon-Bae;Jho, Jae-Young;Jo, Won-Ho;Lee, Moo-Sung
    • Fibers and Polymers
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    • v.3 no.3
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    • pp.103-108
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    • 2002
  • The viscosity effect of matrix polymer on melt exfoliation behavior of an organoclay in poly($\varepsilon$-caprolactone) (PCL) was investigated. The viscosity of matrix polymer was controlled by changing the molecular weight of poly($\varepsilon$-eaprolactone), the processing temperature, and the rotor speed of a mini-molder. Applied shear stress facilitates the diffusion of polymer chains into the gallery of silicate layers by breaking silicate agglomerates down into smaller primary particles. When the viscosity of PCL is lower, silicate agglomerates are not perfectly broken into smaller primary particles. At higher viscosity, all of silicate agglomerates are broken down into primary particles, and finally into smaller nano-scale building blocks. It was also found that the degree of exfoliation of silicate layers is dependent upon not only the viscosity of matrix but thermodynamic variables.

A SHIELDING EFFECTIVENESS of COATED CONDUCTIVE POLYMER for ELECTROMAGNETIC SHIELDING (전자파 차폐용 전도성 고분자 코팅재료의 차폐효율)

  • 최재옥;임윤석;장용무;서광석;구자윤
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2000.07a
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    • pp.624-627
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    • 2000
  • The shielding effectiveness of materials is determined by measuring the ratio of the incident electromagnetic power which passes through the material under test. To measure the shielding effectiveness materials made by conductive polymer, the flanged coaxial transmission-line holder based in ASTM D4935-89, was fabricated. This apparatus has dynamic range between 95dB and 120dB in frequency range of 50Mhz-2Ghz. Furthermore, this system can be utilized to measure the shielding effectiveness of materials produced by conductive polymer and can be adapted for shielding materials design.

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Design and Synthesis of New Fluorene-Based Blue Light Emitting Polymer Containing Electron Donating Alkoxy Groups and Electron Withdrawing Oxadiazole

  • Kim, Yun-Hi;Park, Sung-Jin;Park, Jong-Won;Kim, Jin-Hak;Kwon, Soon-Ki
    • Macromolecular Research
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    • v.15 no.3
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    • pp.216-220
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    • 2007
  • A new polyfluorene-based copolymer having 2-ethylhexyloxy-5-methoxy-l,4-phenylene as an electron donating group and 2,5-diphenyl-oxadiazole as an electron withdrawing group was synthesized by the Suzuki coupling reaction. The obtained copolymer was characterized by $^1H-NMR,\;^{13}C-NMR$, and IR-spectroscopy. The weight average molecular weight ($M_w$) of the obtained polymer was 18,600 with a polydispersity index of 1.5. The maximum photoluminescence of the solution and film of the polymer was observed at 453 nm and 456 nm, respectively. A double-layer device with the configuration, ITO/PEDOT/copolymer/Al, emitted blue light at 460 nm.

Influence of Calcium on the Formation of Aluminosilicate Inorganic Polymer Binder

  • Ahn, Sangwook;Choi, Youngkue;Shin, Byeongkil;Lee, Jungwoo;Lee, Heesoo;Hui, Kwunnam
    • Korean Journal of Metals and Materials
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    • v.49 no.5
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    • pp.362-366
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    • 2011
  • Aluminosilicate inorganic polymer binder has been studied as an alternative to ordinary Portland cement due to its higher physical properties, chemical resistance and thermal resistance. This study has been carried out in an attempt to understand the hardening characteristics of aluminosilicate binder by varying the content of calcium. Samples with four different ratios of Al, Si, and Ca were synthesized in this study with the Al:Si:Ca mol ratio being 1.00:1.85~1.98:0.29~2.12. Furthermore, an alkali silicate solution was prepared with the sodium hydroxide (NaOH) and sodium silicate (NaSi). The hardening characteristics of the specimens were analyzed using XRD, SEM, and TG/DTA. In addition, compressive strength and sintering time of specimens were measured as a function of calcium content. The results showed that the specimen containing 2.12 mol% calcium offered the highest compressive strength. However, the compressive strength of the specimen containing 0.26 mol% calcium was lower relative to the other specimens. The results displayed a distinct tendency that as more calcium was added to the inorganic polymer, setting time became shorter. When calcium was added to the inorganic polymer structure, a second phase was not formed, indicating that the addition of calcium does not affect the crystalline structure.