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Korean Society of Photoscience (한국광과학회)
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Luminescence Properties of Anthracene Chromophores in Cyclosiloxane-Based Hybrid Polymer Films

  • Demirci, Ali (Institute of Multidisciplinary Research for Advanced Materials, Tohoku University) ;
  • Yamamoto, Shunsuke (Institute of Multidisciplinary Research for Advanced Materials, Tohoku University) ;
  • Matsui, Jun (Department of Material and Biological Chemistry, Faculty of Science, Yamagata University) ;
  • Miyashita, Tokuji (Institute of Multidisciplinary Research for Advanced Materials, Tohoku University) ;
  • Mitsuishi, Masaya (Institute of Multidisciplinary Research for Advanced Materials, Tohoku University)
  • Received : 2015.03.04
  • Accepted : 2015.03.18
  • Published : 2015.03.01
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Abstract

Luminescence properties of anthracene chromophores were investigated. Anthracene chromophores were incorporated in cyclosiloxane-based hybrid polymers through one-pot hydrosilylation reaction. Using four-armed cyclosiloxanes, divinylterminated siloxane monomers, and 9-vinylanthracenes, anthracene-labeled hybrid polymers were prepared. Free-standing hybrid polymer films were prepared successfully by doctor-blade method and thermal treatment. The polymer films exhibit strong blue fluorescence from anthracene and its fluorescence lifetime was not influenced by the temperature, indicating that the movement of anthracene chromophores was restrained in cyclosiloxane-based hybrid polymer films.

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References

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