• Title/Summary/Keyword: polymer material

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PCL Infiltration into a BCP Scaffold Strut to Improve the Mechanical Strength while Retaining Other Properties

  • Kim, Min-Sung;Kim, Yang-Hee;Park, Ih-Ho;Min, Young-Ki;Seo, Hyung-Seok;Lee, Byong-Taek
    • Korean Journal of Materials Research
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    • v.20 no.6
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    • pp.331-337
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    • 2010
  • A highly porous Biphasic Calcium Phosphate (BCP) scaffold was fabricated by the sponge replica method with a microwave sintering technique. The BCP scaffold had interconnected pores ranging from $80\;{\mu}m$ to $1000\;{\mu}m$, which were similar to natural cancellous bone. To enhance the mechanical properties of the porous scaffold, infiltration of polycaprolactone (PCL) was employed. The microstructure of the BCP scaffold was optimized using various volume percentages of polymethylmethacrylate (PMMA) for the infiltration process. PCL successfully infiltrated into the hollow space of the strut formed after the removal of the polymer sponge throughout the degassing and high pressure steps. The microstructure and material properties of the BCP scaffold (i.e., pore size, morphology of infiltrated and coated PCL, compressive strength, and porosity) were evaluated. When a 30 vol% of PMMA was used, the PCL-BCP scaffold showed the highest compressive strength. The compressive strength values of the BCP and PCL-BCP scaffolds were approximately 1.3 and 2MPa, respectively. After the PCL infiltration process, the porosity of the PCL-BCP scaffold decreased slightly to 86%, whereas that of the BCP scaffold was 86%. The number of pores in the $10\;{\mu}m$ to $20\;{\mu}m$ rage, which represent the pore channel inside of the strut, significantly decreased. The in-vitro study confirmed that the PCL-infiltrated BCP scaffold showed comparable cell viability without any cytotoxic behavior.

Rapid Repair of Severely Damaged RC Columns with Different Damage Conditions: An Experimental Study

  • He, Ruili;Sneed, Lesley H.;Belarbi, Abdeldjelil
    • International Journal of Concrete Structures and Materials
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    • v.7 no.1
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    • pp.35-50
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    • 2013
  • Rapid and effective repair methods are desired to enable quick reopening of damaged bridges after an earthquake occurs, especially for those bridges that are critical for emergency response and other essential functions. This paper presents results of tests conducted as a proof-of-concept in the effectiveness of a proposed method using externally bonded carbon fiber reinforced polymer (CFRP) composites to rapidly repair severely damaged RC columns with different damage conditions. The experimental work included five large-scale severely damaged square RC columns with the same geometry and material properties but with different damage conditions due to different loading combinations of bending, shear, and torsion in the previous tests. Over a three-day period, each column was repaired and retested under the same loading combination as the corresponding original column. Quickset repair mortar was used to replace the removed loose concrete. Without any treatment to damaged reinforcing bars, longitudinal and transverse CFRP sheets were externally bonded to the prepared surface to restore the column strength. Measured data were analyzed to investigate the performance of the repaired columns compared to the corresponding original column responses. It was concluded that the technique can be successful for severely damaged columns with damage to the concrete and transverse reinforcement. For severely damaged columns with damaged longitudinal reinforcement, the technique was found to be successful if the damaged longitudinal reinforcement is able to provide tensile resistance, or if the damage is located at a section where longitudinal CFRP strength can be developed.

Electrochemistry and Corrosion Characteristics of Polyaniline Dispersion Coating for Protection of Steels (강철보호를 위한 폴리아닐린 분산 코팅의 전기화학 및 부식특성)

  • Huh, Jae-Hoon;Oh, Eung-Ju;Cho, Jeong-Hwan
    • Journal of the Korean Electrochemical Society
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    • v.6 no.2
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    • pp.113-118
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    • 2003
  • Processible polyaniline (PAM) dispersions consisting of polyaniline micro-particles, cyclohexanone, and a polymeric surfactant were prepared in a micro-milling machine with various mixing conditions. The electrochemical properties of the dispersion film coated on Pt electrode were investigated by cyclic voltammetry (CV). The electrochemistry of the PAM dispersion coatings was basically similar to a pure PAM coating based on the results of CV. The results of polarization measurements and open circuit potential measurements carried out in $3\;wt.\%$ NaCI solution showed increase in corrosion potential when the PANI dispersion coatings applied on steel surface. Variation of open circuit potential $(OCP,\;V_{OC})$ of the dispersion coating/steel electrodes was observed, which differed with milling conditions. The results demonstrated practical use of the conducting polymer dispersion as a coating material for corrosion prevention of steel.

Electrochemical Properties of Poly(Styrenesulfonate)-Carbon Composite Anode for Organic Rechargeable Battery (유기이차전지를 위한 Poly(Styrenesulfonate)-Carbon 복합 음극의 전기화학적 특성)

  • Lim, Ji-Eun;Kang, Dong-Won;Kim, Jae-Kwang
    • Journal of the Korean Electrochemical Society
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    • v.19 no.4
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    • pp.129-133
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    • 2016
  • In this study, a polymer-carbon composite material is prepared for environmental-friendly organic anode. On poly(styrenesulfonate)(PSS)-carbon composite anode, the carbon is coated by PSS as a core-shell structure and the PSS-carbon composite anode has $524mAh\;g^{-1}$ theoretical capacity with <0.6V voltage. Moreover, the PSS-carbon composite anode shows $519.6mAh\;g^{-1}$, $461.2mAh\;g^{-1}$, $411.8mAh\;g^{-1}$ and $315.9mAh\;g^{-1}$ discharge capacities at 0.1, 0.5, 1 and 10 C, respectively, and stable cycle performance up to 30 cycles. The PSS-carbon composite anode, containing polystyrene and sulfonate functional groups, is suitable for high electrochemical properties organic rechargeable battery.

Evaluation of Permeability Performance by Cryogenic Thermal Shock in Composite Propellant Tank for Space Launch Vehicles (우주 발사체용 복합재 산화제 탱크 구조물의 극저온 열충격에 따른 투과도 성능 평가)

  • Kim, Jung-Myung;Hong, Seung-Chul;Choi, Soo-Young;Jeong, Sang-Won;Ahn, Hyon-Su
    • Composites Research
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    • v.33 no.5
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    • pp.309-314
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    • 2020
  • Polymer composites were used to reduce the weight of the spacecraft's cryogenic propellant tank. Since these materials were directional, the permeability performance of the gas permeated or delivered in the stacking direction was an indicator directly related to performance such as tank stability and onboard fuel quantity estimation. In addition, the results of permeation measurements and optical analysis of the surface to verify the effect of the number of cycles exposed to the cryogenic-room temperature environment are included. As a result, the permeability was inversely proportional to the thickness and was proportional to the number of thermal shocks, and it was verified that the permeability performance was suitable for the cryogenic propellant tank material for the space launch vehicle.

A Comparison Study of CFD Analysis and Flow Visualization on Behavior of Liquid Water in Cathode Channels of PEM Fuel Cells (PEM 연료전지 공기극 유로에서 물의 거동에 대한 CFD 해석과 가시화 실험의 비교 연구)

  • Kim, Hyun-Il;Nam, Jin-Hyun;Shin, Dong-Hoon;Chung, Tae-Yong;Kim, Young-Gyu;Seo, Won-Seok;Lee, Jung-Woon
    • Proceedings of the Korea Society for Energy Engineering kosee Conference
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    • 2008.04a
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    • pp.101-108
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    • 2008
  • Polymer electrolyte membrane (PEM) fuel cells are promising power generation devices which are ideal for residential and automobile applications, thanks to their fast transient characteristics. However, liquid water produced in PEM fuel cells should be properly managed to enhance the performances and durabilities of the cells. In this study, a visualization experiment was conducted to investigate the flow behavior of water droplets in cathode channels. The visualization experiment was done with four different model flow channels which were made by varying the material (Acrylic and Teflon) and the channel width (1 mm and 2 mm). Acrylic is hydrophilic (contact angle is about $80^{\circ}$) while Teflon is hydrophobic (contact angle is about $120^{\circ}$). A computational fluid dynamics (CFD) analysis was also performed to compare the observed and the simulated two-phase water/air flow characteristics in cathode channels. The computational models were made to be consistent with the geometries and surface properties of the model flow channels. Both the experimental and numerical results showed that the Teflon cathode channel with 1 mm width has the best water management performance among four model flow channels considered. A close correlation was found between the experimental visualization results and the numerical CFD simulation results.

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Effect of Solvent Annealing on the Characteristics of PEDOT:PSS as a Ammonia Gas Sensor Film (용매열처리에 따른 PEDOT:PSS 암모니아 가스 감지막 특성 변화)

  • Noh, Wang Gyu;Yeom, Se-Hyuk;Lee, Wanghoon;Shin, Han Jae;Kye, Ji Won;Kwak, Giseop;Kim, Se Hyun;Ryu, Si Ok;Han, Dong Cheul
    • Journal of Sensor Science and Technology
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    • v.26 no.2
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    • pp.96-100
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    • 2017
  • Poly(3,4-ethylenedioxythiophene):poly(styrenesulfonate) (PEDOT:PSS) has been extensively studied as the active material in ammonia gas sensor because of its fast response time, high conductivity and environmental stability. It is well known that a post annealing process for organic devices based on PEDOT:PSS significantly increases the device performance. In this study, we propose the solvent annealing of PEDOT:PSS and investigated its effects. As a results, post solvent annealing on PEDOT:PSS lead to the surface chemical and physical properties change. These changes result in improved conductivity of the PEDOT:PSS. In additional, ammonia sensitivity of solvent annealed PEDOT:PSS become higher than pristine polymer film. The enhancement is mainly caused by the depletion of gas barrier PSS and structural re-forming PEDOT networks. We believe that the post solvent annealing is a promising method to achieve highly sensitivity PEDOT:PSS films for applications in efficient, low-cost and flexible ammonia gas sensor.

The study on Development and characteristic of ultrasound biopsy training phantom of breast (유방 초음파 팬텀의 제작과 특성에 관한 연구)

  • Ma, Sang-Chull;Kong, Young-Kun;Ahn, Young-Man
    • Journal of radiological science and technology
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    • v.26 no.3
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    • pp.19-24
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    • 2003
  • We carried out studies on development and characteristic of ultrasound brast training biopsy phantom. the major finding were of follow ; (1) C type TMM was shown good homogeneity, brightness and attenuation as like human soft tissue. (2) $TiO_2$ 4.10%w/v TMM was shown good homogeneous echo texture and propagated speed as like the human Tissue. (3) $TiO_2$ type TMM was appeared lower brightness and higher penetration rate than C type TMM. Therefor, Breast TM phantom and target material TMM will be useful $TiO_2$ 4.10 %w/v TMM and C 2.09 %w/v TMM.

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Evaluation of the Adhesive Strength and the Drying Energy of Corrugated Board Using a Mixed Adhesive (혼합접착제 적용에 따른 골판지의 접착강도와 건조에너지 평가)

  • Lee, Ji Young;Kim, Chul Hwan;Kim, Eun Hea;Park, Tae Ung;Choi, Jae Sung
    • Journal of Korea Technical Association of The Pulp and Paper Industry
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    • v.48 no.3
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    • pp.51-56
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    • 2016
  • The most widely used glue in a corrugator is starch, which is a natural polymer. This material needs thermal energy to achieve a binding force, so a heating section is installed in a corrugator. However, this heating section can cause quality problems in linerboards and corrugating medium and increase the production cost because of the high cost of fossil resources. Therefore, a new adhesive that provides the binding force at lower temperatures than the conventional one must be developed. In this study, SB-latex was selected as a co-adhesive and added to the starch solution. The addition of the SB-latex was determined based on the viscosity of the new adhesive. The adhesive strength and the drying energy reduction of a corrugated board were measured to evaluate the functionalities of the new adhesive. The addition of SB-latex was determined to be under 20% of the oven-dried starch based on the viscosity of the new adhesive. The adhesive strength was improved and the drying energy was reduced by applying the new adhesive.

Thermal Characteristics of $H_2O$-NaOH Mixtures Type PCM for the Low Temperature Storage of Food and Medical Products (식.의약품 저온 저장을 위한 $H_2O$-NaOH 혼합형 잠열재의 냉축 열특성)

  • Song, Hyun-Kap;Ro, Jeong-Geun;Moon, Young-Mo
    • Journal of the Korean Solar Energy Society
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    • v.24 no.1
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    • pp.7-12
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    • 2004
  • Mixtures type PCM, $H_2O$-NaOH that has relatively large capacity of the latent heat and long duration of phase change temperature was developed and experimentally analyzed for the low temperature storage of the food and medical products. The results could be summarized as follows; 1. Borax as nucleating agent and acrylic polymer as thickening agent were added to $H_2O$ to prevent the supercooling and phase separation. 2. Phase change (solid$\leftrightarrows$liquid) duration of $H_2O$ added with NaOH was prolonged longer 50% than that of pure $H_2O$. 3. Phase change temperature of the latent heat material, $H_2O$-NaOH was $1.5\sim2^{\circ}C$ the maximum latent Heat was 279 kJ/kg at the NaOH addition of 1.3 wt.%. 4. The specific heat of $H_2O$-NaOH at the solid and liquid state was increased in proportion to the wt.% of NaOH, when NaOH of $1.15\sim1.60$ wt.% was added to $H_2O$, the specific heat of the solid state was increased from 3.19 kJ/kg to 5.84 kJ/kg and that of liquid state from 7.8 kJ/kg to 10.28 kJ/kg. 5. When NaOH of $1.15\sim1.60$ wt.% was added to $H_2O$, the total heat storage capacity composed of sensible and latent heat was $313\sim331.3$ kJ/kg and the maximum heat storage capacity was occurred at NaOH addition of 1.30 wt. %.