Journal of the Korean Electrochemical Society (전기화학회지)

The Korean Electrochemical Society (한국전기화학회)
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Electrochemical Properties of Poly(Styrenesulfonate)-Carbon Composite Anode for Organic Rechargeable Battery

유기이차전지를 위한 Poly(Styrenesulfonate)-Carbon 복합 음극의 전기화학적 특성

  • Lim, Ji-Eun (Department of Solar & Energy Engineering, Cheongju University) ;
  • Kang, Dong-Won (Department of Solar & Energy Engineering, Cheongju University) ;
  • Kim, Jae-Kwang (Department of Solar & Energy Engineering, Cheongju University)
  • 임지은 (청주대학교 태양광에너지공학과) ;
  • 강동원 (청주대학교 태양광에너지공학과) ;
  • 김재광 (청주대학교 태양광에너지공학과)
  • Received : 2016.09.11
  • Accepted : 2016.10.09
  • Published : 2016.11.30
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Abstract

In this study, a polymer-carbon composite material is prepared for environmental-friendly organic anode. On poly(styrenesulfonate)(PSS)-carbon composite anode, the carbon is coated by PSS as a core-shell structure and the PSS-carbon composite anode has $524mAh\;g^{-1}$ theoretical capacity with <0.6V voltage. Moreover, the PSS-carbon composite anode shows $519.6mAh\;g^{-1}$, $461.2mAh\;g^{-1}$, $411.8mAh\;g^{-1}$ and $315.9mAh\;g^{-1}$ discharge capacities at 0.1, 0.5, 1 and 10 C, respectively, and stable cycle performance up to 30 cycles. The PSS-carbon composite anode, containing polystyrene and sulfonate functional groups, is suitable for high electrochemical properties organic rechargeable battery.

본 연구에서는 고분자와 탄소 물질을 복합화시켜 친환경의 유기 음극을 제조하였다. Poly(styrenesulfonate)(PSS)-carbon 복합 음극은 탄소 입자를 PSS이 둘러싸고 있는 core-shell 형태를 보이며 $524mAh\;g^{-1}$의 이론용량과 0.6 V 이하의 낮은 전압을 가진다. PSS-carbon 복합 음극은 0.1, 0.5, 1, 10C에서 각각 용량 $519.6mAh\;g^{-1}$, $461.2mAh\;g^{-1}$, $411.8mAh\;g^{-1}$, $315.9mAh\;g^{-1}$의 첫 번째 방전 용량을 가지면 30사이클까지 안정적인 주기 특성을 보여준다. Polystyrene 구조와 sulfonate 기능 기를 갖는 PSS와의 탄소 복합 전극은 유기 이차전지의 전기화학적 특성을 향상 시키기 적합한 음극활 물질로 여겨 진다.

Keywords

References

  1. S. Renault, D. Brandell, T. Gustafsson, and K. Edstrom, 'Improving the electrochemical performance of organic Li-ion battery electrodes' Chem. Commum, 49, 1945-1947 (2013). https://doi.org/10.1039/c3cc39065a
  2. J. Kim, T. Artur V., T. Yim, and J. Mun, 'The influence of impurities in room temperature ionic liquid electrolyte for lithium ion batteries containing high potential cathode' J. the Korean Electrochem. Soc., 18, 51 (2015). https://doi.org/10.5229/JKES.2015.18.2.51
  3. Z. Song, and H. Zhou, 'Towards sustainable and versatile energy storage devices: an overview of organic electrode materials' Energy Environ. Sci., 6, 2280 (2013). https://doi.org/10.1039/c3ee40709h
  4. J.K. Kim, Y. Kim, S. Park, H. Ko, and Y. Kim, 'Encapsulation of organic active materials in carbon nanotubes for application to high-electrochemical-performance sodium batteries' Energy Environ. Sci., 9, 1264 (2016). https://doi.org/10.1039/C5EE02806J
  5. R. Yue, H. Wang, D. Bin, J. Xu, Y. Du, W Lu, and J. Guo, 'Facile one-pot synthesis of Pd-PEDOT/graphene nanocomposites with hierarchical structure and high electrocatalytic performance for ethanol oxidation' J. Mater. Chem., A 3, 1077 (2015). https://doi.org/10.1039/C4TA05131A
  6. S. S. Karade, and B. R. Sankapal, 'Room temperature PEDOT:PSS encapsulated MWCNTs thin film for electrochemical supercapacitor' J. Electroanalytical Chem., 771, 80 (2016). https://doi.org/10.1016/j.jelechem.2016.04.012
  7. J. Jeong, H. Lee, H. Lee, M.-H. Ryou, and Y.M. Lee, 'Effects of lithium bis(Oxalate) borate as an electrolyte additive on high-temperature performance of Li(Ni1/3Co1/3Mn1/3)O2/graphite cells' J. the Korean Electrochem. Soc., 18, 58 (2015). https://doi.org/10.5229/JKES.2015.18.2.58
  8. J.K. Kim, J. Scheers, T.J. Park, and Y. Kim, 'Superior ion-conducting hybrid solid electrolyte for all-solid-state batteries' ChemSusChem, 8, 636 (2015). https://doi.org/10.1002/cssc.201402969
  9. D. Aurbach, K. Gamolsky, B. Markovsky, Y. Gofer, M. Schmidt, and U. Heider, 'On the use of vinylene carbonate (VC) as an additive to electrolyte solutions for Li-ion batteries' Electrochim. Acta, 47, 1423 (2002). https://doi.org/10.1016/S0013-4686(01)00858-1
  10. J. Kalhoff, G.G. Eshetu, D. Bresser and S. Passerini, 'Safer electrolytes for lithium-ion batteries: State of the art and perspectives' ChemSusChem, 8, 2154 (2015). https://doi.org/10.1002/cssc.201500284