• Bulletin of the Korean Chemical Society
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• v.24 no.8
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• pp.1102-1106
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• 2003

In our previous work we developed the Finite Field method in order to calculate the fifth-order Raman response. The method was applied to calculate various polarization components of the two-dimensional response of liquid $CS_2$. So far, all calculations relied on the dipole-induced dipole. Accurate time-dependent density functional theory calculations have shown that this model has big discrepancies, when molecules are close together as in the liquid. We now report results of investigations on the importance of multipole and electron overlap effects on the polarizability and the fifth-order Raman response. It is shown that these collision effects, especially the induced multipoles, are crucial in the description of the fifth-order response. The impact is found to be especially pronounced for the χ_{mmzzzz}^{(5)}$response that is solely due to interaction induced effects. The calculated response will be compared with various experimental results.

• Tribology and Lubricants
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• v.26 no.5
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• pp.272-276
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• 2010

Aminated oilve oil derivative as the new organic disperse phases of the water soluble metal working fluid has been synthesized and tribological properties of the aqueous solutions composed of aminated olive oil derivative investigated using Four Ball Wear Tester and Falex EP Tester. The formulated aqueous solutions showed higher antiwear and extreme pressure properties and also lower friction coefficient. On the basis of the the results, water soluble aminated oilve oil derivative showed excellent tribological properties due to the polarizability of oleic acid derivative composed of majority part in oilve oil.

• Proceedings of the Korean Society of Tribologists and Lubrication Engineers Conference
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• 2004.11a
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• pp.323-329
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• 2004

The electrical and rheological properties pertaining to the electrorheological (ER) behavior of chitosan derivatives, chitosan, chitosan ammonium salt and chitosan phosphate suspensions in silicone oil were investigated. Chitosan derivative suspensions showed a typical ER response (Bingham flow behavior) upon application of an electric field. However, chitosan phosphate suspension exhibited an excellent shear yield stress compared with chitosan and chitosan ammonium salt suspensions. The difference in behavior results from the difference in the conductivity of the disperse phases due to the difference of their polarizability. The shear stress for the chitosan, chitosan ammonium salt and chitosan phosphate suspensions exhibited a linear dependence on the volume fraction of particles and 1.18 ,1.41 and 1.67 powers of the electric field. On the basis of the experimental results, the newly synthesized chitosan derivative suspensions found to be an ER fluid.

• KSTLE International Journal
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• v.2 no.1
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• pp.71-74
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• 2001

The electrorheological(ER) performance of a chitosan sebaciate suspension in silicone oil was investigated by varying the electric fields, volume fractions of particles, and shear rates, respectively. The chitosan sebacicate susepnsion showed a typical ER response caused by the polarizability of an amide polar group and shear yield stress due to the formation of multiple chains upon application of an electric field. The shear stress for the suspension exhibited a linear dependence on the volume fraction of particles and an electric field power of 1.88. On the basis of the results, the newly synthesized chitosan sebacicate suspension was found to be an anhydrous ER fluid.

• KSTLE International Journal
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• v.5 no.2
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• pp.49-51
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• 2004

The electrical and rheological properties pertaining to the electrorheological (ER) behavior of chitosan derivatives, chitosan, chitosan ammonium salt and chitosan phosphated suspensions in silicone oil were investigated. Chitosan derivative suspensions showed a typical ER response (Bingham flow behavior) upon application of an electric field. However, chitosan phosphate suspension exhibited an excellent shear yield stress compared with chitosan and chitosan ammonium salt suspensions. The difference in behavior results from the difference in the conductivity of the disperse phases due to the difference of their polarizability. The shear stress for the chitosan, chitosan ammonium salt and chitosan phosphate suspensions exhibited a linear dependence on the volume fraction of particles and 1.18, 1.41 and 1.67 powers of the electric field. On athe basis of the experimental results, the newly synthesized chitosan dervative suspensions found to be an ER fluid.

• Electrical & Electronic Materials
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• v.9 no.3
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• pp.265-269
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• 1996

We have studied the effect of the mesogenic core of nematic liquid crystals (NLCs) for polar (out-of-plane tilt) anchoring strength and surface order parameter on rubbed polyimide (PI) surfaces. The order of polar anchoring strength for NLCs on rubbed PI surfaces is 5CB > PCH5 > CCH5. From the above results, we suggest that the polar anchoring strength depends on the polarizability of the NLCs. The surface order parameter for NLCs is 5CB > PCH5 > CCH5 on rubbed PI surfaces. We conclude that the polar anchoring strength is strongly related to the surface order parameter on rubbed PI surfaces.

• Journal of the Korean Institute of Telematics and Electronics A
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• v.30A no.2
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• pp.29-35
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• 1993

A guided-wave TE to TM mode converter was demonstrated by using of the off-diagonal electrooptic coefficients in LiTaO$_{3}$. The input mode is coupled to the other orthogonal mode by the electrooptically induced off-diagonal polarizability. Compared with LiNbO$_{3}$, LiTaO$_{3}$ provides a smaller birefringence and thus a larger phase match period and larger optical bnadwidth. A novel electrode structure allowed a first-order Bragg-coupling phase matching. TE/TM mode conversion efficiency of 90% at 25 [V] was demonstrated with ${\lambda}$=0.63$\mu$m He-Ne laser.

• Journal of the Korean Chemical Society
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• v.25 no.3
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• pp.145-151
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• 1981

The intrinsic reactivity of $S_N2$reaction in the gas phase was discussed MO theoretically (CNDO/2). We investigated the changes in geometry and electronic structure by means of the partial geometry optimization for reactantes, transition states, and products with various nucleophiles and leaving groups. We found that it was possible to discuss qualitatively the reactivity of $S_N2$ reaction with CNDO/2 MO calculation and the reactivity was controlled by basicity and of induced polarizability.

• Journal of the Korean Chemical Society
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• v.57 no.4
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• pp.461-471
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• 2013

Optimized geometrical structure, atomic charges, molecular electrostatic potential, nonlinear optical (NLO) effects and thermodynamic properties of the title compound N-(2,5-methylphenyl)salicylaldimine (I) have been investigated by using ab initio quantum chemical computational studies. Calculated results showed that the enol form of (I) is more stable than keto form. The solvent effect was investigated for obtained molecular energies, hardneses and the atomic charge distributions of (I). Natural bond orbital and frontier molecular orbital analysis of the title compound were also performed. The total molecular dipole moment (${\mu}$), linear polarizability (${\alpha}$), and first-order hyperpolarizability (${\beta}$) were calculated by B3LYP method with 6-31G(d), 6-31+G(d,p), 6-31++G(d,p), 6-311+G(d) and 6-311++G(d,p) basis sets to investigate the NLO properties of the compound (I). The standard thermodynamic functions were obtained for the title compound with the temperature ranging from 200 to 450 K.

• KSTLE International Journal
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• v.3 no.1
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• pp.23-25
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• 2002

The electrorheological (ER) behavior of amino coated chitosan phosphate suspension in silicone oil is investigated. Amino coated chitosan phosphate suspension shows a typical ER response (Bingham flow behavior) upon application of an electric field due to the polarizability of phosphoryl polar group. The shear stress for the suspension exhibits a linear dependence on an electric field power of 1.94. The values of structure factors $A_s$obtains 2 far mine coated chitosan phosphate suspension and it may be due to the formation of multiple chains upon application of the electric field. Throughtout the experimental results, amino coated chitosan phosphate suspension shows good dispersion stability and found to be an anhydrous ER fluid.