• Title/Summary/Keyword: optimal matrix

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Simulation on Optimum Doping Levels in Si Solar Cells

  • Choe, Kwang Su
    • Korean Journal of Materials Research
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    • v.30 no.10
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    • pp.509-514
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    • 2020
  • The two key variables of an Si solar cell, i.e., emitter (n-type window layer) and base (p-type substrate) doping levels or concentrations, are studied using Medici, a 2-dimensional semiconductor device simulation tool. The substrate is p-type and 150 ㎛ thick, the pn junction is 2 ㎛ from the front surface, and the cell is lit on the front surface. The doping concentration ranges from 1 × 1010 cm-3 to 1 × 1020 cm-3 for both emitter and base, resulting in a matrix of 11 by 11 or a total of 121 data points. With respect to increasing donor concentration (Nd) in the emitter, the open-circuit voltage (Voc) is little affected throughout, and the short-circuit current (Isc) is affected only at a very high levels of Nd, exceeding 1 × 1019 cm-3, dropping abruptly by about 12%, i.e., from Isc = 6.05 × 10-9 A·㎛-1, at Nd = 1 × 1019 cm-3 to Isc = 5.35 × 10-9 A·㎛-1 at Nd = 1 × 1020 cm-3, likely due to minority-carrier, or hole, recombination at the very high doping level. With respect to increasing acceptor concentration (Na) in the base, Isc is little affected throughout, but Voc increases steadily, i.e, from Voc = 0.29 V at Na = 1 × 1012 cm-3 to 0.69 V at Na = 1 × 1018 cm-3. On average, with an order increase in Na, Voc increases by about 0.07 V, likely due to narrowing of the depletion layer and lowering of the carrier recombination at the pn junction. At the maximum output power (Pmax), a peak value of 3.25 × 10-2 W·cm-2 or 32.5 mW·cm-2 is observed at the doping combination of Nd = 1 × 1019 cm-3, a level at which Si is degenerate (being metal-like), and Na = 1 × 1017 cm-3, and minimum values of near zero are observed at very low levels of Nd ≤ 1 × 1013 cm-3. This wide variation in Pmax, even within a given kind of solar cell, indicates that selecting an optimal combination of donor and acceptor doping concentrations is likely most important in solar cell engineering.

Application and Validation of an Optimal Analytical Method using QuEChERS for the determination of Tolpyralate in Agricultural Products (QuEChERS법을 활용한 농산물 중 제초제 Tolpyralate의 최적 분석법 선발 및 검증)

  • Lee, Han Sol;Park, Ji-Su;Lee, Su Jung;Shin, Hye-Sun;Kim, Ji-Young;Yun, Sang Soon;Jung, Yong-hyun;Oh, Jae-Ho
    • Korean Journal of Environmental Agriculture
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    • v.39 no.3
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    • pp.246-252
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    • 2020
  • BACKGROUND: Pesticides are broadly used to control weeds and pests, and the residues remaining in crops are managed in accordance with the MRLs (maximum residue limits). Therefore, an analytical method is required to quantify the residues, and we conducted a series of analyses to select and validate the quick and simple analytical method for tolpyralate in five agricultural products using QuEChERS (quick, easy, cheap, effective, rugged and safe) method and LC-MS/MS (liquid chromatography-tandem mass spectrometry). METHODS AND RESULTS: The agricultural samples were extracted with acetonitrile followed by addition of anhydrous magnesium sulfate, sodium chloride, disodium hydrogencitrate sesquihydrate and trisodium citrate dihydrate. After shaking and centrifugation, purification was performed with d-SPE (dispersive-solid phase extraction) sorbents. To validate the optimized method, its selectivity, linearity, LOD (limit of detection), LOQ (limit of quantitation), accuracy, repeatability, and reproducibility from the inter-laboratory analyses were considered. LOQ of the analytical method was 0.01 mg/kg at five agricultural products and the linearity of matrix-matched calibration were good at seven concentration levels, from 0.0025 to 0.25 mg/L (R2≥0.9980). Mean recoveries at three spiking levels (n=5) were in the range of 85.2~112.4% with associated relative standard deviation values less than 6.2%, and the coefficient of variation between the two laboratories was also below 13%. All optimized results were validated according to the criteria ranges requested in the Codex Alimentarius Commission (CAC) and Ministry of Food and Drug Safety (MFDS) guidelines. CONCLUSION: In conclusion, we suggest that the selected and validated method could serve as a basic data for detecting tolpyralate residue in imported and domestic agricultural products.

A Marriage Problem Algorithm Based on Duplicated Sum of Inter-Preference Moving Method (중복된 최소 상호-호감도 합 이동방법을 적용한 결혼문제 알고리즘)

  • Lee, Sang-Un
    • Journal of the Korea Society of Computer and Information
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    • v.20 no.5
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    • pp.107-112
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    • 2015
  • This paper proposes a simplified algorithm devised to obtain optimal solution to the marriage problem. In solving this problem, the most widely resorted to is the Gale-Shapley algorithm with the time complexity of $O({\mid}V{\mid}^2{\mid}E{\mid})$. The proposed algorithm on the other hand firstly constructs a $p_{ij}$ matrix of inter-preference sum both sexes' preference over the opposite sex. Secondly, it selects $_{min}p_i$ from each row to establish ${\mid}p_{.j}{\mid}{\geq}2,j{\in}S$, ${\mid}p_{.j}{\mid}=1$, $j{\in}H$, ${\mid}p_{.j}{\mid}=0$, $j{\in}T$. Finally, it shifts $_{min}\{_{min}p_{ST},p_{SH}+p_{HT\}$ for $_{min}P_{ST}$ of $S{\rightarrow}T$ and $p_{SH}+p_{HT}$, $p_{HT}<_{min}p_{ST}$ of $S{\rightarrow}H$, $H{\rightarrow}T$. The proposed algorithm has not only improved the Gale-Shapley's algorithm's complexity of $O({\mid}V{\mid}^2{\mid}E{\mid})$ to $O({\mid}V{\mid}^2)$ but also proved its extendable use on unbalanced marriage problems.

Calculation of Stability Number of Tetrapods Using Weights and Biases of ANN Model (인공신경망 모델의 가중치와 편의를 이용한 테트라포드의 안정수 계산 방법)

  • Lee, Jae Sung;Suh, Kyung-Duck
    • Journal of Korean Society of Coastal and Ocean Engineers
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    • v.28 no.5
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    • pp.277-283
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    • 2016
  • Tetrapod is one of the most widely used concrete armor units for rubble mound breakwaters. The calculation of the stability number of Tetrapods is necessary to determine the optimal weight of Tetrapods. Many empirical formulas have been developed to calculate the stability number of Tetrapods, from the Hudson formula in 1950s to the recent one developed by Suh and Kang. They were developed by using the regression analysis to determine the coefficients of an assumed formula using the experimental data. Recently, software engineering (or machine learning) methods are introduced as a large amount of experimental data becomes available, e.g. artificial neural network (ANN) models for rock armors. However, these methods are seldom used probably because they did not significantly improve the accuracy compared with the empirical formula and/or the engineers are not familiar with them. In this study, we propose an explicit method to calculate the stability number of Tetrapods using the weights and biases of an ANN model. This method can be used by an engineer who has basic knowledge of matrix operation without requiring knowledge of ANN, and it is more accurate than previous empirical formulas.

Development of Matrix for the Immobilization of High Level Radioactive Waste : Study on the Synthesis of Ce-pyrochlore (고준위 핵페기물의 고정화를 위한 메트릭스 개발 : Ce파이로클로어 합성 연구)

  • ;;;Yudintsev, S. V²
    • Economic and Environmental Geology
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    • v.35 no.2
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    • pp.97-102
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    • 2002
  • Ce-pyrochlore (CaCe $Ti_2 $O_7)was synthesized to study its properties and phase relations in CaO-Ce $O_2$-Ti $O_2$ system because Ce-pyrochlore was known as a promising material for the immobilization of radioactive actinide. The samples were prepared from the high purity starling materials under the pressure of 200~400 kg/$\textrm{cm}^2$ at room temperature, and annealed at 1000~ 150$0^{\circ}C$. The Synthesized samples were analysed and indentified with XRD and SEM/EDS methods. The optimal formation condition of Ce-pyrochlore was at 130$0^{\circ}C$ under $O_2$ atmosphere and the chemical composition of it wasCa$Ca_{1-x}Ti_{2-y}O_{7-x-2y}$(x=0.03-0.05, y=0.02~0.04) At temperature between 130$0^{\circ}C$ 140$0^{\circ}C$, Ce-pyrochlore underwent rapidly the incongruent decomposition to perovskite. Ce-perovskite, a partial solid solution between perovskite and loparite (C $e_{0.66}$Ti $O_3$), was observed as a major phase above 140$0^{\circ}C$.>.

Elution Buffers for Human Enteric Viruses in Vegetables with Applications to Norovirus Detection

  • Moon, Aerie;Ahn, Jaehyun;Choi, Weon Sang
    • Journal of Food Hygiene and Safety
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    • v.28 no.4
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    • pp.287-292
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    • 2013
  • The efficient elution of viruses from contaminated food is a critical step for its detection. In this study, conditions optimal for enteric viral recovery from three leafy vegetables (cabbage, lettuce, sesame leaf) and three root vegetables (carrot, onion, mooli) were analyzed to find common buffers (statistically not different) applicable to the leafy and root vegetables. Viral recovery varied depending on the food matrices or elution buffers. Buffer solutions containing 0.25M threonine / 0.3M NaCl (pH 9.5) or 0.25M glycine / 0.14M NaCl (pH 9.5) could efficiently recover poliovirus from five out of six vegetables. The threonine buffer was applied to one leafy vegetable (sesame) and one root vegetable (carrot) for genogroup II norovirus (NoV) detection. The detection sensitivity was significantly higher from the leafy vegetable compared to the root vegetable. The use of these common elution buffers should facilitate the detection of low levels of NoV and other enteric viruses in a wide range of vegetables.

A Study on the Development and Dielectric Properties of Insulating Materials for Super-Conductor -For Matrix of Composite Materials- (초전도체 절연용 재료의 전기적 절연 특성과 개발에 관한 연구-복합 재료의 매트릭스에 대하여-)

  • 조정수;최세원;김종경;이규철;이종호
    • The Transactions of the Korean Institute of Electrical Engineers
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    • v.38 no.7
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    • pp.511-523
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    • 1989
  • This paper investigates physical properties, the electrical and mechanical characteristics of the epoxy resin with different curing methods and postcuring conditions at room temperature or cryogenic temperature (LN2). According to the results in this paper, first, it is found that the physical properties, electrical and mechanical characteristics of the epoxy resin are largely affected by the interior reaction temperature on the curing. Thus, in the fabrication of the sample, several excellent characteristics of the sample are obtained by controlling the interior reaction temperature of the epoxy resin. Second, the sample having optimal electrical and mechanical characteristics is obtained for the repetitive post-curing method at 100c in view point of the post-curing conditions of the epoxy resin. Third, it appears that tan and characteristics at LN2 temperature are about half of those at room temperature. Fourth, it appears that the dielectric strength of the epoxy resin at LN2 temperature is higher by about 0.6-1.0 MV/cm than that at room temperature. The heat-aging of the epoxy resin due to the micro-defect and excess fever-movement have been noticed to affect dielectric strength at LN2 temperature more significantly than at room temperature.

A Study on Shape Optimization of Distributed Actuators using Time Domain Finite Element Method (시간유한요소법을 이용한 분포형 구동기의 형상최적화에 관한 연구)

  • Suk, Jin-Young;Kim, You-Dan
    • Journal of the Korean Society for Aeronautical & Space Sciences
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    • v.33 no.9
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    • pp.56-65
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    • 2005
  • A dynamic analysis method that freezes a time domain by discretization and solves the spatial propagation equation has a unique feature that provides a degree of freedom on spatial domain compared with the space discretization or space-time discretization finite element method. Using this feature, the time finite element analysis can be effectively applied to optimize the spatial characteristics of distributed type actuators. In this research, the time domain finite element method was used to discretize the model. A state variable vector was used in the discretization to include arbitrary initial conditions. A performance index was proposed on spatial domain to consider both potential and vibrational energy, so that the resulting shape of the distributed actuator was optimized for dynamic control of the structure. It is assumed that the structure satisfies the final rest condition using the realizable control scheme although the initial disturbance can affect the system response. Both equations on states and costates were derived based on the selected performance index and structural model. Ricatti matrix differential equations on state and costate variables were derived by the reconfiguration of the sub-matrices and application of time/space boundary conditions, and finally optimal actuator distribution was obtained. Numerical simulation results validated the proposed actuator shape optimization scheme.

Characterizations of Cellulose Blend Films: Morphology, Mechanical Property, and Gas Permeability (셀룰로오스 블렌드 필름의 특성연구 : 모폴로지, 기계적 성질, 및 가스 투과도)

  • Jang, Seo-Won;Chang, Jin-Hae
    • Polymer(Korea)
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    • v.32 no.1
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    • pp.63-69
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    • 2008
  • The mechanical properties and morphologies of cellulose blends with two different additives were compared. Poly (vinyl alcohol) (PVA) of ethylene glycol (EG) were used as additives in the formation of cellulose blends through the solution blending. The properties of blends were varied with the additive content in the polymer matrix. The ultimate tensile strength and initial modulus of the cellulose blends were highest for a blend PVA content of 30 wt% and for a blend EG content of 10 wt%, respectively. Ternary blended systems of composition of cellulose/PVA (70/30=w/w)/EG were also prepared by the solution blending method with different EG contents. The mechanical properties of these systems were found to be optimal for EG contents of up to 40 wt%. The mechanical properties of the cellulose ternary blend films were superior to those of the cellulose binary blend films. The oxygen permeability transmission rate ($O_2TR$) monotonically decreased with increasing EG content in the ternary blend films. Overall, the mechanical properties of the cellulose blend films were found to be better than those of pure cellulose films.

Characterizations of Lyocell and Its Blended Nanocomposite Film: Morphology and Mechanical Property (라이오셀 및 라이오셀 블렌드 나노복합체 필름의 특성 연구 : 모폴로지 및 기계적 성질)

  • Jang, Seo-Won;Chang, Jin-Hae
    • Polymer(Korea)
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    • v.31 no.3
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    • pp.221-227
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    • 2007
  • The mechanical properties and morphologies of lyocell and its blend we compared. Poly (vinyl alcohol) (PVA) was used as a filler in blends with lyocell produced through solution blending. The variations of their properties with polymer matrix filler content are discussed. The ultimate tensile strength of the PVA/lyocell blend is highest for a blend lyocell content of 30 wt%, and decreases as the lyocell content is increased up to 40 wt%. The variations in the initial moduli of the blends with filler content are similar. Lyocell and its blended hybrid films were prepared by the solution intercalation method, using dodecyltriphenylphosphonium-mica ($C_{12}PPh$-Mica) as the organoclay. The variations of the mechanical tensile properties of the hybrids with the organoclay content were examined. These properties were found to be optimal for an organoclay content of up to 5 wt%. However, the mechanical tensile properties of the PVA/Lyocell (w/w=30/70) blended hybrid films were found to decrease linearly with increases in organoclay content from 1 to 5 wt%.