• Bulletin of the Korean Chemical Society
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• 제35권7호
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• pp.1985-1988
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• 2014

$Cu_2ZnSnSe_4$ (CZTSe) thin films were synthesized on transparent conducting oxide glass substrates via a simple, non-toxic, and low-cost process using a precursor solution paste. A three-step heating process (oxidation, sulfurization, and selenization) was employed to synthesize a CZTSe thin film as an absorber layer for use in thin-film solar cells. In particular, we focused on the effects of sulfurization conditions on CZTSe film formation. We found that sulfurization at $400^{\circ}C$ involves the formation of secondary phases such as $CuSe_2$ and $Cu_2SnSe_3$, but they gradually disappeared when the temperature was increased. The formed CZTSe thin films showed homogenous and good crystallinity with grain sizes of approximately 600 nm. A solar cell device was tentatively fabricated and showed a power conversion efficiency of 2.2% on an active area of 0.44 $cm^2$ with an open circuit voltage of 365 mV, a short current density of 20.6 $mA/cm^2$, and a fill factor of 28.7%.

• 한국도로학회논문집
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• 제16권6호
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• pp.51-57
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• 2014

PURPOSES : An conventional method for electric power generation is converting thermal energy into mechanical energy then to electrical energy. Due to environmental issues such as global warming related with $CO_2$ emission etc., were the limiting factor for the energy resources which resulting in extensive research and novel technologies are required to generate electric power. Thermal energy harvesting using thermoelectric generator is one of energy harvesting technologies due to diverse advantages for new green technology. This paper presents a possibility of application of the thermoelectric generator's application in the direct exchange of waste solar energy into electrical power in road space. METHODS : To measure generated electric power of the thermoelectric generator, data logger was adopted as function of experimental factors such as using cooling sink, connection methods etc. Also, the thermoelectric generator、s behavior at low ambient temperature was investigated as measurement of output voltage vs. elapsed times. RESULTS : A few temperature difference between top an bottom of the thermoelectric generator is generated electric voltage. Components of an electrical circuit can be connected in various ways. The two simplest of these are called series and parallel and occur so open. Series shows slightly better performance in this study. An installation of cooling sink in the thermoelectric generator system was enhanced the output of power voltage. CONCLUSIONS : In this paper, a basic concepts of thermoelectric power generation is presented and applications of the thermoelectric generator to waste solar energy in road is estimated for green energy harvesting technology. The possibility of usage of thermoelectric technology for road facilities was found under the ambient thermal gradient between two surfaces of the thermoelectric module. An experiment results provide a testimony of the feasibility of the proposed environmental energy harvesting technology on the road facilities.

• 조명전기설비학회논문지
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• 제19권3호
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• pp.75-84
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• 2005

유도전동기 구동시스템의 예상치 않은 고장은 많은 산업 응용분야에서 심각한 문제를 초래시킬 수 있으므로, 유도전동기 구동을 위한 전압형 PWM 인버터의 고장진단에 대해 연구한다. 진단의 고려 대상은 정류기 다이오드, 스위칭 장치 및 입력단의 개방회로 고장이며, 진단신호는 전동기 전류로부터 유도한다. 고장의 특징추출은 dq-전류 경로의 크기를 이용하였고, 진단은 PCA와 LDA를 적용한다. 또한, 본 논문에서는 일반적인 중${\cdot}$소형 유도전동기 구동 시스템의 제어기에 진단 소프트웨어를 추가하여 사용하는 것에 대한 가능성을 제시하며, 그에 관련해 수행속도에 따른 진단결과들을 보여준다. 최종적으로, MATLAB을 이용하여 인버터의 고장진단에 대한 모의실험을 수행 하였고, 제안된 알고리즘의 유용성을 검증하였다.

• Asian-Australasian Journal of Animal Sciences
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• 제24권3호
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• pp.400-406
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• 2011

An experiment was carried out to assess the effects of xylanase supplementation on the performance, net energy and gut microflora of broilers fed a wheat-based diet. Day-old male broiler chicks were allocated to two dietary treatments. Each treatment was composed of six replicate cages of seven broilers per cage. The diets were wheat-based and offered as mash. The treatments included i) basal diet deficient in metabolizable energy; and ii) basal diet supplemented with a commercial xylanase added at 4,000 U/kg feed. Bird performance, nutrient utilization and gut microbial populations were measured. Heat production and net energy were determined using an auto-control, open circuit respiration calorimetry apparatus. Results showed that exogenous xylanase supplementation improved feed conversion efficiency (p<0.05) and increased diet AME (+4.2%; p<0.05), as well as heat production (HP), net energy for production (NEp), production of $CO_2$, and consumption of $O_2$. The respiratory quotient (RQ) was also increased (p<0.01) by the addition of xylanase. NEp value was increased by 26.1% while daily heat production per kg metabolizable body weight was decreased by 26.2% when the xylanase was added. Xylanase supplementation numerically increased the ileal digestibility of protein and energy by 3 and 6 percentage units respectively (p>0.05). The ileal digestibility of hemicellulose was significantly improved by xylanase addition (p<0.05).

• 한국진공학회:학술대회논문집
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• 한국진공학회 2014년도 제46회 동계 정기학술대회 초록집
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• pp.471.2-471.2
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• 2014

We demonstrate here that an improvement in precursor film density (green density) leads to a great enhancement in the photovoltaic performance of CuInSe2 (CISe) thin film solar cells fabricated with Cu-In nanoparticle precursor films via chemical solution deposition. A cold-isostatic pressing (CIP) technique was applied to uniformly compress the precursor film over the entire surface (measuring 3~4 cm2) and was found to increase its relative density (particle packing density) by ca. 20%, which resulted in an appreciable improvement in the microstructural features of the sintered CISe film in terms of lower porosity, reduced grain boundaries, and a more uniform surface morphology. The low-bandgap (Eg=1.0 eV) CISe PV devices with the CIP-treated film exhibited greatly enhanced open-circuit voltage (VOC, from 0.265 V to 0.413 V) and fill factor (FF, from 0.34 to 0.55), as compared to the control devices. As a consequence, an almost 3-fold increase in the average power conversion efficiency, 3.0 to 8.2% (with the highest value of 9.02%), was realized without an anti-reflection coating. A diode analysis revealed that the enhanced VOC and FF were essentially attributed to the reduced reverse saturation current density (j0) and diode ideality factor (n). This is associated with the suppressed recombination, likely due to the reduction in recombination sites such as grain/air surfaces (pores), inter-granular interfaces, and defective CISe/CdS junctions in the CIP-treated device. From the temperature dependences of VOC, it was confirmed that the CIP-treated devices suffer less from interface recombination.

• 한국진공학회:학술대회논문집
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• 한국진공학회 2014년도 제46회 동계 정기학술대회 초록집
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• pp.470.2-470.2
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• 2014

RF-PECVD 장치에 의해 증착된 실리콘 질화막(SiNx)은 결정질 실리콘 태양전지에서 반사 방지막 효과 및 우수한 표면 패시베이션 특성을 제공하는 것으로 알려져 있다. 본 논문에서는 실리콘 질화막의 패시베이션 특성을 향상시키기 위해서 공정온도를 $400^{\circ}C$로 고정하고 공정압력, 가스비, RF (radio frequency) power를 가변하였다. 이 때의 실리콘 질화막의 굴절률 및 두께는 각각 2.0, 80 nm로 증착하여 그에 따른 특성에 대해 분석하였다. 공정 압력이 감소할수록 실리콘 질화막이 증착된 결정질 실리콘 태양전지의 유효 반송자 수명이 증가함을 보였고, 반면에 증착속도는 감소하였다. 또한 RF-power 500 W에서 실리콘 질화막이 증착된 결정질 실리콘 태양전지의 유효 반송자 수명이 상대적으로 높았으며 출력이 올라갈수록 증착속도가 증가하였다. 결과적으로 결정질 실리콘 태양전지에 증착한 실리콘 질화막은 0.8torr 공정 압력과 RF-power 500 W에서 $38.8{\mu}s$로 가장 좋은 유효 반송자 수명을 확인하였다. 위의 결과를 바탕으로 결정질 실리콘 태양전지를 제작하였고 향상된 패시베이션 특성을 갖는 실리콘 질화막의 조건을 찾기 위해서 개방전압(open circuit voltage)을 비교하였다. 공정압력 0.8 torr, RF-power 500 W에서 가장 높은 결과를 보였으며 이는 유효 반송자 수명과 유사한 결과를 나타냈다. 하지만 낮은 FF (fill factor)로 인해 변환 효율이 낮은 결과를 보였다. 태양전지 제작시 낮은 fill factor를 보인 이유와 위의 단점을 보완하기 위해 추가 실험을 수행하였으며, 개선된 fill factor를 통해 18.3% 효율의 태양전지를 제작하였다.

• 한국진공학회:학술대회논문집
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• 한국진공학회 2014년도 제46회 동계 정기학술대회 초록집
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• pp.466.2-466.2
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• 2014

The Quantum dot (QD) solar cells have been under active research due to their high light harvesting efficiencies and low fabrication cost. In spite of these advantages, there have been some problems on the charge collection due to the limitation of the diffusion length. The modification of advanced nanostructure is capable of solving the charge collection problem by increasing diffusion length of electron. One dimensional nanomaterials such as nanorods, nanowires, and nanotubes may enhance charge collection efficiency in QD solar cells. In this study, we synthesized $TiO_2$ anatase nanorod arrays with length of 200 nm by two-step sol-gel method. The morphology and crystal structure for the nanorod were characterized by using scanning electron microscopy (SEM), transmission electron microscopy (TEM), and X-ray diffraction (XRD). The anatase nanorods are single-crystalline and possess preferred orientation along with (001) direction. The photovoltaic properties for the heterojunction structure QD solar cells based on the anatase nanorod were also characterized. Compared with conventional $TiO_2$ nanoparticle based QD solar cells, these nanostructure solar cells exhibited better charge collection properties due to long life time measured by transient open circuit studies. Our findings demonstrate that the single crystalline anatase nanorod arrays are promising charge transport semiconductors for heterojunction QD solar cells.

• 전력전자학회논문지
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• 제14권4호
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• pp.333-342
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• 2009

중성점 클램핑 방식(Neutral Point Clamped) 인버터로 알려져 있는 3레벨 NPC 인버터는 그 구조적 특성상 직류-링크(DC-link) 중성점(Neutral Point)에서 전압이 변동한다. 지금까지 많은 논문에서 이 문제에 대한 연구가 진행되었고 다양한 형태의 해결책들이 제시되었다. 그러나 인버터 내부에서 고장이 발생하여 그에 따른 고장허용제어가 NPC 인버터 시스템에 적용되었을 경우 중성점 전압변동은 정상 운전 시 나타나는 전압변동과 다르게 나타나기 때문에 고장허용 제어에 따른 중성점 전압변동에 대한 분석이 필요하다. 본 논문에서는 삼각파 비교 변조방법을 시스템에 적용하였을 경우 정상운전과 고장 발생 과 고장허용 제어 적용 시 직류-링크 중성점 전압 변동이 어떤 양상으로 나타나는지 분석하고 고장허용 제어에 의한 NPC 인버터의 고장검출 시간과 커패시터의 용량 사이의 관계를 고찰하였다. 시뮬레이션과 실험 결과를 이용하여 이론적 분석의 타당성을 검증하였다.

• Journal of Power Electronics
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• 제13권4호
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• pp.679-691
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• 2013

High-power electromagnetic transmitter power supplies are an important part of deep geophysical exploration equipment. This is especially true in complex environments, where the ability to produce a highly accurate and stable output and safety through redundancy have become the key issues in the design of high-power electromagnetic transmitter power supplies. To solve these issues, a high-frequency switching power cascade based emission power supply is designed. By combining the circuit averaged model and the equivalent controlled source method, a modular mathematical model is established with the on-state loss and transformer induction loss being taken into account. A triple-loop control including an inner current loop, an outer voltage loop and a load current forward feedback, and a digitalized voltage/current sharing control method are proposed for the realization of the rapid, stable and highly accurate output of the system. By using a new algorithm referred to as GAPSO, which integrates a genetic algorithm and a particle swarm algorithm, the parameters of the controller are tuned. A multi-module cascade helps to achieve system redundancy. A simulation analysis of the open-loop system proves the accuracy of the established system and provides a better reflection of the characteristics of the power supply. A parameter tuning simulation proves the effectiveness of the GAPSO algorithm. A closed-loop simulation of the system and field geological exploration experiments demonstrate the effectiveness of the control method. This ensures both the system's excellent stability and the output's accuracy. It also ensures the accuracy of the established mathematical model as well as its ability to meet the requirements of practical field deep exploration.

• 한국표면공학회:학술대회논문집
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• 한국표면공학회 2017년도 춘계학술대회 논문집
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• pp.150.2-150.2
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• 2017

This research was conducted to investigate in detail the effect of $PO_4{^{3-}}$, $CO_3{^{2-}}$ and $F^-$ anions on the electrochemical properties of the thin air-formed oxide film-covered AZ31 Mg alloy. In this work, native air-formed oxide films on AZ31 Mg alloy samples were prepared by knife-abrading method and the changes in the electrochemical properties of the air-formed oxide film were investigated in electrolytes containing 0.01 M, 0.05 M and 0.1 M of $PO_4{^{3-}}$, $CO_3{^{2-}}$ and $F^-$ anions. It was observed that the trend of open circuit potential (OCP) transients changed only in the solution containing $PO_4{^{3-}}$ ions. The Nyquist plots obtained from electrochemical impedance spectroscopy (EIS) showed that the resistance of the new surface films formed in fluoride ion containing bath increased with the increase in concentration of fluoride ions but the resistance of surface films formed in carbonate ion containing bath decreased with the increase in concentration of carbonate ions. The potentiodynamic polarization curves illustrated that under anodic polarization, there was growth of porous passive layer only in fluoride ion containing solution while the surface layer formed in phosphate and carbonate ion containing solutions lost its passivity at high anodic potential of $2.5V_{Ag/AgCl}$.