• Bulletin of the Korean Chemical Society
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• v.32 no.7
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• pp.2279-2285
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• 2011

The geometries, electronic structures and absorption spectra of the two organic triphenylamine-based dyes TA-St-CA and TA-DM-CA, containing identical electron donors and acceptors but the different conjugated bridges, were studied by density functional theory (DFT) at the B3LYP and PBE1PBE levels, respectively. The influence of para-orientating methoxyl units on the electronic structures and light absorption properties of the dyes and the consequent photovoltaic performance of the dye-sensitized solar cells (DSSCs) were investigated in detail. The results indicate that the introduction of the para-orientating methoxyl units into the conjugated bridge induces the increased absorption wavelength as well as the more negative EHOMO corresponding to the bigger driving force $(E_{I^-/I^-_3}-E_{HOMO})$ for dye reduction, which together improve the photovoltaic performance of TA-DM-CA, although there is a decline of the open circuit voltage caused by the more negative $E_{LUMO}$.

• Bulletin of the Korean Chemical Society
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• v.35 no.7
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• pp.1985-1988
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• 2014

$Cu_2ZnSnSe_4$ (CZTSe) thin films were synthesized on transparent conducting oxide glass substrates via a simple, non-toxic, and low-cost process using a precursor solution paste. A three-step heating process (oxidation, sulfurization, and selenization) was employed to synthesize a CZTSe thin film as an absorber layer for use in thin-film solar cells. In particular, we focused on the effects of sulfurization conditions on CZTSe film formation. We found that sulfurization at $400^{\circ}C$ involves the formation of secondary phases such as $CuSe_2$ and $Cu_2SnSe_3$, but they gradually disappeared when the temperature was increased. The formed CZTSe thin films showed homogenous and good crystallinity with grain sizes of approximately 600 nm. A solar cell device was tentatively fabricated and showed a power conversion efficiency of 2.2% on an active area of 0.44 $cm^2$ with an open circuit voltage of 365 mV, a short current density of 20.6 $mA/cm^2$, and a fill factor of 28.7%.

• International Journal of Highway Engineering
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• v.16 no.6
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• pp.51-57
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• 2014

PURPOSES : An conventional method for electric power generation is converting thermal energy into mechanical energy then to electrical energy. Due to environmental issues such as global warming related with $CO_2$ emission etc., were the limiting factor for the energy resources which resulting in extensive research and novel technologies are required to generate electric power. Thermal energy harvesting using thermoelectric generator is one of energy harvesting technologies due to diverse advantages for new green technology. This paper presents a possibility of application of the thermoelectric generator's application in the direct exchange of waste solar energy into electrical power in road space. METHODS : To measure generated electric power of the thermoelectric generator, data logger was adopted as function of experimental factors such as using cooling sink, connection methods etc. Also, the thermoelectric generator、s behavior at low ambient temperature was investigated as measurement of output voltage vs. elapsed times. RESULTS : A few temperature difference between top an bottom of the thermoelectric generator is generated electric voltage. Components of an electrical circuit can be connected in various ways. The two simplest of these are called series and parallel and occur so open. Series shows slightly better performance in this study. An installation of cooling sink in the thermoelectric generator system was enhanced the output of power voltage. CONCLUSIONS : In this paper, a basic concepts of thermoelectric power generation is presented and applications of the thermoelectric generator to waste solar energy in road is estimated for green energy harvesting technology. The possibility of usage of thermoelectric technology for road facilities was found under the ambient thermal gradient between two surfaces of the thermoelectric module. An experiment results provide a testimony of the feasibility of the proposed environmental energy harvesting technology on the road facilities.

• Journal of the Korean Institute of Illuminating and Electrical Installation Engineers
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• v.19 no.3
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• pp.75-84
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• 2005

Since an unexpected fault of induction motor drive systems can cause serious troubles in many industrial applications, which the technique is required to diagnose faults of a voltage-fed PWM inverter for induction motor drives. The considered fault types are rectifier diodes, switching devices and input terminals with open-circuit faults, and the signal for diagnosis is derived from motor currents. The magnitude of dq-current trajectory is used for the feature extraction of a fault and PCA LDA are applied to diagnose. Also, we show results with respect to the execution time because of the possibility to use that a diagnosis software is embedded in the controllers of medium and small size induction motors drive for real-time diagnosis. After we performed various simulations for the fault diagnosis of the inverter, the usefulness of proposed algerian was verified.

• Asian-Australasian Journal of Animal Sciences
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• v.24 no.3
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• pp.400-406
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• 2011

An experiment was carried out to assess the effects of xylanase supplementation on the performance, net energy and gut microflora of broilers fed a wheat-based diet. Day-old male broiler chicks were allocated to two dietary treatments. Each treatment was composed of six replicate cages of seven broilers per cage. The diets were wheat-based and offered as mash. The treatments included i) basal diet deficient in metabolizable energy; and ii) basal diet supplemented with a commercial xylanase added at 4,000 U/kg feed. Bird performance, nutrient utilization and gut microbial populations were measured. Heat production and net energy were determined using an auto-control, open circuit respiration calorimetry apparatus. Results showed that exogenous xylanase supplementation improved feed conversion efficiency (p<0.05) and increased diet AME (+4.2%; p<0.05), as well as heat production (HP), net energy for production (NEp), production of $CO_2$, and consumption of $O_2$. The respiratory quotient (RQ) was also increased (p<0.01) by the addition of xylanase. NEp value was increased by 26.1% while daily heat production per kg metabolizable body weight was decreased by 26.2% when the xylanase was added. Xylanase supplementation numerically increased the ileal digestibility of protein and energy by 3 and 6 percentage units respectively (p>0.05). The ileal digestibility of hemicellulose was significantly improved by xylanase addition (p<0.05).

• Proceedings of the Korean Vacuum Society Conference
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• 2014.02a
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• pp.471.2-471.2
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• 2014

We demonstrate here that an improvement in precursor film density (green density) leads to a great enhancement in the photovoltaic performance of CuInSe2 (CISe) thin film solar cells fabricated with Cu-In nanoparticle precursor films via chemical solution deposition. A cold-isostatic pressing (CIP) technique was applied to uniformly compress the precursor film over the entire surface (measuring 3~4 cm2) and was found to increase its relative density (particle packing density) by ca. 20%, which resulted in an appreciable improvement in the microstructural features of the sintered CISe film in terms of lower porosity, reduced grain boundaries, and a more uniform surface morphology. The low-bandgap (Eg=1.0 eV) CISe PV devices with the CIP-treated film exhibited greatly enhanced open-circuit voltage (VOC, from 0.265 V to 0.413 V) and fill factor (FF, from 0.34 to 0.55), as compared to the control devices. As a consequence, an almost 3-fold increase in the average power conversion efficiency, 3.0 to 8.2% (with the highest value of 9.02%), was realized without an anti-reflection coating. A diode analysis revealed that the enhanced VOC and FF were essentially attributed to the reduced reverse saturation current density (j0) and diode ideality factor (n). This is associated with the suppressed recombination, likely due to the reduction in recombination sites such as grain/air surfaces (pores), inter-granular interfaces, and defective CISe/CdS junctions in the CIP-treated device. From the temperature dependences of VOC, it was confirmed that the CIP-treated devices suffer less from interface recombination.

• Proceedings of the Korean Vacuum Society Conference
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• 2014.02a
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• pp.470.2-470.2
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• 2014

RF-PECVD 장치에 의해 증착된 실리콘 질화막(SiNx)은 결정질 실리콘 태양전지에서 반사 방지막 효과 및 우수한 표면 패시베이션 특성을 제공하는 것으로 알려져 있다. 본 논문에서는 실리콘 질화막의 패시베이션 특성을 향상시키기 위해서 공정온도를 $400^{\circ}C$로 고정하고 공정압력, 가스비, RF (radio frequency) power를 가변하였다. 이 때의 실리콘 질화막의 굴절률 및 두께는 각각 2.0, 80 nm로 증착하여 그에 따른 특성에 대해 분석하였다. 공정 압력이 감소할수록 실리콘 질화막이 증착된 결정질 실리콘 태양전지의 유효 반송자 수명이 증가함을 보였고, 반면에 증착속도는 감소하였다. 또한 RF-power 500 W에서 실리콘 질화막이 증착된 결정질 실리콘 태양전지의 유효 반송자 수명이 상대적으로 높았으며 출력이 올라갈수록 증착속도가 증가하였다. 결과적으로 결정질 실리콘 태양전지에 증착한 실리콘 질화막은 0.8torr 공정 압력과 RF-power 500 W에서 $38.8{\mu}s$로 가장 좋은 유효 반송자 수명을 확인하였다. 위의 결과를 바탕으로 결정질 실리콘 태양전지를 제작하였고 향상된 패시베이션 특성을 갖는 실리콘 질화막의 조건을 찾기 위해서 개방전압(open circuit voltage)을 비교하였다. 공정압력 0.8 torr, RF-power 500 W에서 가장 높은 결과를 보였으며 이는 유효 반송자 수명과 유사한 결과를 나타냈다. 하지만 낮은 FF (fill factor)로 인해 변환 효율이 낮은 결과를 보였다. 태양전지 제작시 낮은 fill factor를 보인 이유와 위의 단점을 보완하기 위해 추가 실험을 수행하였으며, 개선된 fill factor를 통해 18.3% 효율의 태양전지를 제작하였다.

• Proceedings of the Korean Vacuum Society Conference
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• 2014.02a
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• pp.466.2-466.2
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• 2014

The Quantum dot (QD) solar cells have been under active research due to their high light harvesting efficiencies and low fabrication cost. In spite of these advantages, there have been some problems on the charge collection due to the limitation of the diffusion length. The modification of advanced nanostructure is capable of solving the charge collection problem by increasing diffusion length of electron. One dimensional nanomaterials such as nanorods, nanowires, and nanotubes may enhance charge collection efficiency in QD solar cells. In this study, we synthesized $TiO_2$ anatase nanorod arrays with length of 200 nm by two-step sol-gel method. The morphology and crystal structure for the nanorod were characterized by using scanning electron microscopy (SEM), transmission electron microscopy (TEM), and X-ray diffraction (XRD). The anatase nanorods are single-crystalline and possess preferred orientation along with (001) direction. The photovoltaic properties for the heterojunction structure QD solar cells based on the anatase nanorod were also characterized. Compared with conventional $TiO_2$ nanoparticle based QD solar cells, these nanostructure solar cells exhibited better charge collection properties due to long life time measured by transient open circuit studies. Our findings demonstrate that the single crystalline anatase nanorod arrays are promising charge transport semiconductors for heterojunction QD solar cells.

• The Transactions of the Korean Institute of Power Electronics
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• v.14 no.4
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• pp.333-342
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• 2009

Three-level Diode Clamped Multilevel Inverter, generally known as Neutral-Point-Clamped (NPC) Inverter, has an inherent problem causing Neutral Point (NP) potential variation. Until now, in many literatures NP potential problem has been investigated and lots of solutions have also been proposed. However, under fault and fault tolerant control, distinctive feature for NP potential variation problem was rarely published from the standpoint of reliability. In this paper, NP potential is analytically investigated both normal and faulty conditions under carrier based PWM. Subsequently, relation between fault detection time and size of capacitor is analyzed. This information is explored by simulation and experiment results, which contribute to enhance the reliability of inverter system.

• Journal of Power Electronics
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• v.13 no.4
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• pp.679-691
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• 2013

High-power electromagnetic transmitter power supplies are an important part of deep geophysical exploration equipment. This is especially true in complex environments, where the ability to produce a highly accurate and stable output and safety through redundancy have become the key issues in the design of high-power electromagnetic transmitter power supplies. To solve these issues, a high-frequency switching power cascade based emission power supply is designed. By combining the circuit averaged model and the equivalent controlled source method, a modular mathematical model is established with the on-state loss and transformer induction loss being taken into account. A triple-loop control including an inner current loop, an outer voltage loop and a load current forward feedback, and a digitalized voltage/current sharing control method are proposed for the realization of the rapid, stable and highly accurate output of the system. By using a new algorithm referred to as GAPSO, which integrates a genetic algorithm and a particle swarm algorithm, the parameters of the controller are tuned. A multi-module cascade helps to achieve system redundancy. A simulation analysis of the open-loop system proves the accuracy of the established system and provides a better reflection of the characteristics of the power supply. A parameter tuning simulation proves the effectiveness of the GAPSO algorithm. A closed-loop simulation of the system and field geological exploration experiments demonstrate the effectiveness of the control method. This ensures both the system's excellent stability and the output's accuracy. It also ensures the accuracy of the established mathematical model as well as its ability to meet the requirements of practical field deep exploration.